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Volume 33(3); May 2020

Changes of Photovoltaic Properties of Flexible CIGS Solar Cell Under Mechanical Bending Stress
Sungjun Kim, Jeha Kim
J Electr Electron Mater 2020;33(3):163-168.   Published online May 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.3.1
We studied the change of photovoltaic properties of a flexible CuInxGa(1-x)Se2 (CIGS) solar cell fabricated on polyimide by mechanical bending with curvature radii of 75 mm (75R) and 20 mm (20R). The flexible CIGS cells were flattened on a PET film, then placed and forced against the surface of a curved block fabricated with pre-designed curvatures. Both up (compressive) and down (tensile) bending were applied to a specimen of CIGS on PET with curvatures of 75R and 20R for 10,000 times and 2,000 times, respectively. From J-V measurements, we found that the conversion efficiency (Eff.) was reduced by 3% and 4% for up-and down-bending, respectively, at curvature 75R; it was greatly reduced by 15% for curvature 20R in the up-bending. However, the open circuit voltage (Voc) and short-circuit current density (Jsc) seemed to change little, within 3%, for the applied mechanical stresses. The degradation in Eff. resulted from the deterioration of the series (Rs) and shunt (Rsh) resistances of the solar cell.
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Research for Hot Carrier Degradation in N-Type Bulk FinFETs
Jinsu Park, Sanchari Showdhury, Geonju Yoon, Jaemin Kim, Keewon Kwon, Sangwoo Bae, Jinseok Kim, Junsin Yi
J Electr Electron Mater 2020;33(3):169-172.   Published online May 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.3.2
In this paper, the effect of hot carrier injection on an n-bulk fin field-effect transistor (FinFET) is analyzed. The hot carrier injection method is applied to determine the performance change after injection in two ways, channel hot electron (CHE) and drain avalanche hot carrier (DAHC), which have the greatest effect at room temperature. The optimum condition for CHE injection is VG=VD, and the optimal condition for DAHC injection can be indirectly confirmed by measuring the peak value of the substrate current. Deterioration by DAHC injection affects not only hot electrons formed by impact ionization, but also hot holes, which has a greater impact on reliability than CHE. Further, we test the amount of drain voltage that can be withstood, and extracted the lifetime of the device. Under CHE injection conditions, the drain voltage was able to maintain a lifetime of more than 10 years at a maximum of 1.25 V, while DAHC was able to achieve a lifetime exceeding 10 years at a 1.05-V drain voltage, which is 0.2 V lower than that of CHE injection conditions.
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Analysis of Electrical Characteristics According to the Pillar Spacing of 4.5 kV Super Junction IGBT
Geon Hee Lee, Byoung Sup Ahn, Ey Goo Kang
J Electr Electron Mater 2020;33(3):173-176.   Published online May 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.3.3
This study focuses on a pillar in which is implanted a P-type maneuver under a P base. This structure is called a super junction structure. By inserting the pillar, the electric field concentrated on the P base is shared by the pillar, so the columns can be dispersed while maintaining a high breakdown voltage. Ten pillars were generated during the multi epitaxial process. The interval between pillars is varied to optimize the electric field to be concentrated on the pillar at a threshold voltage of 6 V, a yield voltage of 4,500 V, and an on-state voltage drop of 3.8 V. The density of the filler gradually decreased when the interval was extended by implanting a filler with the same density. The results confirmed that the size of the depletion layer between the filler and the N-epitaxy layer was reduced, and the current flowing along the N-epitaxy layer was increased. As the interval between the fillers decreased, the cost of the epitaxial process also decreased. However, it is possible to confirm the trade-off relationship that deteriorated the electrical characteristics and efficiency.
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Electrical Characteristics of 1,200 V Reverse Conducting-IGBT
Se Young Kim, Byoungsub Ahn, Ey Goo Kang
J Electr Electron Mater 2020;33(3):177-180.   Published online May 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.3.4
This paper focuses on the 1,200-V level reverse conducting-insulated gate bipolar transistor (RC-IGBT). The structure of the RC-IGBT has an n+ collector at the collector terminal. The breakdown voltage, Vth, Vce-sat, and turn-off time, and the electrical characteristics of a field-stop IGBT (FS-IGBT) and RC-IGBT are compared and analyzed using simulations. Based on the results, the RC-IGBT obtained a turn-off time of 320.6 ㎲ and a breakdown voltage of 1,720 V, while the FS-IGBT obtained a turn-off time of 742.2 ㎲ and a breakdown voltage of 1,440 V. Therefore, RC-IGBTs have faster on/off transitions and a higher breakdown voltage, which can reduce the size of the element.
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A Study on the Fabrication of Multi-Walled Nanotubes (MWCNT) Based Thin Film and Chemical Sensor Operation Characteristics
Jae Ha Noh, Junseck Choi, Dongwan Ko, Joonyoung Seo, Sangtae Lee, Jung-yeul Jung, Jiho Chang
J Electr Electron Mater 2020;33(3):181-185.   Published online May 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.3.5
Hazardous and noxious substance (HNS) detection sensors were fabricated using multi-walled carbon nanotubes (MWCNTs) and various binder materials for ion batteries. To obtain uniformly printed films, the printing precision according to the substrate cleaning method was monitored, and the printing paste mixing ratio was investigated. Binders were prepared using styrene butadiene rubber + carboxymethyl cellulose (SBR+CMC), polyvinylidene fluoride + n-methyl-2-pyrrolidene (PVDF+NMP), and mixed with MWCNTs. The surface morphology of the printed films was examined using an optical microscope and a scanning electron microscope, and their electrical properties are investigated using an I-V sourcemeter. Finally, sensing properties of MWCNT printed films were measured according to changes in the concentration of the chemical under the various applied voltages. In conclusion, the MWCNT printed films made of (SBR+CMC) were found to be feasible for application to the detection of hazardous and noxious chemicals spilled in seawater.
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A Research on the Improvement of Visibility Using Low Deck Lighting in Bad Weather
Ki Ho Nam, Chung Hyeok Kim, Ki Ho Nam
J Electr Electron Mater 2020;33(3):186-193.   Published online May 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.3.6
We investigate a fog-detection CCT control system using low deck lighting as a solution to the forward visibility of pole-type street lamps employed on existing roads. The lighting standards were met with a light source that has less compared with those of pole-type street lamps. The results show that the transmission rate was increased by changing the color temperature by automatically recognizing fog in bad weather and minimizing the phenomenon of lighting. In addition, it was allowed to create a safer and more comfortable driving environment for drivers owing to flicker or light pollution of existing pole-type street lamps. As a result, if lighting is used at a lower level than pole-type street lamps, the accident rate caused by securing the driver’s forward visibility can be reduced sharply and existing problems can be resolved.
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Preparation and Characterization of Swallow-Tail Terrylene Bisimide as Organic Phosphor
Sung Bong Jung, Yeon Tae Jeong
J Electr Electron Mater 2020;33(3):194-200.   Published online May 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.3.7
Perylene bisimide derivatives are developed for red organic phosphor because of their advantages, such as excellent luminous efficiency and high thermal stability. Despite these advantages, they have poor solubility characteristics in organic solvents and short emission wavelength as red organic phosphor for hybrid light-emitting diodes (LEDs). In this study, we prepared terrylene bisimide using a coupling reaction and swallow-tail imide group, which has excellent solubility. The structures and properties of swallow-tail terrylene bisimide (9C) were analyzed using 1H-nuclear magnetic resonance (1H-NMR), Fourier-transform infrared (FT-IR), UV/Vis spectroscopy, and thermal gravimetric analysis (TGA). The maximum absorption wavelength of (9C) in the UV/Vis spectrum was 647 nm, and the maximum emission wavelength was 676 nm. In the TGA, (9C) demonstrated good thermal stability with less than 5 wt% weight loss up to 415℃. In the solubility test, (9C) has a good solubility of more than 5 wt% in chloroform and dichloromethane. When the compounds (9C) were mixed with PMMA (polymethly methacrylate), the films showed peaks at 680 nm in the PL spectra. The results verify the suitability of (9C) as a red organic phosphor for hybrid LEDs.
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Design for a Fuse of High Durability Protection Elements for Improving the Safety of DC Current Measurement Device
Ye Ji Lee, Jae Seo Youn, Sung Chul Cho, Sung Yeo Noh
J Electr Electron Mater 2020;33(3):201-207.   Published online May 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.3.8
With the expansion in the use of DC power systems and increased need for system maintenance, the development of measurement devices for maintenance requires high stability. Of the different kinds of DC current measurement devices, the single-shot measurement device causes the input signal of the current measuring unit to initially generate a high inrush current. The high inrush current flows into the signal processor of the meter, shortening the life of the internal fuses and causing failure. Therefore, in this study, the I2t value for increasing the durability of the fuse is designed using the available wire diameter. Operating characteristics for 210~400% over-current of the rated current, which is relatively low over-current, are realized by the plating of low melting tin metal. As a result, a method of designing a fuse element for a DC power supply, which improves the safety of the DC current measurement device by blocking the failure caused by the inrush current, is presented.
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Effect of Starting Powder on the Growth of BaTiO3 Film Prepared by Aerosol Deposition Process
Myung-yeon Cho, Ik-soo Kim, Dong-won Lee, Sang-mo Koo, Jong-min Oh
J Electr Electron Mater 2020;33(3):208-213.   Published online May 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.3.9
Four types of BaTiO3 powders are prepared and successfully deposited on glass and Pt/Si substrates using the aerosol deposition process. Particles with sizes of 0.45 μm and 0.3 μm are selected as the starting powder, while those powders are treated using a different milling method. The jet-milled and ball-milled powders not only showed a smaller particle-size distribution, but compared with the non-milled powder, it also had a higher deposition rate using the uniformly generated aerosol. Although the films deposited using particles with size 0.45 μm exhibited some craters on the surface, significantly flat film surfaces were obtained. However, particles with size 0.3 μm create a slightly rough film surface, but the dielectric constant was greater than in the case involving particles with size 0.45 μm. Consequently, a suitably large particle size significantly influences the deposition rate and improvement in the surface roughness, and a uniform particle size distribution appears to contribute to an improved dielectric constant. Therefore, it is believed that the dielectric properties along with the growth characteristics can be enhanced by limiting particle size and shape.
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The Effect of Mg Precursors on Optical and Structural Characteristics of Sol-Gel Processed Mg0.3Zn0.7O Thin Films
Ahram Yeom, Hong Seung Kim, Nak Won Jang, Young Yun, Hyung Soo Ahn
J Electr Electron Mater 2020;33(3):214-218.   Published online May 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.3.10
In this study, MgxZn1-xO thin films, which can be applied not only to active layers of light-emitting devices (LEDs), such as UV-LEDs, but also to solar cells, high mobility field-effect transistors, and power semiconductor devices, are fabricated using the sol-gel method. ZnO and Mg0.3Zn0.7O solution synthesized by the sol-gel method and the thin film were grown by spin coating on a Si (100) substrate and sapphire substrate. The solutions are synthesized by dissolving precursor materials in 2-methoxyethanol (2-ME) solvent, and then monoethanolamine (MEA) was added to the mixed solution as a sol stabilizer. Zinc acetate dihydrate is used as a ZnO precursor, while Mg nitrate hexahydrate and Mg acetate tetrahydrate are used as an MgO precursor. Then, the optical and structural characteristics of the fabricated thin films are compared. The molar concentration of the Zn precursor in the solvent is fixed at 0.3 M, and the amount of the Mg precursor is 30% of Mg2+/Zn2+. The optical characteristics are measured using an UV-vis spectrophotometer, and the transmittance of each wavelength is measured. Structural characteristics are measured using X-ray diffraction (XRD) and transmission electron microscopy (TEM). Composition analyses are performed using energy dispersive X-ray spectroscopy (EDS). The Mg0.3Zn0.7O thin film was well formed at the ratio of the Mg precursor added regardless of the type of Mg precursor, and the c-axis of the thin film was decreased, while the band gap was increased to 3.56 eV.
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Study of Deposition Mechanism of Al2O3 Films According to Al2O3 Particle Size via Aerosol Deposition Process
Ik-soo Kim, Myung-yeon Cho, Sang-mo Koo, Dong-won Lee, Jong-min Oh
J Electr Electron Mater 2020;33(3):219-224.   Published online May 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.3.11
Al2O3 powders with particle sizes of 0.35 μm, 0.5 μm, 1.5 μm, and 2.5 μm are deposited onto glass and Cu substrates using the aerosol deposition (AD) process. The deposition characteristics of Al2O3 films using those four types of Al2O3 powders are investigated to determine the influence of the particle size on the films. To observe detailed micro-structures of the films, the cross-section and surface morphology are observed. Then, the crystalline size and internal strain are calculated from X-ray diffraction peaks in order to confirm the hammering effect as well as the micro-strain during the AD deposition. From the above results, deposition mechanisms related to the particle size are studied. The results of this study indicate the optimal particle size and formation mechanisms for dense Al2O3 film with a smooth surface roughness as well as for a porous Al2O3 film with a rough surface roughness.
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Methodology for Optimizing Permittivity Distribution of 145 kV Miniaturized Functional Graded Spacer Using Non-Dominated Sorting Genetic Algorithm-Ⅱ
Yo-han Noh, Seung-hyun Kim, Jong-hun Cheong, Han-goo Cho
J Electr Electron Mater 2020;33(3):225-230.   Published online May 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.3.12
Recently, with the miniaturization of GIS, there is a need for the miniaturization of spacers as accessories. Miniaturized spacers make it difficult to secure adequate insulation distances, resulting in a more concentrated electric field at the triple junction of high-voltage (HV) conductor-insulator (spacer)-insulation gas (SF6), which is a weakness in GIS. Therefore, by introducing a new concept design technology, functionally graded material (FGM), which is recently applied to various materials and parts industries, three-dimensional control of the dielectric constant distribution in a spacer can be expected to alleviate triple-junction electric field occupancy and improve insulation performance. In this study, we propose an optimized model using NSGA-II to optimize the permittivity distribution of FGM applied spacer.
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Analysis on Damage of Porcelain Insulators Using AE Technique
In-hyuk Choi, Koo-yong Shin, Yun-seog Lim, Ja-bin Koo, Ju-am Son, Dae-yeon Lim, Tae-keun Oh, Young-geun Yoon
J Electr Electron Mater 2020;33(3):231-238.   Published online May 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.3.13
This paper investigates the soundness of porcelain insulators associated with the acoustic emission (AE) technique. The AE technique is a popular non-destructive method that measures and analyzes the burst energy that occurs mainly when a crack occurs in a high-frequency region. Typical AE methods require continuous monitoring with frequent sensor calibration. However, in this study, the AE technique excites a porcelain insulator using only an impact hammer, and it applies a high-pass filter to the signal frequency range measured only in the AE sensor by comparing the AE and the acceleration sensors. Next, the extracted time-domain signal is analyzed for the damage assessment. In normal signals, the duration is about 2ms, the area of the envelope is about 1,000, and the number of counts is about 20. In the damage signal, the duration exceeds 5ms, the area of the envelope is about 2,000, and the number of counts exceeds 40. In addition, various characteristics in the time and frequency domain for normal and damage cases are analyzed using the short-time Fourier transform (STFT). Based on the results of the STFT analysis, the maximum energy of a normal specimen is less than 0.02, while in the case of the damage specimen, it exceeds 0.02. The extracted high-frequency components can present dynamic behavior of crack regions and eigenmodes of the isolated insulator parts, but the presence, size, and distribution of cracks can be predicted indirectly. In this regard, the characteristics of the surface crack region were derived in this study.
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Image Analysis by CNN Technique for Maintenance of Porcelain Insulator
In-hyuk Choi, Koo-yong Shin, Ja-bin Koo, Ju-am Son, Dae-yeon Lim, Tae-keun Oh, Young-geun Yoon
J Electr Electron Mater 2020;33(3):239-244.   Published online May 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.3.14
This study examines the feasibility of the image deep learning method using convolution neural networks (CNNs) to maintain a porcelain insulator. Data augmentation is performed to prevent over-fitting, and the classification performance is evaluated by training the age, material, region, and pollution level of the insulator using image data in which the background and labelling are removed. Based on the results, it was difficult to predict the age, but it was possible to classify 76% of the materials, 60% of the pollution level, and more than 90% of the regions. From the results of this study, we identified the potential and limitations of the CNN classification for the four groups currently classified. However, it was possible to detect discoloration of the porcelain insulator resulting from physical, chemical, and climatic factors. Based on this, it will be possible to estimate the corrosion of the cap and discoloration of the porcelain caused by environmental deterioration, abnormal voltage, and lightning.
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Effect of Native Oxide Layer on the Water Contact Angle to Determine the Surface Polarity of SiC Single Crystals
Jin Yong Park, Jung Gon Kim, Dae Sung Kim, Woo Sik Yoo, Won Jae Lee
J Electr Electron Mater 2020;33(3):245-248.   Published online May 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.3.15
The wettability of silicon carbide (SiC) crystal, which has 6H-SiC and 4H-SiC regions prepared using the physical vapor transport (PVT) method, is quantitatively analyzed using dispensed deionized (DI) water droplets. Regardless of the polytypes in SiC, the average of five contact angle measurements showed a difference of about 6° between the Si-face and C-face. The contact angle on the Si-face (C-face) is measured after the removal of the native oxide using BOE (6:1), and revealed a significant decrease of the contact angle from 74.9° (68.4°) to 47.7° (49.3°) and from 75.8° (70.2°) to 51.6° (49.5°) for the 4H-SiC and 6H-SiC regions, respectively. The contact angle of the Si-face recovered over time during room temperature oxidation in air; in contrast, that of the C-face did not recover to the initial value. This study shows that the contact angle is very sensitive to SiC surface polarity, specific surface conditions, and process time. Contact angle measurements are expected to be a rapid way of determining the surface polarity and wettability of SiC crystals.
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