We investigated dielectric relaxation properties of 0.95(Na0.5K0.5)NbO3-0.05BaTiO3 ceramics byaddition (0∼0.3 wt%) of (Ba,Ca)SiO3 glass frit. All composition of 0.95(Na0.5K0.5)NbO3-0.05BaTiO3 added(Ba,Ca)SiO3 glass frit showed the same crystallographic properties, coexistence of orthorhombic andtetragonal phase. By increasing addition of (Ba,Ca)SiO3 glass frit, the Curie temperatures of0.95(Na0.5K0.5)NbO3-0.05BaTiO3 ceramics were decreased, whereas maximum dielectric constants of0.95(Na0.5K0.5)NbO3-0.05BaTiO3 ceramics were dramatically increased. Especially the deviations of Curietemperature 0.95(Na0.5K0.5)NbO3-0.05BaTiO3 ceramics were increased by increasing amount of(Ba,Ca)SiO3 glass frit, and it indicated that 0.95(Na0.5K0.5)NbO3-0.05BaTiO3 ceramics added (Ba,Ca)SiO3glass frit have relaxor characteristics.