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Volume 31(7); November 2018

Study on Reflectance Improvement of Al-Ti Based Oxide Thin Films for Semitransparent Solar Cell Applications
Eun Kyu Lee, So Un Jeong, Ki Su Bang, Seung-yun Lee
J Electr Electron Mater 2018;31(7):437-442.   Published online November 1, 2018
This work reports the preparation of Al-Ti based oxide thin films and their optical properties. Although the transmittance of a TiO2/Al2O3 bilayer structure was as high as 90% at wavelengths of 600 nm or larger, the reflectance of the bilayer reached its minimum at wavelengths of around 360 nm. The transmittance of an 89-nm-thick TiO2 thin film rapidly increased and then decreased at a critical wavelength because of destructive interference. The wavelength corresponding to the reflectance minimum increased after an increase in TiO2 film thickness. The smooth surface morphology of the AlTiO thin film was retained up to a film thickness of 65 nm, and the transmittance of the film was inversely proportional to film thickness, in accordance with the general tendency for optical films. The reflectance of the AlTiO film at visible light wavelengths was lower than that of the TiO2 film, which implies that the AlTiO film is suitable for applications as an optical thin film layer in semitransparent solar cells.
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The Effect of Temperature on the Photoluminescence Properties of the InZnP/ZnSe/ZnS (Core/Multishell) Quantum Dots
Min Ji Son, Hyunsung Jung, Younki Lee, Eunhae Koo, Jiwon Bang
J Electr Electron Mater 2018;31(7):443-449.   Published online November 1, 2018
We investigated the temperature-dependent photoluminescence spectroscopy of colloidal InZnP/ZnSe/ZnS (core/ shell/shell) quantum dots with varying ZnSe and ZnS shell thickness in the 278~363 K temperature range. Temperature-dependent photoluminescence of the InZnP-based quantum dot samples reveal red-shifting of the photoluminescence peaks, thermal quenching of photoluminescence, and broadening of bandwidth with increasing temperature. The degree of bandgap shifting and line broadening as a function of temperature is affected little by shell composition and thickness. However, the thermal quenching of the photoluminescence is strongly dependent on the shell components. The irreversible photoluminescence quenching behavior is dominant for thin-shell-deposited InZnP quantum dots, whereas thick-shelled InZnP quantum dots exhibit superior thermal stability of the photoluminescence intensity.
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Defect Prediction Using Machine Learning Algorithm in Semiconductor Test Process
Suyeol Jang, Mansik Jo, Seulki Cho, Byungmoo Moon
J Electr Electron Mater 2018;31(7):450-454.   Published online November 1, 2018
Because of the rapidly changing environment and high uncertainties, the semiconductor industry is in need of appropriate forecasting technology. In particular, both the cost and time in the test process are increasing because the process becomes complicated and there are more factors to consider. In this paper, we propose a prediction model that predicts a final “good” or “bad” on the basis of preconditioning test data generated in the semiconductor test process. The proposed prediction model solves the classification and regression problems that are often dealt with in the semiconductor process and constructs a reliable prediction model. We also implemented a prediction model through various machine learning algorithms. We compared the performance of the prediction models constructed through each algorithm. Actual data of the semiconductor test process was used for accurate prediction model construction and effective test verification.
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Characterization and Synthesis of BN Fibers According to the Content of BN Nanopowder by Electrospinning Method
Jong Hyeok Lee, Myoung Pyo Chun, Jin Ah Hwang, Young Geun Jung, Jae Uk Chu
J Electr Electron Mater 2018;31(7):455-461.   Published online November 1, 2018
Boron nitride (BN) nanofibers were fabricated using BN nanoparticles (70 nm) by electrospinning. Morphologies such as the diameter and density of the BN nanofibers are strongly influenced by the viscosity and dispersion state of the precursor solution. In this study, the precursor solution was prepared by ball milling BN nanoparticles and polyvinylpyrrolidone (PVP, Mw~1,300,000) in ethanol, which was electrospun and then calcined to produce BN fibers. High-quality BN nanofibers were well fabricated at a BN concentration of 15 wt% with their diameters in the range of 500 nm to 800 nm; the viscosity of the precursor solution was 400 mPa·S. The calcination of the as-electrospun BN fibers seemed to be completed by holding them at 350℃ for 2 h considering the TGA data. The morphologies and phases of the BN fibers were investigated by scanning electron microscopy (SEM) and X-ray diffractometry (XRD), respectively; Fourier transform infrared (FT-IR) was also used for structure analysis.
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Piezoelectric Energy Harvesting Characteristics of Trapezoidal PZT/Ag Laminate Cantilever Generator
Yong-hyeon Na, Min-seon Lee, Ji-sun Yun, Youn-woo Hong, Jong-hoo Paik, Jeong-ho Cho, Jung Woo Lee, Young-hun Jeong
J Electr Electron Mater 2018;31(7):462-468.   Published online November 1, 2018
The piezoelectric energy harvesting characteristics of a trapezoidal cantilever generator with lead zirconate titanate (PZT) laminate were investigated with various Ag inner electrodes. The piezoelectric mode of operation was a transverse mode by using a planar electrode pattern. The piezoelectric cantilever generator was fabricated using trapezoidal cofired-PZT/Ag laminates by five specimens of 2, 3, 4, 7, and 13 layers of Ag. As the number of Ag electrodes increased, impedance and output voltage at resonant frequency significantly decreased, and capacitance and output current showed an increasing tendency. A maximum output power density of 7.60 mW/cm3 was realized for the specimen with seven Ag layers in the optimal condition of acceleration (1.2 g) and resistive load (600 Ω), which corresponds to a normalized power factor of 5.28 mW/g2·cm3.
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A Study on Dielectric Properties of Polycarbonate Film Due to Variation of Degradation Time
Sung Ill Lee
J Electr Electron Mater 2018;31(7):469-474.   Published online November 1, 2018
In this study, the capacity and FTIR of polycarbonate film that was degraded for 2, 4, and 8 h in a thermostat at 180℃ was measured. The results of this study are as follows. It was found that the capacity decreased with increasing degradation time and frequency. This findings suggest that the attraction between molecules and amorphous polycarbonate increased because it contains the ketone group (-C=O-) and the chain of dioxides group (-O-R-O-). Measurement by FTIR found that the time of thermal degradation has a smaller impact because the transmutation or variation of the material does not occur. Measurement by SEM magnified 1,000 times found that a longer thermal degradation time results in thermal decomposition of the specimen’s particles.
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CrC Interlayer Effect on Tribological Properties of Amorphous Carbon Deposited by UBMS Method
Phil Jung Kim, Yong Seob Park
J Electr Electron Mater 2018;31(7):475-480.   Published online November 1, 2018
We investigated the tribological properties of amorphous carbon (a-C) films deposited with CrC interlayers of various thicknesses as the adhesive layer. A-C and CrC thin films were deposited using the unbalanced magnetron (UBM) sputtering method with graphite and chromium as the targets. CrC films as the interlayer were fabricated under a-C films, and various structural, surface, and tribological properties of a-C films deposited with various CrC interlayer thicknesses were investigated. With various CrC interlayer thicknesses under a-C films, the tribological properties of CrC/a-C films were improved; the increased film thickness exhibited a maximum high hardness of over 27.5 GPa, high elastic modulus of over 242 GPa, critical load of 31 N, residual stress of 1.85 GPa, and a smooth surface below 0.09 nm at the condition of 30-nm CrC thickness.
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Aluminum Based Oxide/Metal/Oxide Structures for the Application in Transparent Electrodes
Daekyun Kim, Dooho Choi
J Electr Electron Mater 2018;31(7):481-485.   Published online November 1, 2018
In this study, oxide/metal/oxide-type transparent electrodes based on Al and ZnO were investigated. Thin films of these materials were sputter-deposited at room temperature. To evaluate the thickness dependence of the oxide layers, the top and bottom ZnO layers were varied in the range of 5~80 nm and 2.5~20 nm, respectively. When the thicknesses of the top and bottom ZnO layers were fixed at 30 nm and 2.5 nm, a maximum transmitance of 66% and sheet resistance of 16.5 Ω/□ were achieved, which is significantly improved compared with the Al layer without top and bottom ZnO layers showing a maximum transmitance of 44.3% and sheet resistance of 44 Ω/□.
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Fully Solution-Processed Green Organic Light-Emitting Diodes Using the Optimized Electron Transport Layers
Joo Won Han, Yong Hyun Kim
J Electr Electron Mater 2018;31(7):486-489.   Published online November 1, 2018
Solution-processed organic light-emitting diodes (OLEDs) have the advantages of low cost, fast fabrication, and large-area devices. However, most studies on solution-processed OLEDs have mainly focused on solution-processable hole transporting materials or emissive materials. Here, we report fully solution-processed green OLEDs including hole/electron transport layers and emissive layers. The electrical and optical properties of OLEDs based on solution-processed TPBi (2,2′,2″-(1,3,5-Benzinetriyl)-tris(1-phenyl-1-H-benzimidazole)) as the electron transport layer were investigated with respect to the spin speed and the number of layers. The performance of OLEDs with solution-processed TPBi exhibits a power efficiency of 9.4 lm/W. We believe that the solution-processed electron transport layers can contribute to the development of efficient fully solution-processed multilayered OLEDs.
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A Study on Variation of Single Color by Applied Voltage in Multi-Electrode Type Electronic Film
Sang-il Lee, Youn-chan Hong, Young-cho Kim
J Electr Electron Mater 2018;31(7):490-495.   Published online November 1, 2018
A multielectrode electronic paper film capable of expressing a single-color image was fabricated by injecting color electronic ink into an electronic paper panel; on the basis of its reflective or transparent properties, it is possible to control the expression of six single-color images and their transmittance. In this study, a single-color image was represented by driving a multielectrode electronic paper film; color coordinates were measured. The six capable single colors were yellowish pink (0.444, 0.354), white (0.355, 0.352), black (0.241, 0.241), orange (0.514, 0.360), reddish orange (0.606, 0.338), and reddish purple (0.469, 0.145). Color particles used in this paper were black and white, by which six colors are accomplished, but more single-color images can be combined by using cyan, magenta, and yellow particles.
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Electrical and Mechanical Strength Properties of Epoxy/Micro Silica and Alumina Composites for Power Equipment
Joo-eon Park, Jae-jun Park
J Electr Electron Mater 2018;31(7):496-501.   Published online November 1, 2018
In this study, we prepared 40, 45, 50, 55, 60, 65, and 70 wt% content composites filled in epoxy matrix for two micro silica and three micro alumina types for use as a GIS heavy electric machine. As a filler type of epoxy composite, micro silica composites showed excellent AC breakdown strength properties compared to micro alumina composites in the case of electrical properties of micro silica and alumina. The electrical breakdown properties of micro silica composites increased with increasing filler content, whereas those of micro alumina decreased with increasing filler content. In the case of mechanical properties, the micro silica composite showed improved tensile strength and flexural strength compared with the micro alumina composite. In addition, mechanical properties such as tensile strength and flexural strength of micro silica and alumina composites decreased with increasing filler content. This is probably because O-H groups are present on the surface of silica in the case of micro silica but are not present on the surface of alumina in the case of micro alumina.
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Epitaxial Growth of ZnO Nanowires on Sapphire (001) Substrates Using a Hydrothermal Process
Daseul Ham, Byeong Eon Jeong, Myeong Hun Yang, Jong Kwan Lee, Young Bin Choi, Hyon Chol Kang
J Electr Electron Mater 2018;31(7):502-509.   Published online November 1, 2018
Epitaxial ZnO nanowires (NWs) were synthesized on sapphire (001) substrates using a hydrothermal process. The effects of the pH value of the precursor solution on the structural and optical properties of the resulting NWs was studied. The epitaxial relationship and the domain matching configuration between the sapphire (001) substrate and the as-grown ZnO NWs were determined using synchrotron X-ray diffraction measurements. The (002) plane of wurtzite ZnO NW grows in the surface normal direction parallel to the sapphire (001) direction. However, three types of in-plane domain matching configurations were observed, such as the on-position, 30°-rotated position, and ±8.5°-rotated position relative to the on-position, which might be attributed to inheriting the in-plane domain configuration of the ZnO seed layer.
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Structural Stability for Pt Line and Cross-Bar Sub-Micron Patterns
Tae Wan Park, Woon Ik Park
J Electr Electron Mater 2018;31(7):510-514.   Published online November 1, 2018
This study discusses and demonstrates the structural stability of highly ordered Pt patterns formed on a transparent and flexible substrate through the process of nanotransfer printing (nTP). Bending tests comprising approximately 1,000 cycles were conducted for observing Pt line patterns with a width of 1 μm formed along the direction of the horizontal (x-axis) and vertical (y-axis) axes (15 mm × 15 mm); and adhesion tests were performed with an ultrasonicator for a period greater than ten minutes, to analyze the Pt crossbar patterns. The durability of both types of patterns was systematically analyzed by employing various microscopes. The results show that the Pt line and Pt crossbar patterns obtained through nTP are structurally stable and do not exhibit any cracks, breaks, or damages. These results corroborate that nTP is a promising nanotechnology that can be applied to flexible electronic devices. Furthermore, the multiple patterns obtained through nTP can improve the working performance of flexible devices by providing excellent structural stability.
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Detection Algorithm and Extract of Deviation Parameters for Battery Pack Based on Internal Resistance Aging
Jung-yong Song, Chang-su Huh
J Electr Electron Mater 2018;31(7):515-520.   Published online November 1, 2018
A large number of lithium-ion batteries are arranged in series and parallel in battery packs, such as those in electric vehicles or energy storage systems. As battery packs age, their output power and energy density drop because of voltage deviation, constant and non-uniform exposure to abnormal environments, and increased contact resistance between batteries; this reduces application system efficiency. Despite the balancing circuit and logic of the battery management system, the output of the battery pack is concentrated in the most severely aged unit cell and the output is frequently limited by power derating. In this study, we implemented a cell imbalance detection algorithm and selected parameters to detect a sudden decrease in battery pack output. In addition, we propose a method to increase efficiency by applying the measured testing values considering the operating conditions and abnormal conditions of the battery pack.
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The Detection Characterization of NOX Gas Using the MWCNT/ZnO Composite Film Gas Sensors by Heat Treatment
Hyun-soo Kim, Kyung-uk Jang
J Electr Electron Mater 2018;31(7):521-526.   Published online November 1, 2018
In particular, gas sensors require characteristics such as high speed, sensitivity, and selectivity. In this study, we fabricated a NOX gas sensor by using a multi-walled carbon nanotube (MWCNT)/zinc oxide (ZnO) composite film. The fabricated MWCNT/ZnO gas sensor was then treated by a 450℃ temperature process to increase its detection sensitivity for NOx gas. We compared the detection characteristics of a ZnO film gas sensor, MWCNT film gas sensor, and the MWCNT/ZnO composited film gas sensor with and without the heat-treatment process. The fabricated gas sensors were used to detect NOX gas at different concentrations. The gas sensor absorbed NOX gas molecules, exhibiting increased sensitivity. The sensitivity of the gas sensor was increased by increasing the gas concentration. Additionally, while changing the temperature inside the chamber for the MWCNT/ZnO composite film gas sensor, we obtained its sensitivity for detecting NOX gas. Compared with ZnO, the MWCNT film gas sensor is excellent for detecting NOX gas. From the experimental results, we confirmed the enhanced gas sensor sensing mechanism. The increased effect by electronic interaction between the MWCNT and ZnO films contributes to the improved sensor performance.
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