Smart windows are used as windows and doors to determine the cooling and heating efficiency of a building. They have characteristics that can increase the energy efficiency of a building, which leads to energy savings. In addition, smart windows can control the amount of light transmitted from the external environment of a building to the interior of a building according to the needs of the user. In this study, a 297×210 mm² liquid crystal cell capable of controlling light transmittance was fabricated using a liquid crystal device as an optical shutter. The effect of driving voltage on the transmittance and the effect of the thermal environment on the driving stability were analyzed. We confirmed the applicability of using smart windows as exterior building materials.