We proposed and demonstrated a simultaneous measurement method to detect the refractive index and temperature of a medium using a side-polished fiber involving FBG (fiber Bragg grating). The temperature of a medium was obtained by using the Bragg wavelength shift of FBG, while the refractive index of medium were calculated by using the transmission loss. The Bragg wavelength is independent on the refractive index of the covering medium placed on surface of side-polished fiber, while the transmission loss at off-Bragg wavelength highly depends on the environmental temperature because of thermo-optic effect of the medium.