This study developed a dielectric composition for high-capacitance MLCCs with C0G and U2J temperature compensation characteristics (Class I) under reducing conditions. The potential application of this composition in highpermittivity class I MLCCs was examined. Using (Ba₀.₂₄Ca₀.₁₆Sr₀.₆)(TiₓZr₁₋ₓ)O₃. XRD analysis showed that secondary phases like Sr₂TiO₄ and TiO₂ formed at higher Ti content, affecting the stoichiometric balance. Adjusting the Ti/Zr molar ratio resulted in a dielectric constant of 41.2 ~ 105, a dielectric loss of 0.082 ~ 0.174%, and insulation resistance above 1.6 × 1013 ohms at 25℃. The TCC shifted from C0G to U2J as the Ti/Zr ratio increased, but the composition enabled the design of high-capacitance and high-voltage MLCCs with favorable dielectric and electrical properties.
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High-throughput ceramics processing method using cellulose nanofiber dispersions for rapid materials exploration Sou Yasuhara, Yosuke Sugita, Masaki Tozuka, Takuya Hoshina Journal of Materials Chemistry C.2026; 14(31): 14136. CrossRef
Thermally stimulated depolarization current study of acceptor-doped zirconate-based perovskites Rena Isowaki, Masaya Kawaguchi, Keisuke Kishi, Toshiki Okazaki, Maiko Nagayoshi, Kiyoshi Matsubara, Takao Sada Japanese Journal of Applied Physics.2026; 65(15): 151003. CrossRef
In this study, the electrical properties of a C0G (class 1 ceramic) dielectric composition with internal reducibility, specifically (Ba0.27CaSr)(Zr0.95Ti0.05)O₃, were investigated by fixing Ba at the A site and varying the Ca/Sr molar ratio. The potential application of this composition in high-permittivity C0G MLCCs was examined. The powder was calcined at 1,150℃ for 2 hours, as determined by TG-DTA analysis, and the resulting powder was ground to achieve a particle size (D50) of 0.35 to 0.4 μm and a specific surface area (BET) of 4.5 to 5.0 g/m². With a Ca/Sr molar ratio of 0.3, the composition (Ba0.27Ca0.17Sr0.56) (Zr0.95Ti0.05)O₃ exhibited electrical properties with a permittivity of 41.9, a loss of less than 0.008%, and an insulation resistance exceeding 2.2×10¹³ Ω. The feasibility of using this composition for high-capacitance C0G MLCCs was confirmed.
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Thermally stimulated depolarization current study of acceptor-doped zirconate-based perovskites Rena Isowaki, Masaya Kawaguchi, Keisuke Kishi, Toshiki Okazaki, Maiko Nagayoshi, Kiyoshi Matsubara, Takao Sada Japanese Journal of Applied Physics.2026; 65(15): 151003. CrossRef
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