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J Electr Electron Mater : Journal of Electrical and Electronic Materials

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에너지재료 : PbTe 열전재료에 형성된 HgTe 나노개제물의 석출거동: 초기 격자 불일치의 형성, 이론적 계산 및 실험적 증명

김경호, 권태형, 박수한, 안형근, 이만종

Energy Materials : Precipitation Behaviors of HgTe Nanoinclusions Formed in Thermoelectric PbTe: Initial Induced Lattice Mismatch, Theoretical Calculation and Experimental Verification

Kyung Ho Kim, Tae Hyung Kwon, Su Han Park, Hyung Keun Ahn, Man Jong Lee
J Electr Electron Mater 2011;24(7):599-604.
Published online: July 1, 2011
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A highly strained nanostructure comprising crystallographically aligned HgTe nanoinclusions and a surrounding PbTe matrix has been synthesized using a precipitation process of supersaturated HgTe-PbTe alloys. From the early precipitation stage, HgTe nanoinclusions take disk shape, which is transformed from initial HgTe nuclei, although there is no lattice constant difference of the two end components at standard state. As a primary reason for the morphological transformation of the initial spherical HgTe nuclei to HgTe nanodisks, the induced lattice mismatch is suggested. On the condition that the HgTe nanodisks maintain perfect coherent nature with PbTe matrix, the stress-free lattice constant of constrained HgTe nanodisks has been calculated based on the defined concept of the strain-induced tetragonality, the linear elasticity and the actual measurement in HRTEM images.

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Energy Materials : Precipitation Behaviors of HgTe Nanoinclusions Formed in Thermoelectric PbTe: Initial Induced Lattice Mismatch, Theoretical Calculation and Experimental Verification
J Electr Electron Mater. 2011;24(7):599-604.   Published online July 1, 2011
Download Citation

Download a citation file in RIS format that can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Reference Manager.

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Energy Materials : Precipitation Behaviors of HgTe Nanoinclusions Formed in Thermoelectric PbTe: Initial Induced Lattice Mismatch, Theoretical Calculation and Experimental Verification
J Electr Electron Mater. 2011;24(7):599-604.   Published online July 1, 2011
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