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"Diodes"

Research Trends on the Hole Transport Layer Interface in Blue Perovskite Light-Emitting Diodes
Seungmin Baek, Donghwan Yun, Gwang Yong Shin, Youngchae Cho, Hyeseon Shin, Mihyun Kim, Harin Kim, Gi-hwan Kim
J Electr Electron Mater 2025;38(6):629-637.   Published online November 1, 2025
DOI: https://doi.org/10.4313/JEEM.2025.38.6.4
Perovskite light-emitting diodes (PELEDs) are emerging as promising candidates for next-generation displays, thanks to their narrow full width at half maximum and low-cost solution processing capabilities. Blue PeLEDs are essential for achieving a full-color gamut; however, efficiency and stability challenges limit their practical use. A primary bottleneck arises from interfacial issues between the perovskite emissive and charge transport layers. This review summarizes the key interfacial challenges hindering the performance of blue PeLEDs and highlights recent advances in interfacial engineering strategies. By focusing on interfacial engineering between the hole-transport layer and perovskite, this review compares different strategies and outlines future directions for developing high-performance blue light-emitting devices.
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Recent Advances in Charge Generation Layer Design for Tandem Quantum Dot Light-Emitting Diodes
Eui Chang Jung, Moon Kee Choi
J Electr Electron Mater 2025;38(6):593-603.   Published online November 1, 2025
DOI: https://doi.org/10.4313/JEEM.2025.38.6.1
Quantum dots (QDs) offer size-dependent tunability across the infrared to ultraviolet range with narrow emission linewidths and high color purity, making them highly attractive for next-generation light-emitting devices. Quantum dot lightemitting diodes (QLEDs) further combine precise spectral control with scalable, low-cost solution processing, positioning them as strong candidates for wearable, stretchable, and AR/VR display technologies. However, conventional single-emission QLEDs suffer from charge imbalance, efficiency roll-off, and limited operational lifetime, necessitating new device architectures. Tandem QLEDs, which vertically stack multiple emissive layers (EMLs) connected by charge generation layers (CGLs), provide a compelling solution by enabling higher luminance, improved charge balance, and longer lifetime at equivalent current density. The CGL serves as the interfacial region mediating charge injection and generation between adjacent EMLs, directly determining device efficiency and stability. This review highlights recent progress in CGL engineering, categorizing representative designs into planar heterojunction, inorganic-based, and dipole-based configurations. Comparative analysis of their formation mechanisms, material systems, and process compatibilities reveals evolving charge-control strategies that extend beyond material selection. These insights establish design principles for next-generation tandem QLEDs with enhanced efficiency, durability, and manufacturability.
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Thermal Management Impact of Heat Conductive Layers on Ga₂O₃ Schottky Barrier Diodes
Ye-jin Kim, Geon-hee Lee, Min-yeong Kim, Se-rim Park, Seung-hwan Chung, Sang-mo Koo
J Electr Electron Mater 2024;37(6):657-661.   Published online November 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.6.12
Gallium oxide (Ga₂O₃) is emerging as a next-generation power semiconductor material due to its excellent electrical properties, including an ultra-wide bandgap of approximately 4.8 eV and a breakdown electric field of about 7 MV/cm. However, its low thermal conductivity of around 0.13 W/cmK presents significant challenges to the performance and reliability of Ga₂O₃- based devices. In this study, we employed the Silvaco TCAD simulator to analyze the thermal and electrical characteristics of Ga₂O₃ Schottky barrier diodes (SBDs) with heat sinks of varying thermal conductivities. The results demonstrate that heat sinks with higher thermal conductivity effectively mitigate the temperature rise in the device, leading to an increase in current density. The limitation in heat dissipation due to parasitic on-state resistance not only affects device performance but also impacts longterm reliability. Therefore, this study contributes to the development of effective thermal management strategies for Ga₂O₃-based power semiconductors.
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Micro Light-Emitting Diodes with 3D-Printed Hydrogel Microlens for Optical Property Enhancements
Yujin Ko, Jeong Hyeon Kim, Sang Yoon Park, Kang Hyeon Kim, Seong Min Hong, Bo-yeon Lee, Han Eol Lee
J Electr Electron Mater 2024;37(5):554-561.   Published online September 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.5.13
Micro light-emitting diodes (μLEDs) have been utilized in various fields such as displays, and smart devices, due to their superior stabilities. Since the applications of the μLEDs have been extended to medical devices and wearable sensors, excellent optical properties and uniformity of the μLEDs are important. Hence, several researchers have investigated to enhance the optical efficiency of the μLEDs through micro/nano lens. However, the reported methods for realizing the micro/nano lens have some drawbacks such as complex and high-cost manufacturing processes. Herein, we developed μLEDs with 3D-printed hydrogel microlenses. The printed hydrogel had high transparency and excellent adhesive strength, allowing it to attach onto top surface of the μLEDs without any additional adhesives. Microscale printing technology using a 3D printer achieved quick and fine printing in desired shapes and arrangements, showing the possibility of mass production. The 3D-printed microlens can be applied to improve not only the optical properties of μLEDs but also other optical devices.
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Advances in Intrinsically Stretchable Light-Emitting Diodes
Wonjin Koh, Moon Kee Choi
J Electr Electron Mater 2023;36(6):537-546.   Published online November 1, 2023
DOI: https://doi.org/10.4313/JKEM.2023.36.6.1
Intrinsically stretchable light-emitting diodes, composed of stretchable electrodes, charge transport layers, and luminescent materials, have garnered significant interest for enhancing human well-being and advancing the field of deformable electronics. Various luminescent materials, such as perovskites and organics, have been integrated with stretchable elastomers to function as the stretchable emissive layers in these intrinsically stretchable LEDs. Stretchable conductors including Ag nanowire based percolating structures and conducting polymers have been utilized as stretchable transparent electrode. Despite this progress, their performances in terms of efficiency and stability remain challenging compared to their structurally stretchable and rigid LED counterparts. This review offers a comprehensive overview of recent advancements in intrinsically stretchable LEDs, focusing on material innovations.
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Vertical β-Ga2O3 Schottky Barrier Diodes with High-κ Dielectric Field Plate
Se-rim Park, Tae-hee Lee, Hui-cheol Kim, Min-yeong Kim, Soo-young Moon, Hee-jae Lee, Dong-wook Byun, Geon-hee Lee, Sang-mo Koo
J Electr Electron Mater 2023;36(3):298-302.   Published online May 1, 2023
DOI: https://doi.org/10.4313/JKEM.2023.36.3.14
In this paper, we discussed the effect of field plate dielectric materials such as silicon dioxide (SiO2), aluminum oxide (Al2O3), and hafnium oxide (HfO2) on the breakdown characteristics of β-Ga2O3 Schottky barrier diodes (SBDs). The breakdown voltage (BV) of the SBDs with a field plate was higher than that of SBDs without a field plate. The higher dielectric constant of HfO2 contributed to the superior reduction in electric field concentration at the Schottky junction edge from 5.4 to 2.4 MV/cm. The SBDs with HfO2 field plate showed the highest BV of 720 V, and constant specific on-resistance (Ron,sp) of 5.6 mΩ·㎠, resulting in the highest Baliga’s figure-of-merit (BFOM) of 92.0 MW/㎠. We also investigated the effect of dielectric thickness and field plate length on BV.
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Characteristics of Ga2O3/4H-SiC Heterojunction Diode with Annealing Process
Young-jae Lee, Sang-mo Koo
J Electr Electron Mater 2020;33(2):155-160.   Published online March 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.2.15
Ga2O3/n-type 4H-SiC heterojunction diodes were fabricated by RF magnetron sputtering. The optical properties of Ga2O3 and electrical properties of diodes were investigated. I-V characteristics were compared with simulation data from the Atlas software. The band gap of Ga2O3 was changed from 5.01 eV to 4.88 eV through oxygen annealing. The doping concentration of Ga2O3 was extracted from C-V characteristics. The annealed oxygen exhibited twice higher doping concentration. The annealed diodes showed improved turn-on voltage (0.99 V) and lower leakage current (3 pA). Furthermore, the oxygen-annealed diodes exhibited a temperature cross-point when temperature increased, and its ideality factor was lower than that of as-grown diodes.
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Quantum Dot Light-Emitting Diodes with Poly-TPD/PVK Bilayer Hole Transport Layer
Hyun Soo Kim, Do Hyung Lee, Bada Kim, Bo Ram Hwang, Chang Kyo Kim
J Electr Electron Mater 2019;32(5):393-398.   Published online September 1, 2019
A poly[bis(4-butypheny)-bis(phenyl)benzidine] (poly-TPD) and poly(9-vinylcarbazole) (PVK) bilayer was employed as a hole transport layer (HTL) in solution-processed CdSe/ZnS quantum dot light-emitting diodes (QLEDs). The thickness of the PVK layer spin-coated onto the poly-TPD layer, whose thickness was fixed to 40 nm, was varied, with PVK layer thicknesses of 0 nm, 35 nm, 45 nm, and 55 nm. Because the thickness of the PVK can determine the hole transport properties of the HTL, a PVK thickness that maximizes the performance of the HTL for the QLEDs was investigated. By employing the optimized PVK thickness of 45 nm, the current efficiency of the QLED exhibited a 1.74 times improvement when compared with that of the QLED with poly-TPD based HTL without PVK. This was mainly attributed to the decrease in the energy barrier between the HTL and the quantum dot (QD) emitting layer (EML).
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Fully Solution-Processed Green Organic Light-Emitting Diodes Using the Optimized Electron Transport Layers
Joo Won Han, Yong Hyun Kim
J Electr Electron Mater 2018;31(7):486-489.   Published online November 1, 2018
Solution-processed organic light-emitting diodes (OLEDs) have the advantages of low cost, fast fabrication, and large-area devices. However, most studies on solution-processed OLEDs have mainly focused on solution-processable hole transporting materials or emissive materials. Here, we report fully solution-processed green OLEDs including hole/electron transport layers and emissive layers. The electrical and optical properties of OLEDs based on solution-processed TPBi (2,2′,2″-(1,3,5-Benzinetriyl)-tris(1-phenyl-1-H-benzimidazole)) as the electron transport layer were investigated with respect to the spin speed and the number of layers. The performance of OLEDs with solution-processed TPBi exhibits a power efficiency of 9.4 lm/W. We believe that the solution-processed electron transport layers can contribute to the development of efficient fully solution-processed multilayered OLEDs.
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Enhancement of Electrical Properties of Organic Light-Emitting Diodes Using F4-TCNQ Molecule as a Hole-Transport Layer
Su Hwan Na, Won Jae Lee
J Electr Electron Mater 2017;30(11):717-721.   Published online November 1, 2017
We studied the performance enhancement of organic light-emitting diodes (OLEDs) using 2,3,5,6-fluoro-7,7,8,8-tetracyanoquinodimethane (F4-TCNQ) as the hole-transport layer. To investigate how F4-TCNQ affects the device performance, we fabricated a reference device in an ITO (170 nm)/TPD(40 nm)/Alq3(60 nm)/LiF(0.5 nm)/Al(100 nm) structure. Several types of test devices were manufactured by either doping the F4-TCNQ in the TPD layer or forming a separate F4-TCNQ layer between the ITO anode and TPD layer. N,N'-diphenyl-N,N'-di(m-tolyl)-benzidine (TPD), tri(8-hydroxyquinoline) aluminum (Alq3), and F4-TCNQ layers were formed by thermal evaporation at a pressure of 10-6 torr. The deposition rate was 1.0-1.5 Å/s for TPD and Alq3. The LiF was subsequently thermally evaporated at a deposition rate of 0.2 Å/s. The performance of the OLEDs was considered with respect to the turn-on voltage, luminance, and current efficiency. It was found that the use of F4-TCNQ in OLEDs enhances the performance of the device. In particular, the use of a separate layer of F4-TCNQ realizes better device performance than other types of OLEDs.
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Silver Nanowire-Based Stretchable Transparent Electrodes for Deformable Organic Light-Emitting Diodes
Hyunsu Jung, Hyeck Go, Gye-choon Park, Changhun Yun
J Electr Electron Mater 2017;30(10):609-614.   Published online October 1, 2017
The proposed stretchable transparent electrodes based on silver nanowires (AgNWs) were prepared on a polyurethane (PU) substrate. In order toavoid the surface roughness caused by the silver nanowires, a titanium oxide (TiO2) buffer layer was addedby coating and heating the organometallic sol-gel solution. The fabricated stretchable electrodes showedan electrical sheet resistance of 24 Ωsq-1, 78% transmittance at 550 nm, and an average surface roughness below 5 nm. Furthermore, the AgNW-based electrode maintained its initial electrical resistance under 130% strain testing conditions, without the assistance of additional conductive polymer layers. In this paper, the critical role of the TiO2 buffer layer between the AgNW network and the PU substrate has been discussed.
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Light Source and Application Technology : Design and Fabrication of Heat Sink for Vehicle LED Headlamp Using Thermally-Conductive Plastics
Hyeong Jin Kim, Dong Kyu Lee, Hyun Jung Park, Hoe Seok Yang, Pil Sun Na, Joon Seop Kwak
J Electr Electron Mater 2015;28(8):544-549.   Published online August 1, 2015
Since LEDs (light emitting diodes) have many advantages as a light source in vehicle headlamp, such as good reliability, energy and space saving, and flexible headlamp design. On the other hand, the dependence of its performance and life on temperature have great influence on its practical use. In this study, design and fabrication of heat sink for vehicle LED headlamp were performed using thermally-conductive plastics. This study focused on the effective heat sink structure with limited space in the vehicle LED headlamp. We designed two different prototype of heat sink by thermal simulation using SolidWorks program, which had excellent temperature characteristics. The two different prototype of heat sink were fabricated by injection molding with thermally-conductive plastics. The results showed that LED Tj (junction temperature) of sample B (model 1) and sample C (model 1, 2) was below then 165℃ when applying the thermally-conductive plastics in heat sink of vehicle LED headlamp.
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A Study on the Improvement of Light-Extraction Efficiency of Organic Light-Emitting Diodes with a Use of Random-Textured Film
Hye Sook Kim, Deok Hyeon Hwang, Kyeong Uk Jang, Tae Wan Kim
J Electr Electron Mater 2015;28(7):446-449.   Published online July 1, 2015
An improvement of light-extraction efficiency of organic light-emitting diodes was studied by using random-textured films (RTF). Device was made in a structure of RTF/glass/ITO/TPD/Alq3/LiF/Al. RTF mold was made by spreading PDMS solution on a sandpaper. By pressing this mold on the glass substrate pre-coated with ZPU material, the RTF was obtained. From this study, there was an improvement of external quantum efficiency by about 30% in the device with the random-textured film (RTF 40) compared to that of the reference one.
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Light Source and Application Technology : An Efficiency Improvement of the OLEDs due to the Thickness Variation on Hole-Iniection Materials
Jong Yeol Shin, Yi Wei Guo, Tae Wan Kim, Jin Woong Hong
J Electr Electron Mater 2015;28(5):344-349.   Published online May 1, 2015
A new information society of late has arrived by the rapid development of various information & communications technologies. Accordingly, mobile devices which are light and thin, easy and convenient to carry on the market. Also, the requirements for the larger television sets such as fast response speed, low-cost electric power, wider visual angle display are sufficiently satisfied. The currently most widely studied display material, the Organic Light-emitting Diodes(OLEDs) overwhelms the Liquid Crystal Display(LCD), the main occupier of the market. This new material features a response speed of more than a thousand times faster, no need of backlight, a low driving voltage, and no limit of view angle. And the OLEDs has high luminance efficiency and excellent durability and environment resistance, quite different from the inorganic LED light source. The OLEDs with simple device structure and easy produce can be manufactured in various shapes such as a point light source, a linear light source, a surface light source. This will surely dominate the market for the next generation lighting and display device. The new display utilizes not the glass substrate but the plastic one, resulting in the thin and flexible substrate that can be curved and flattened out as needed. In this paper, OLEDs device was produced by changing thickness of Teflon-AF of hole injection material layer. And as for the electrical properties, the four layer device of ITO/TPD/Alq3/BCP/LiF/Al and the five layer device of ITO/Teflon AF/TPD/Alq3/BCP/Lif/Al were studied experimentally.
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Light Source and Application Technology : A Study on a Novel LED Lighting Fixture for Crosswalk Having Two Different Light Distributions
Hyeong Jin Kim, Dong Kyu Lee, Joon Seop Kwak
J Electr Electron Mater 2014;27(9):606-611.   Published online September 1, 2014
Recently, LED lighting fixtures for crosswalk become popular in order to recognize the pedestrians at crosswalk, which can enhance the safety of the pedestrian at crosswalk. However, there are several problems related to the LED lighting fixtures for crosswalk, such as a lot of energy consumption due to a constant illumination during night and glaring of pedestrians at the opposite side of crosswalk. In this study, in order to overcome these problems, we have investigated a novel LED lighting fixture for crosswalk, which has two modules with different angles (60°, 120°). Illuminance of min and max at four-line city street crosswalk shown 50 Lux, 125 Lux, respectively. Illuminance of min and max at eight-line city street crosswalk shown 150 Lux, 200 Lux, respectively. Simulation investigation was optimized design using optical program. Prototype was verified measurement by goniometer system.
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Simulation of Microlens Array for the Improvement of Outcoupled Efficiency of Organic Light-emitting Diodes
Deok Hyeon Hwang, Hye Sook Kim, Won Jae Lee, Seung Hun Lee, Tae Ho Lee
J Electr Electron Mater 2013;26(10):745-753.   Published online October 1, 2013
Performance of organic light-emitting diodes incorporating microlens array was simulated using a Light Tools software. Use of microlens array can help the light to escape out of the device. We simulated a reference device that is consisted of reflection layer, emissive layer, and flat transparent substrate. And in this reference device, outcoupled efficiency of 22% was obtained. Several shapes of microlens were applied such as hemisphere, trapezoid, cone, and rectangular parallelepiped. The results showed the improvement of outcoupled efficiency of the device with microlens compared to that of the reference one. And from the analyses of the simulated data, the obtained appropriate shape of microlens is hemisphere, and the improvement of the device with hemispherical lens is 57% higher than that of the reference one.
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Optimization of Electrical/Optical Properties of ITO/Al Based Reflector for Vertical-type UV LEDs via SF6 Plasma Treatments
Ki Seob Shin, Dong Yoon Kim, Tae Geun Kim
J Electr Electron Mater 2011;24(11):911-914.   Published online November 1, 2011
We optimize electrical and optical properties of thermal and SF6 plasma treated indium tin oxide (ITO)/Al based reflector for high-power ultraviolet (UV) light-emitting diodes (LEDs). After thermal and SF6 plasma treatments of ITO/Al reflector, the specific contact resistance decreased from 1.04×10(-3) Ω·cm2 to 9.12×10(-4) Ω·cm2, while the reflectance increased from 58% to 70% at the 365 nm wavelength. The low resistance and high reflectance of ITO/Al reflector are attributed to the reduced Schottky barrier height (SBH) between the ITO and AlGaN by large electronegativity of fluorine species and reduced interface roughness between the ITO and Al, respectively.
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Effect on the Electrical Characteristics of OLEDs Depending on Amorphous Fluoropolymer
Sang Min Shim, Hyun Suk Han, Yong Gil Kang, Weon Jong Kim, Jin Woong Hong
J Electr Electron Mater 2011;24(9):750-754.   Published online September 1, 2011
In this research, the electric characteristic of organic light-emitting diodes(OLEDs) was studied depending on thickness of amorphous fluoropolymer(Teflon-AF) which is the material of hole injection layer to improve electric characteristic of OLEDs. Sample composition was fabricated in double layer. The basic structure was fabricated by ITO/tris(8-hydroxyquinoline) aluminum (Alq3)/Al and the 2 layer was fabricated by ITO/2,2-Bistrifluoromethyl-4,5-Difluoro-1,3-Dioxole(Teflon-AF)/tris(8-hydro xyquinoline) aluminum (Alq3)/Al. The experiment was carried with variation of thickness of Teflon-AF at 1.0, 2.0, 2.5, 3.0 nm. The result showed when Teflon-AF thickness was 2.5 nm, the electric and optical characteristic were well performed. Moreover, when it was compared with Teflon-AF without materials, it was improved 15.1 times more on luminance, 12.7 times more on luminous efficiency and 12.1 times more on external quantum efficiency. Therefore, OLEDs element with optimum hole injection layer reduced energy barrier and driving voltage, and confirmed that it improved efficiency widely.
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Regular Paper : Analysis of Thermal Stability and Schottky Barrier Height of Pd Germanide on N-type Ge-on-Si Substrate
Se Kyung Oh, Hong Sik Shin, Min Ho Kang, Jeong Deuk Bok, Yi Jung Jung, Hyuk Min Kwon, Ga Won Lee, Hi Deok Lee
J Electr Electron Mater 2011;24(4):271-275.   Published online April 1, 2011
In this paper, thermal stability of palladium germanide (Pd germanide) is analyzed for high performance Schottky barrier germanium metal oxide semiconductor field effect transistors (SB Ge-MOSFETs). Pd germanide Schottky barrier diodes were fabricated on n-type Ge-on-Si substrates and the formed Pd germanide shows thermal immunity up to 450℃. The barrier height of Pd germanide is also characterized using two methods. It is shown that Pd germanide contact has electron Schottky barrier height of 0.569∼0.631 eV and work function of 4.699∼4.761 eV, respectively. Pd germanide is promising for the nanoscale Schottky barrier Ge channel MOSFETs.
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Electrical Properties of Organic Light-emitting Diodes Using TCNQ Molecules
Su Hwan Na, Tae Wan Kim
J Electr Electron Mater 2010;23(11):896-900.   Published online November 1, 2010
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Display and Optical Devices : Efficient Top-Emitting Organic Light Emitting Diode with Surface Modified Silver Anode
Sung Jun Kim, Ki Hyon Hong, Ki Soo Kim, Ill Hwan Lee, Jong Lam Lee
J Electr Electron Mater 2010;23(7):550-553.   Published online July 1, 2010
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Electrical and Optical Properties of Semitransparent Metal Electrodes for Top-emission Organic Light-emitting Diodes
Eun Chul Shin, Hui Chul An, Tae Wan Kim
J Electr Electron Mater 2008;21(10):938-942.   Published online October 1, 2008
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Built-in Voltage in Organic Light-emitting Diodes depending on the Alq3 Layer Thickness
Eun Hye Lee, Hee Myoung Yoon, Tae Wan Kim
J Electr Electron Mater 2008;21(3):255-259.   Published online March 1, 2008
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Electrical and Optical Properties of Top Emission OLEDs with Ba/Ag Transparent Cathodes
J Electr Electron Mater 2006;19(9):873-877.   Published online September 1, 2006
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Dielectric Properties depending on Bias Voltage in Organic Light-emitting Diodes
J Electr Electron Mater 2005;18(11):1038-1042.   Published online November 1, 2005
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Effects of Hole-Injection Buffer Layer in Organic Light-Emitting Diodes
Dong Hoe Jeong, Sang Geol Kim, Hyeon Seog O, Jin Ung Hong, Jun Ung Lee, Yeong Sig Kim, Tae Wan Kim
J Electr Electron Mater 2003;16(9):816-825.   Published online September 1, 2003
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Display : Electrical Properties and Luminous Efficiency in Organic Light-Emitting Diodes Depending on Buffer Layer and Cathodes
Dong Hoe Chung, Sang Keol Kim, Jin Woong Hong, Joon Ung Lee, Tae Wan Kim
J Electr Electron Mater 2003;16(5):409-417.   Published online May 1, 2003
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