In recent years, the challenge of higher energy efficiency has emerged as urban buildings have become taller, and the area of window glasses has increased. To address the problem of energy efficiency in buildings, research on smart windows is being actively conducted. In this study, an accelerated experiment for thermal stability was conducted to fabricate a liquid crystal cell applicable to external windows. It was confirmed from the study that the function is maintained even in a high-temperature external environment through the change in transmittance by voltage. Compared with the initial transmittance, after the passage of time, the smart window cell to which the sealant was applied showed a small change in transmittance of 1~2%. This result confirmed the thermal stability of the liquid crystal-based smart window.