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Volume 28(7); July 2015

Study on the Thin-film Transistors Based on TiO2 Active-channel Using Atomic Layer Deposition Technique
Sung Jin Kim
J Electr Electron Mater 2015;28(7):415-418.   Published online July 1, 2015
In this paper, TiO2 based thin-film transistors (TFTs) were fabricated using by an atomic layer deposition with high aspect ratio and excellent step coverage. Ti02 semiconducting layer was deposited showing a rutile phase through the rapid thermal annealing process, and exhibited TFT characteristics with a 200 pm channel length of low-leakage currents (none of current flow during off-state), stable threshold voltages (-10 V - 0 V), and a much higher on/off current ratio (
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Thermal and Dielectric Properties of LiF-Doped MgO Ceramics
Shin Kim, So Jung Kim, Kyung Jin Nam, Hansol Cha, Sang Ok Yoon
J Electr Electron Mater 2015;28(7):419-423.   Published online July 1, 2015
Sintering, microstructure, thermal conductivity and microwave dielectric properties of xLiF-(1-x)MgO ceramics (x=0.03-0.10 mol) were investigated. The high density was obtained in the specimens of x≥0.06, i.e., 0.04 LiF-0.96 MgO in mol, whereas the amount of 0.03 mol LiF was insufficient to densify. From the result that the contact flattening in the sintered specimen was observed, the densification occurred through the liquid-phase sintering. The specimen of x=0.06 showed the highest room-temperature thermal conductivity. Relative density, thermal conductivity, dielectric constant, and quality factor (Q x f) of the specimen for x=0.06 sintered at 900°C for 4 h were 97.8%, 39.2 Wm-1K-1, 9.45, and 14,671 GHz, respectively.
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Microstructure and Dielectric Properties of (Ba0.86Ca0.14)(Ti0.85Zr0.12Sn0.03)O3 Ceramics
Sang Hoon Shin, Ju Hyun Yoo, Gwang Min Lee, Dong Chan Shin
J Electr Electron Mater 2015;28(7):424-427.   Published online July 1, 2015
In this study, in order to develop the capacitor composition ceramics with the good dielectric properties, (Ba0.86Ca0.14)(Ti0.85Zr0.12Sn0.03)O3+ xCuO (x= 0.006~0.010) ceramics were prepared by the conventional solid-state reaction method. The effects of CuO addition on the microstructure and dielectric properties was investigated. All specimens indicated rhombohedra1 phase without any secondary phase. As CuO addition increased, the variation width of TCC was increased at more than 40°C. Also, the specimen with x=0.007 sintered at 1,250°C showed the high dielectric constant of 9,632 in spite of low temperature sintering temperature.
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Sintering and Microwave Dielectric Properties of Zn2-2xSi1+xO4 Ceramics
Sang Ok Yoon, Yun Han Kim, So Jung Kim, So Ra Jo, Shin Kim
J Electr Electron Mater 2015;28(7):428-432.   Published online July 1, 2015
Sintering and microwave dielectric properties of Zn2-2xSil+xO4 (x=O-0.10) ceramics were investigated. The secondary phase of ZnO was observed in the specimen for x=O whereas SiO2 was detected in that for x=0.05. The composition of Zn2SiO4 might be close to x=0.02, i.e., Zn1.96Si1.02O4; the ratio of Zn/Si is 1.922. The insufficient grain growth was observed in the specimen of x=O. For the specimens of x≥0.05 , the grain growth sufficiently occurred through the liquid phase sintering. The value of quality factor of all specimens was dependent on the x value, i.e., the ratio of Zn/Si, whereas that of dielectric constant was independent. Relative density, dielectric constant, and quality factor (Q×f) of the specimen for x=0.05, i.e., Znl.9Si1.05O4, sintered at 1,400℃ were 96.5%, 6.43, and 115,166 GHz, respectively.
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Thin Films and Sensors : Influence of Source/Drain Electrodes on the Properties of Zinc Tin Oxide Transparent Thin Film Transistors
Tae Young Ma, Mu Hee Choi
J Electr Electron Mater 2015;28(7):433-438.   Published online July 1, 2015
Zinc tin oxide transparent thin film transistors (ZTO TTFTs) were fabricated by using n`` Si wafers as gate electrodes. Indium (In), aluminum (Al), indium tin oxide (ITO), silver (Ag), and gold (Au) were employed for source and drain electrodes, and the mobility and the threshold voltage of ZTO TTFTs were observed as a function of electrode. The ZTO TTFTs adopting In as electrodes showed the highest mobility and the lowest threshold voltage. It was shown that Ag and Au are not suitable for the electrodes of ZTO TTFTs. As the results of this study, it is considered that the interface properties of electrode/ZTO are more influential in the properties of ZTO TTFTs than the conductivity of electrode.
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Droplet Size Distribution Effect on the Electro-Optical Properties of Emulsion Type Polymer Dispersed Liquid Crystal
Hee Sang Yoo, Nam Seok Oh, Yin Yan, Soon Bum Kwon
J Electr Electron Mater 2015;28(7):439-445.   Published online July 1, 2015
We established the emulsion method using membrane filter with precise control of LC droplet distribution in PDLC. PDLC cells with various LC droplet size distributions such as single droplet sizes of 1.0 μn, 1.9 μn and 3.5 μm, the mixture of two different LC droplet sizes and the mixture of three different LC droplet sizes were fabricated and the electro-optical properties of the emulsion type PDLC cells with various droplet size distribution were investigated. In the appropriate droplet size range, the PDLCs with the single droplet sizes distributions have good electro optical properties than those with the mixture of three different LC droplet sizes. In addition, the PDLC cells with the mixture of two different LC droplet sizes have the better electro optical properties than those with single droplet sizes distribution. The PDLC cell with dual droplet size distribution of 1.0+1.9 μm shown the best electro optical properties than the PDLC cells with other size distributions. This method enabled us to find the proper LC droplet size distribution for achieving both high transmittance and contrast ratio.
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A Study on the Improvement of Light-Extraction Efficiency of Organic Light-Emitting Diodes with a Use of Random-Textured Film
Hye Sook Kim, Deok Hyeon Hwang, Kyeong Uk Jang, Tae Wan Kim
J Electr Electron Mater 2015;28(7):446-449.   Published online July 1, 2015
An improvement of light-extraction efficiency of organic light-emitting diodes was studied by using random-textured films (RTF). Device was made in a structure of RTF/glass/ITO/TPD/Alq3/LiF/Al. RTF mold was made by spreading PDMS solution on a sandpaper. By pressing this mold on the glass substrate pre-coated with ZPU material, the RTF was obtained. From this study, there was an improvement of external quantum efficiency by about 30% in the device with the random-textured film (RTF 40) compared to that of the reference one.
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Development of Large-sized YBCO High Temperature Superconductor Bulk Magnets and Actuator
Sang Chul Han, Byung Jun Park, Se Yong Jung, Young Hee Han, Jong Won Lee
J Electr Electron Mater 2015;28(7):450-455.   Published online July 1, 2015
For the practical application of a YBCO superconductor bulk, the superconductor bulk magnet with high magnetic field on a large area surface should be fabricated. To make this, YBCO single crystal bulks with fine Y2BaCuO5(Y211) particles have been prepared by the top-seed melt growth(TSMG) method with YBa2Cu3Ox, Y2O3, and CeO2 mixing precursor. By using Y2O3 instead of Y2BaCuO5 as precursor, the manufacturing process became simpler and more economical. The microstructures, trapped field and critical current density of the various conditioned YBCO bulks have been observed, analyzed and measured. The different characteristic values of the several samples have been analyzed from the viewpoint of their microstructures. We have developed a 8x12 cm size superconductor bulk magnet, up to 3 T class, by using the 4 T class-high field superconducting magnetizer and confirmed the applicability of the transmission level circuit breakers by measuring the strength and speed of the superconductor bulk magnet actuator.
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In this study, the frequency properties of electrostatic capacity and dielectric loss for the samples with different types of filler has been measured in through the applied frequency range of 7 kHz -3,000 kHz at temperature of 80℃, 110℃, 140℃, 170℃. The results of this study are as follows. When the sample is degradated at the temperature of 80℃, 110℃, 140℃, 170℃ and the frequency range of 7 kHz -3,000 kHz is applied, It found that the electrostatic capacity of the sample with Polyimide film is larger than the sample with Grass fiber. It found that the dielectric loss for the sample with Polyimide film is larger than the sample with Grass fiber with increasing frequency and temperature in the 80℃, 110℃, 140℃, 170℃ range. Also, the dielectric loss decreased with increasing frequency. In case of the sample with Polyimide film, It found that the electrostatic capacity decreased with increasing temperature, and the dielectric loss gradually decreased with increasing frequency.
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In this paper, we investigated the relations between dispersion of CNTs (carbon nanotubes) and electrical conductivity in the CNT/PVDF (polyvinylidene fluoride) composite film. By adding hydrophobic CNTs as filler into the PVDF matrix, we fabricated hydrophobic and electrically conducting polymer coating film. Dispersion of CNTs in the CNT/PVDF composite film plays a significant role in terms of electrical conductivity and wetting property. Spray coating method was used to form the CNT/PVDF composite films by injecting the dispersed CNTs in the PVDF solution with different weight ratios from 0.7 wt% to 7 wt%. We investigated the electrical properties and contact angles of the CNT/PVDF composite films with the CNT concentration. Finally we discussed the conducting mechanism and feasibility of the CNT/PVDF composite film for the conducting polymer films.
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Energy Materials : Characteristics of Ceramic Separator Impregnated by Molten Salt for Thermal Batteries
Seung Ho Kang, Chae Nam Im, Byung Jun Park, Sung Baek Cho, Hae Won Cheong, Junsin Yi
J Electr Electron Mater 2015;28(7):467-472.   Published online July 1, 2015
Thermal batteries are primary power sources for military applications requiring high reliability, robustness and long storage life. Conventional electrodes for thermal batteries are prepared by compacting powder mixtures into pellets. Separator is composed of halide mixture, such as LiCl-KC1 eutectic salt, blended with MgO to immobilize the molten salt. In order to increase the power density and energy density, the resistance of electrolyte should be reduced because the resistance of electrolyte is predominant in thermal batteries. In this study, wetting behaviors and impregnation weight of molten salts as well as the micro structures of ceramic felt were investigated to be applicable to thin electrolyte. Discharge performances of single cell with the ceramic separator impregnated by molten salt were evaluated also. Zirconia felt with high porosity and large pore outperformed alumina felt in wetting characteristics and molten salt impregnation as well as discharge performances. Based on the results of this study, ceramic felt separator impregnated with molten salt have revealed as an alternative of conventional thick MgO based separator with no conspicuous sign of thermal runaway by short circuit.
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Disaster Prevention Materials : The Operation Characteristics of Hybrid Supercapacitor Module for LED Emergency Luminaires
Ju Cheul Mang, Jung Rag Yoon
J Electr Electron Mater 2015;28(7):473-479.   Published online July 1, 2015
Hybrid supercapacitors with high power density and long cycle life are widely used for emergency power source of LED emergency luminaires. In this paper, we designed and fabricated a hybrid capacitor cell and a module for the LED emergency luminaires. Using hybrid supercapacitor cells (1,000 F, 2.8 V), we designed a module in a 10-year warranty considering aging and ESR. Considering the ESR and efficiency has been designed to module with 1,000 F 5.6 V design results in 2 series and 2 parallel combination. Module was used to confirm that the operation 77.5 minutes at room temperature, discharge LED emergency luminaires with 2 W. As a LED emergency luminaires of emergency power supply that we can support more than 10 years of life was confirmed the applicability of hybrid supercapacitor.
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