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"Palladium"

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"Palladium"

Durability and Characteristics of Ag-Pd Rod Heater for Bidet Fabricated by Screen Printing Process
Tae-ung Park, Da-eun Hyun, Ik-soo Kim, Sung-chul Lee, Yeon-sook Lee, Yong-nam Kim, Dong-won Lee, Jong-min Oh
J Electr Electron Mater 2023;36(1):81-87.   Published online January 1, 2023
DOI: https://doi.org/10.4313/JKEM.2023.36.1.13
Heaters using the resistance heating principle are used in various industrial fields that require heat and are also essentially used in bidet among small home appliances. A planar heater and a coil-inserted heater mounted on a conventional commercially used bidet have disadvantages and limitations of complicated manufacturing process and local heating. In this study, silver-palladium (Ag-Pd) powder material was used for a screen-printing process that is more advantageous in achieving simplification than the existing process, and a rod-type heater for bidet was manufactured. The on-off cycle test under actual conditions was conducted to confirm the durability and the capability of the fabricated heater, and the fabricated heater operated more than 2,600 on-off cycles, which means it could be applied for a commercial product. In addition, through the on-off cycles under harsh conditions, the cause of failure was identified after the test that the durability limit temperature of the heater was 850℃. Through Ag-Pd rod heater in this study, it is expected to contribute to the efficient development of electrode materials for heaters and the improvement of the durability of heaters in the future.
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Self-Regeneration of Intelligent Perovskite Oxide Anode for Direct Hydrocarbon-Type SOFC by Nano Metal Particles of Pd Segregated
Mi Young Oh, Tatsumi Ishihara, Tae Ho Shin
J Electr Electron Mater 2018;31(5):345-350.   Published online July 1, 2018
Nanomaterials have considerable potential to solve several key challenges in various electrochemical devices, such as fuel cells. However, the use of nanoparticles in high-temperature devices like solid-oxide fuel cells (SOFCs) is considered problematic because the nanostructured surface typically prepared by deposition techniques may easily coarsen and thus deactivate, especially when used in high-temperature redox conditions. Herein we report the synthesis of a self-regenerated Pd metal nanoparticle on the perovskite oxide anode surface for SOFCs that exhibit self-recovery from their degradation in redox cycle and CH4 fuel running. Using Pd-doped perovskite, La(Sr)Fe(Mn, Pd)O3, as an anode, fairly high maximum power densities of 0.5 and 0.2 cm-2 were achieved at 1,073 K in H2 and CH4 respectively, despite using thick electrolyte support-type cell. Long-term stability was also examined in CH4 and the redox cycle, when the anode is exposed to air. The cell with Pd-doped perovskite anode had high tolerance against re-oxidation and recovered the behavior of anodic performance from catalytic degradation. This recovery of power density can be explained by the surface segregation of Pd nanoparticles, which are self-recovered via re-oxidation and reduction. In addition, self-recovery of the anode by oxidation treatment was confirmed by X-ray diffraction (XRD) and scanning electron microscopy (SEM).
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Fabrication and Application of Palladium Coated Fiber-Optic Hydrogen Detection Sensor
Kwang Taek Kim, Sang Won Lee, Dong Geun Kim, Nu Ri Choi, Jong Ryeok Lee, Se Jong Baik
J Electr Electron Mater 2018;31(3):160-164.   Published online March 1, 2018
We have proposed a hydrogen detection sensor based on a Pd (palladium)-coated, single-mode, optical fiber. The experimental results demonstrated that the sensor could detect hydrogen in air as well as in insulation oil. The influence of Pd film thickness and environmental temperature on response time and sensitivity was analyzed. The reflected optical power at the optical-fiber/Pd interface decreased as the concentration of hydrogen increased, in both air and the insulation oil. The sensor showed 0.75 dB of optical power variation when the concentration of dissolved hydrogen was saturated in the insulation oil.
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