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Volume 37(2); March 2024

High Energy Density Dielectric Ceramics Capacitors by Aerosol Deposition
Hyunseok Song, Geon Lee, Jiwon Ye, Ji Yun Jung, Dae-yong Jeong, Jungho Ryu
J Electr Electron Mater 2024;37(2):119-132.   Published online March 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.2.1
Dielectric ceramic capacitors present high output power density due to the fast energy charge and discharge nature of dielectric polarization. By forming dense ceramic films with nano-grains through the Aerosol Deposition (AD) process, dielectric ceramic capacitors can have high dielectric breakdown strength, high energy storage density, and leading to high power density. Dielectric capacitors fabricated by AD process are expected to meet the increasing demand in applications that require not only high energy density but also high power output in a short time. This article reviews the recent progress on the dielectric ceramic capacitors with improved energy storage properties through AD process, including energy storage capacitors based on both leadbased and lead-free dielectric ceramics.
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A Brief Review of Power Semiconductors for Energy Conversion in Photovoltaic Module Systems
Hyeong Gi Park, Do Young Kim, Junsin Yi
J Electr Electron Mater 2024;37(2):133-140.   Published online March 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.2.2
This study offers a comprehensive evaluation of the role and impact of advanced power semiconductors in solar module systems. Focusing on silicon carbide (SiC) and gallium nitride (GaN) materials, it highlights their superiority over traditional silicon in enhancing system efficiency and reliability. The research underscores the growing industry demand for high-performance semiconductors, driven by global sustainable energy goals. This shift is crucial for overcoming the limitations of conventional solar technology, paving the way for more efficient, economically viable, and environmentally sustainable solar energy solutions. The findings suggest significant potential for these advanced materials in shaping the future of solar power technology.
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Electric-Field-Induced Strain Measurement of Ferroelectric Ceramics Using a Linear Variable Differential Transducer
Hyoung-su Han, Chang Won Ahn
J Electr Electron Mater 2024;37(2):141-147.   Published online March 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.2.3
The measurement of strain under an electric field has been widely employed to comprehend the fundamental principles of electro-mechanical responses in ferroelectric, piezoelectric, and electrostrictive materials. In particular, understanding the strain properties of piezoelectric materials in response to electrical stimulation is crucial for researching and developing components such as piezoelectric actuators, acoustic devices, and ultrasonic generators. This tutorial paper introduces the components and operational principles of the linear variable differential transducer (LVDT), a widely used displacement measurement device in various industries. Additionally, we present the configuration of an experimental setup using LVDT to measure the strain characteristics of ferroelectric, piezoelectric, or electrostrictive materials under the application of an electric field. This paper includes simple measurement results and analyses obtained through the LVDT experimental setup, providing valuable information on research methods for the electro-mechanical interactions of various materials.
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Enhancement of SiO2 Uniformity by High-Pressure Deuterium Annealing
Yong-sik Kim, Dae-han Jung, Hyo-jun Park, Ju-won Yeon, Tae-hyun Kil, Jun-young Park
J Electr Electron Mater 2024;37(2):148-153.   Published online March 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.2.4
As complementary metal-oxide semiconductor (CMOS) is scaled down to achieve higher chip density, thin-film layers have been deposited iteratively. The poor film uniformity resulting from deposition or chemical mechanical planarization (CMP) significantly affects chip yield. Therefore, the development of novel fabrication processes to enhance film uniformity is required. In this context, high-pressure deuterium annealing (HPDA) is proposed to reduce the surface roughness resulting from the CMP. The HPDA is carried out in a diluted deuterium atmosphere to achieve cost-effectiveness while maintaining high pressure. To confirm the effectiveness of HPDA, time-of-flight secondary-ion mass spectrometry (ToF-SIMS) and atomic force microscopy (AFM) are employed. It is confirmed that the absorbed deuterium gas facilitates the diffusion of silicon atoms, thereby reducing surface roughness.
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Building Integrated Photovoltaics: Technical and Aesthetic Prospects
Polgampola Chamani Madara, Hasnain Yousuf, Muhammad Aleem Zahid, Suresh Kumar Dhungel, Youngkuk Kim, Junsin Yi
J Electr Electron Mater 2024;37(2):154-163.   Published online March 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.2.5
The energy demand in the world is expected to exceed 740 million TJ by 2040 and our dependence on fossil fuels needs to be switched to sustainable and renewable energy sources like solar energy. Building Integrated Photovoltaic (BIPV) is one of the best approaches to extracting solar energy. There are more than 200 BIPV products in the market currently but when it comes to integrating these products into the technical aspects such as buildings’ structural integrity, thermal, daylight retainment and aesthetic prospects to be considered. The share of BIPV integration potential of different building types in the world of residential, agricultural, industrial, commercial and other buildings account for 66%, 4.8%, 8.1%, 19.9%, and 1.2% accordingly. Many solar technologies developed to achieve architectural requirements, but the main problem is the trade-off between efficiency and aesthetic appeal, which is less than 10% in coloured and transparent solar modules. This paper discusses the different applications of solar photovoltaics (PV) in building architecture, technical requirements, and different module technologies. The article provides a comprehensive guide for researchers and designers working on the development of BIPV integrations.
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Structural and Electrical Properties of (La0.7Sr0.3)(Mn1-xFex)O3 Thin Films Prepared by Sol-Gel Method for Thermistor Devices
Ji-su Yuk, Sam-haeng Yi, Myung-gyu Lee, Joo-seok Park, Young-gon Kim, Sung-gap Lee
J Electr Electron Mater 2024;37(2):164-168.   Published online March 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.2.6
(La0.7Sr0.3)(Mn1-xFex)O3 (LSMFO) (x = 0.03, 0.06, 0.09, 0.12) precursor solution are prepared by sol-gel method. LSMFO thin films are fabricated by the spin-coating method on Pt/Ti/SiO2/Si substrate, and the sintering temperature and time are 800℃ and 1 hr, respectively. The average thickness of the 6-times coated LSMFO films is about 181 to 190 nm and average grain size is about 18 to 20 nm. As the amount of Fe added in the LSMFO thin film increased, the resistivity decreased, and the TCR and B25/65-value increased. Electrical resistivity, TCR and B25/65-value of the (La0.7Sr0.3)(Mn0.88Fe0.12)O3 thin film are 0.0136 mΩ-cm, 0.358%/℃, and 328 K at room temperature, respectively. The resistivity properties of LSMFO thin films matched well with Mott’s VRH model.
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Changes in Structural, Electrical, and Optical Properties Depending on the Thickness of AZO Thin Films Deposited with FTS
Haechan Kim, Hyungmin Kim, Seongmin Shin, Kyunghwan Kim, Jeongsoo Hong
J Electr Electron Mater 2024;37(2):169-174.   Published online March 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.2.7
In this study, the structural, electrical, and optical properties of AZO films of various thicknesses are compared. The AZO films were deposited on a glass substrate by FTS (Facing-Target-Sputtering) This research was conducted to find the optimal thickness for Transparent Conductive Oxide (TCO). AZO has suitable properties for TCO such as low resistivity, and high transmittance. Thin films of all thicknesses showed a transmittance of over 80% in the visible light region and electrical properties improved as thickness increased. It was confirmed that the film of 300 nm thick had the best performance due to its low resistivity, and uniform surface. This research is expected to help find optimal conditions in various fields where TCO is used, such as solar cells, displays, and sensors in the future.
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Design and Fabrication of an LPVT Embedded in a GIS Spacer
Seung-gwan Park, Gyeong-yeol Lee, Nam-hoon Kim, Cheol-hwan Kim, Gyung-suk Kil
J Electr Electron Mater 2024;37(2):175-181.   Published online March 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.2.8
In electrical power substations, bulky iron-core potential transformers (PTs) are installed in a tank of gas-insulated switchgear (GIS) to measure system voltages. This paper proposed a low-power voltage transformer (LPVT) that can replace the conventional iron-core PTs in response to the demand for the digitalization of substations. The prototype LPVT consists of a capacitive voltage divider (CVD) which is embedded in a spacer and an impedance matching circuit using passive components. The CVD was fabricated with a flexible PCB to acquire enough insulation performance and withstand vibration and shock during operation. The performance of the LPVT was evaluated at 80%, 100%, and 120% of the rated voltage (38.1 kV) according to IEC 61869-11. An accuracy correction algorithm based on LabVIEW was applied to correct the voltage ratio and phase error. The corrected voltage ratio and phase error were +0.134% and +0.079 min., respectively, which satisfies the accuracy CL 0.2. In addition, the voltage ratio of LPVT was analyzed in ranges of -40~+40℃, and a temperature correction coefficient was applied to maintain the accuracy CL 0.2. By applying the LPVT proposed in this paper to the same rating GIS, it can be reduced the length per GIS bay by 11%, and the amount of SF6 by 5~7%.
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Research on Water-Repellent Coating Materials to Prevent Solar Module Pollution
Young-a Park, Da Yeon Jung, Hyun Chul Ki
J Electr Electron Mater 2024;37(2):182-187.   Published online March 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.2.9
Currently, the most developed new energy source is solar energy. Because solar power is installed outside, it is exposed to many pollutants. Pollutants are causing the characteristics of solar energy to deteriorate. Therefore, this study aims to develop a water-repellent coating to prevent contamination of solar modules. Silica and Titania materials are mainly used as water-repellent coating materials. In this study, it was based on silica and the contact angle characteristics were measured according to the change in the amount of silica and ammonia water added and the number of coatings. As a result of the measurement, it was confirmed that the contact angle was more than 60 degrees when 0.5 mol of TEOS was added to 50 mL and 0.15 M when 1 mL of ammonia water was added to 296.47 ml of distilled water. And it was confirmed that the contact angle improved when the number of coatings was applied twice. A water-repellent coating material was applied to low iron tempered glass used to protect dye-sensitized solar cell modules. The characteristics of the module were measured after spraying DI-Water on low-emission tempered glass with a water-repellent coating. As a result of the measurement, the efficiency of the module without application, the efficiency of the module coated once, and the module coated twice were 4.87%, 4.90%, and 4.91%, respectively. It was confirmed that the efficiency of the module increased by applying water-repellent coating. As a result of this study, it is determined that the water-repellent coating material will help improve solar power generation efficiency and lifespan by being self-cleaning and non-reflective.
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Optimized O2 Plasma Surface Treatment for Uniform Sphere Lithography on Hydrophobic Photoresist Surfaces
Yebin Ahn, Jongchul Lee, Hanseok Kwon, Jungbin Hong, Han-don Um
J Electr Electron Mater 2024;37(2):188-194.   Published online March 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.2.10
This paper introduces an optimized oxygen (O2) plasma surface treatment technique to enhance sphere lithography on hydrophobic photoresist surfaces. The focus is on semiconductor manufacturing, particularly the creation of finer structures beyond the capabilities of traditional photolithography. The key breakthrough is a method that makes substrate surfaces hydrophilic without altering photoresist patterns. This is achieved by meticulously controlling the O2 plasma treatment duration. The result is the consistent formation of nano and microscale patterns across large areas. From an academic perspective, the study deepens our understanding of surface treatments in pattern formation. Industrially, it heralds significant progress in semiconductor and precision manufacturing sectors, promising enhanced capabilities and efficiency.
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EMI (Electromagnetic Interference) Shielding Properties of Barium-Based Ferrite Thin Films Prepared by Spin Spray Method
Hye Ryeong Oh, Yeon-ju Park, Woo-sung Lee, Chan-sei Yoo, Myong-jae Yoo, Intae Seo
J Electr Electron Mater 2024;37(2):195-201.   Published online March 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.2.11
The low-temperature deposition of BaNi(2-x)CoxFe16O27 thin films with a Ba hexaferrite structure for electromagnetic shielding was studied. The BaNi(2-x)CoxFe16O27 thin films produced through the spin spray process were suitable for thin film deposition on a flexible substrate because it crystallized well at low temperature below 90℃. The change in shielding characteristics depending on the Co content of the BaNi(2-x)CoxFe16O27 thin film was investigated, and excellent shielding characteristics with S21 of -1 dB were obtained in a wide frequency range of 26~40 GHz when the Co content was 0.4 or more. The purpose of this study is to analyze changes in shielding properties caused by change in Co content in relation to phase changes in BaNi(2-x)CoxFe16O27 and obtain basic data for developing excellent flexible electromagnetic wave shielding materials.
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Characterization of Ag/TiO2 Nanoparticles Synthesis
Kyungho Kang, Yonggi Jo, Sun-geum Kim
J Electr Electron Mater 2024;37(2):202-207.   Published online March 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.2.12
This study examines a manufacturing process for the photoelectrode material of dye-sensitized solar cell (DSSC) intending to increase efficiency through the surface plasmon resonance phenomenon of nanoparticles with a composite structure made of Ag and TiO2. This invention involves the use of Ag and TiO2 nanoparticles in the solar cell. These nanoparticles cause surface plasmon resonance, which amplifies and scatters incident solar energy, enhancing the dye’s rate of light absorption. It also makes it possible to absorb energy in wavelength ranges that were previously difficult to do, which increases efficiency. Centrifugal separation and heat synthesis are used to create the composite metal structures, and certain combinations are used to decide the particle morphologies. To increase the efficiency of organic solar cells and DSSC, the Ag/TiO2 composite structure is therefore quite likely to be used.
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Comparison of Electrical Properties of β-Gallium Oxide (β-Ga2O3) Power SBDs with Guard Ring Structures
Hoon-ki Lee, Kyujun Cho, Woojin Chang, Jae-kyoung Mun
J Electr Electron Mater 2024;37(2):208-214.   Published online March 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.2.13
This reports the electrical properties of single-crystal β-gallium oxide (β-Ga2O3) vertical Schottky barrier diodes (SBDs) with a different guard ring structure. The vertical Schottky barrier diodes (V-SBDs) were fabricated with two types guard ring structures, one is with metal deposited on the Al2O3 passivation layer (film guard ring: FGR) and the other is with vias formed in the Al2O3 passivation layer to allow the metal to contact the Ga2O3 surface (metal guard ring: MGR). The forward current values of FGR and MGR V-SBD are 955 mA and 666 mA at 9 V, respectively, and the specific on-resistance (Ron,sp) is 5.9 mΩ·cm2 and 29 mΩ·cm2. The series resistance (Rs) in the nonlinear section extracted using Cheung’s formula was 6 Ω, 4.8 Ω for FGR V-SBD, 10.7 Ω, 6.7 Ω for MGR V-SBD, respectively, and the breakdown voltage was 528 V for FGR V-SBD and 358 V for MGR V-SBD. Degradation of electrical characteristics of the MGR V-SBD can be attributed to the increased reverse leakage current caused by the guard ring structure, and it is expected that the electrical performance can be improved by preventing premature leakage current when an appropriate reverse voltage is applied to the guard ring area. On the other hand, FGR V-SBD shows overall better electrical properties than MGR V-SBD because Al2O3 was widely deposited on the Ga2O3 surface, which prevent leakage current on the Ga2O3 surface.
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A Study on the Development of Nanorod-Type Ni-Rich Cathode Materials by Using Co-Precipitation Method
Joohyuk Park
J Electr Electron Mater 2024;37(2):215-222.   Published online March 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.2.14
Ni-rich cathode materials have been developed as the most promising candidates for next-generation cathode materials for lithium-ion batteries because of their high capacity and energy density. In particular, the electrochemical performance of lithium-ion batteries could be enhanced by increasing the contents of nickel ion. However, there are still limitations, such as low structural stability, cation mixing, low capacity retention and poor rate capability. Herein, we have successfully developed the nanorod-type Ni-rich cathode materials by using co-precipitation method. Particularly, the nanorod-type primary particles of LiNi0.7Co0.15Mn0.15O2 could facilitate the electron transfer because of their longitudinal morphology. Moreover, there were holes at the center of secondary particles, resulting in high permeability of the electrolyte. Lithium-ion batteries using the prepared nanorod-type LiNi0.7Co0.15Mn0.15O2 achieved highly improved electrochemical performance with a superior rate capability during battery cycling.
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Formation of Metal Mesh Electrodes via Laser Plasmonic Annealing of Metal Nanoparticles for Application in Flexible Touch Sensors
Seongmin Jeong, Yun Sik Hwang, Yu Mi Woo, Yong Jun Cho, Chan Hyeok Kim, Min Gi An, Ho Seok Seo, Chan Hyeon Yang, Kwi-il Park, Jung Hwan Park
J Electr Electron Mater 2024;37(2):223-229.   Published online March 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.2.15
Laser-induced plasmonic sintering of metal nanoparticles (NPs) holds significant promise as a technology for producing flexible conducting electrodes. This method offers immediate, straightforward, and scalable manufacturing approaches, eliminating the need for expensive facilities and intricate processes. Nevertheless, the metal NPs come at a high cost due to the intricate synthesis procedures required to ensure long-term reliability in terms of chemical stability and the prevention of NP aggregation. Herein, we induced the self-generation of metal nanoparticles from Ag organometallic ink, and fabricated highly conductive electrodes on flexible substrates through laser-assisted plasmonic annealing. To demonstrate the practicality of the fabricated flexible electrode, it was configured in a mesh pattern, realizing multi-touchable flexible touch screen panel.
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