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"LTCC (low temperature co-fired ceramics)"

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"LTCC (low temperature co-fired ceramics)"

Microwave Dielectric Properties of Ca[(Li1/3Nb2/3)0.2Ti0.8]O3-δ Ceramics with Addition of Zn-B-O Glass Systems
Chi-seung In, Shi Yeon Kim, Dong-hun Yeo, Hyo-soon Shin, Sahn Nahm
J Electr Electron Mater 2016;29(12):781-785.   Published online December 1, 2016
With trend of the miniaturization and the high-functionalizing of mobile communication system, low-loss microwave dielectric materials are widely used for high frequency communication components. These dielectric materials should be co-sintered with highly electric-conducting metal such as silver or copper for high-frequency and thick film process application. Sintering temperature of Ca[(Li1/3Nb2/3)1-xTix]O3-δ, which has excellent dielectric properties such as εr above 40, quality factor (Q·f0) above 16,000 GHz, and TCF (temperature coefficient of resonant frequency) of -20~-10 ppm/℃, is reported as high as 1,175℃, so it could not be co-sintered with silver or copper. Therefore in this study, low-temperature melting glasses of Zn-B-O and Zn-B-Si-O systems were added to Ca[(Li1/3Nb2/3)1-xTix]O3-δ to lower its sintering temperature under 900℃ without losing excellency of dielectric properties. With 15 weight % of Zn-B-Si-O glass and sintered at 875℃, specimen showed density of 4.11 g/cm3r of 40.1, Q·f0 of 4,869 GHz, and TCF of -5.9 ppm/℃. With 15 weight % of Zn-B-O glass and sintered at 87 5℃, specimen showed density of 4.14 g/cm3, εr of 40.4, Q·f0 of 7,059 GHz, and TCF of -0.92 ppm/℃.
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