This study examined the size and shape of the nano-silver particle through the analysis of electrical resistance when synthesizing nano-sized silver by using the chemical liquid reduction. Changes in particle behaviors formed according to the changes in electronic characteristics by electric resistance in each time period in the beginning of reduction reaction in a course of synthesizing the nano-silver particle formation were studied. In addition, analysis was conducted on particle behaviors according to the changes in concentration of AgNO3 and in temperature at the time of reduction and nucleation and growth course when synthesizing the particles based on the particle behaviors were also examined. As the concentration of AgNO3 increased, the same amount of resistance of approximately 5 Ω was increased in terms of initial electronic resistance. Furthermore, according to the result of formation of nuclear growth graph and estimation of slope based on estimated resistance, slops of 6.25×10-3, 2.89×10-3, and 1.85×10-3 were derived from the concentrations of 0.01 M, 0.05 M, and 0.1 M, respectively. As the concentration of AgNO3 increased, the more it was dominantly influenced by the nuclear growth areas in the initial phase of reduction leading to increase the size and cohesion of particles. At the time of reduction of nano-silver particle, the increases of initial resistance were 4 Ω, 4.2 Ω, 5 Ω, and 5.3 Ω, respectively as the temperature increased. As the temperature was increased into 23℃, 40℃, 60℃, and 80℃, slopes were formed as 4.54×10-3, 4.65×10-3, 5.13×10-3, and 5.42×10-3 respectively. As the temperature increased, the particles became minute due to the increase of nuclear growth area in the particle in initial period of reduction.