With the rapid expansion of electric vehicles (EVs) and energy storage systems (ESS), ensuring the operational safety of lithium-ion batteries has become a critical technical challenge. Conventional battery management systems (BMS) primarily rely on threshold-based rule logic, which is limited in detecting coupled anomalies and early-stage degradation patterns. In this study, a deep learning-based framework for multivariate anomaly detection is proposed using BMS sensor data, including voltage, current, temperature, state of charge (SOC), and state of health (SOH). Five representative fault scenarios were defined, including thermal runaway precursors, cell voltage imbalance, SOC inconsistency, internal resistance increase, and communication delay. The proposed CNN-LSTM model was compared with conventional Rule-based methods and machine learning models, including Isolation Forest, Autoencoder, and LSTM. Experimental results show that the proposed model achieved the highest performance, with an F1-score of 0.885, an AUC of 0.94, and a detection delay of 8.1 s. In contrast, the Rule-based method exhibited a significantly higher false negative rate of 42.0%, indicating limitations in detecting complex anomaly patterns. These results demonstrate that the proposed spatiotemporal deep learning approach can significantly improve the accuracy and responsiveness of battery anomaly detection. Furthermore, the proposed method is expected to contribute to enhancing safety, reliability, and predictive diagnostics in next-generation intelligent BMS platforms.

This study proposes an optimization strategy for the over-current protection (OCP) parameters of a lithium iron phosphate (LiFePO₄, LFP) battery system used in electric golf carts operating under high motor-load conditions. Real-world hillclimbing tests were conducted under four clearly defined payload/passenger conditions to analyze the transient discharge-current pro-file, voltage sag, and cell-temperature response. The maximum discharge current reached -238.2 A under the 200 kg cargopayload and one-passenger condition, and the current interval exceeding 150 A lasted up to 27 s. The maximum instantaneous power was 11.05 kW. Thermal analysis showed that the cell-temperature rise was within 2°C and the maximum measured cell temperature was 22.3°C. Linear regression of voltage and current yielded R² = 0.9368 and dV/dI = 0.0126 Ω, which was used as the DC internalresistance estimate. Based on these quantitative results and the cell specification limit of 300 A continuous discharge, the OCP threshold was reviewed from 250 A to 280 A to improve driving continuity while remaining below the allowable continuous-discharge current. EIS-based SOH estimation and the AI-BMS variable protection logic are presented as an extension framework for reflecting temperature and aging effects in future OCP-setting decisions.

The safety and stability concerns of liquid electrolytes in conventional lithium-ion batteries have accelerated the development of solid-state alternatives. NASICON type ceramics Li_1.5Al_0.5Ti_1.5(PO₄)₃ (LATP) offer promising properties, including high bulk ionic conductivity and good compatibility with lithium anodes. However, their practical application is hindered by grain boundary resistance and relatively low total ionic conductivity. This study investigates the effect of Ta₂O₅ doping on LATP to overcome these limitations. Doping with 5 wt% Ta₂O₅ improved the ionic conductivity to 2.95 × 10-4 S/cm by enhancing lattice structure, reducing grain boundary resistance, and suppressing the formation of secondary phase. Additionally, Ta₂O₅ positively influenced the sintering behavior, resulting in a denser, and more uniform microstructure. These enhancements suggest that Ta₂O₅-doped LATP is a strong candidate for next-generation all-solid-state lithium-ion batteries.

Thermal batteries are designed to activate at high temperatures (~500℃), therefore, the electrodes used in these systems are typically made into pellet form using compression molding techniques that do not involve polymer binders. However, the compression molding technique poses limitations in scaling up the electrode area without increasing thickness for high-power properties. Additionally, the tape casting method has been studied as a way to solve with, but too low a loading level is still an obstacle to practical use. This study fabricated a film cathode of high loading level (35.79 mAh·cm^-2) using the tape casting method for these problem. As utilized fabricated cathode, it investigated the influence of electrode thickness and density on electrochemical performance. Furthermore, a film cathode with a larger area but the same amount of active material as the pellet was fabricated, enabling the design of high-power cells with the same energy density. We expect that the fabricated film cathode with a high loading level and scalable area will enable the development of various thermal battery designs.

Lithium-ion batteries are utilized as an energy source for electric vehicles because of their advantages such as excellent cyclability, high energy density, high capacity, high efficiency, and low price. However, lithium-ion batteries use combustible electrolytes, which have also reported problems related to fire safety. Therefore, research on the fire safety of lithium-ion batteries is actively being conducted. In this study, detection criteria for the fire safety of lithium-ion batteries were proposed through incremental capacity analysis (ICA) and frequency analysis. The experimental results showed that the battery micro internal short circuit (MISC) indicator could be identified through changes in specific frequency bands and fluctuations in the ICA curve.

Lithium-ion batteries (LIBs) have attracted great attention as the common power source in energy storage fields of large-scale applications such as electrical vehicles (EVs), industries, power plants, and grid-scale energy storage systems (ESSs). Insertion, alloying, and conversion reactions are the main electrochemical energy storage mechanisms in LIBs, which determine their electrochemical properties and performances. The electrochemical reaction mechanisms are determined by several factors including crystal structure, components, and composition of electrode materials. This article reviews a new strategy to compensate for the intrinsic shortcomings of each reaction mechanism by introducing the material systems to form a single compound with different types of reaction mechanisms and to allow the simultaneous hybrid electrochemical reaction of two different mechanisms in a single solid solution phase.

Recently, active research has been conducted to enhance the power characteristics and thermal stability of lithiumion batteries (LiBs) by modifying separators using a ceramic coating method. However, since the thermal properties and surface features of the separator vary depending on the characteristics of the ceramic powders applied to the separator, it is crucial to manufacture ceramic powders optimized for the separator’s performance. In this study, we evaluated the characteristics of three types of α-alumina (A-1, A-2, and A-3) produced with varying dispersant contents and milling times, in addition to commercial α-alumina (AES-11). Subsequently, the optimized powders (A-3) were coated onto the separator using an aqueous binder for comparison with the characteristics of an AES-11 coated separator and an uncoated PE separator. The A-3 coated separator improved electrolyte wettability with a low contact angle (44.69°) and increased puncture strength (538 gf). Furthermore, it exhibited excellent thermal stability, with a shrinkage value of 5.64% when exposed to 140℃ for 1 hour, compared to the AES- 11 coated separator (6.09%) and the bare PE separator (69.64%).

In this study, an induction heating system using resonance is developed to remove remaining moisture and contaminations which could be generated during fabricating secondary batteries. This system is composed of power supply and induction coil. Power supply needs an oscillator, zero crossing detection, frequency tracking function, and induction coil needs a dummy coil to obtain a uniform temperature distribution. It is very important to obtain a uniform heating temperature distribution of battery cell case in the induction heating system before pouring electrolyte into battery cell. Experimental results show a temperature distribution deviation of below 1℃ in the external position of battery cell cases. As well, the temperature of battery cell itself shows distribution of 40℃±3℃.

Herein we investigated the effect of the conductive agent on the electrochemical performance of the SiOx anode. SiOx anodes have a relatively low volume expansion (~160%) compared to Pure-silicon, but have a problem in that they have a poor electrical conductivity characteristic. In this study, physical and electrochemical measurements were performed using two 0-dimensional amorphous carbon conductive agents with different crystallinity and surface area. The crystal structure of the conductive agents and the local graphitization degree were analyzed through XRD and Raman, and the surface area of the particles was observed through BET. In addition, the electrical performance according to the graphitization degree of the conductive agents was confirmed through a 4-point probe. As a result of the electrochemical cycle and rate performance, it was confirmed that the performance of SiOx using a conductive agent having a low graphitization degree and a high surface area was improved. The results in this study suggest that the graphitization degree and surface area of the amorphous carbon conductive agent may play an important role in the SiOx electrode.

All-solid-state thin-film battery can realize the integration of electronic circuits into small devices. However, a high voltage cathode material is required to compensate for the low energy density. Therefore, it is necessary to study all-solid-state thin-film battery based on the high voltage cathode material LNMO. Nevertheless, the electrochemical properties deteriorate due to the problem of the interface between LiNi_0.5Mn_1.5O₄ (LNMO) and the solid electrolyte LiPON. In this study, to solve this problem, amorphous V₂O₅ was deposited as an interlayer between LNMO and LiPON. We confirmed the possibility of improving cycle performance of LNMO based thin-film battery. We expect that the results of this study can extend the battery lifespan of small devices using LNMO based all-solid-state thin-film battery.

Lithium-ion batteries (LIBs) have become a main energy storage device in various applications, such as portable appliances, renewable energy facilities, and electric vehicles. However, the poor thermal stability of LIBs may cause explosion or fire. The thermal runaway is the result of a failure of the separator inside LIB. Damages like tearing, piercing, and collapsing of the separator were simulated in a mechanical, an electrical, and a thermal way, and small discharge pulses of a few mV were detected at the time of separator damages. From the experimental results, this paper provided a method that can identify the separator failure before thermal runaway in the aspect of a potential explosion and fire prevention measures.

In this study, we introduce a Na β″-alumina composite thick film as a solid electrolyte, to reduce the resistance of electrolyte for a Na/S battery. An alumina/zirconia composite material was used to enhance the mechanical properties of the electrolyte. A solid electrolyte of about 40 μm thick was successfully fabricated through the conversion and tape-casting methods. In order to investigate the effect of the surface treatment process of the solid electrolyte on the battery performance, the electrolyte was polished by dry and wet processes, respectively, and then the Na/S batteries were prepared for analyzing the battery characteristics. The battery with the dry process performed much better than the battery made with the wet process. As a result, the battery manufactured by the dry process showed excellent performance. Therefore, it is confirmed that the surface treatment process of the solid electrolyte has an important effect on the battery capacity and coulombic efficiency, as well as the interface reaction.

All-solid-state thin-film lithium-ion batteries are important in the development of next-generation energy storage devices with high energy density. However, thin-film batteries have many challenges in their manufacturing procedure. This is because there are many factors, such as substrate selection, to consider when producing the thin film multilayer structure. In this study, we compare the fabrication and performance of all-solid-state thin-film lithium-ion batteries with a LiNi_0.5Mn_1.5O₄ cathode/LiPON solid electrolyte/ Li₄Ti₅O₁₂ anode structure using stainless steel and Si substrates with different surface roughness. We demonstrate that the smoother the surface of the substrate, the thinner the thickness of the all-solid-state thin-film lithium-ion battery that can be made, and as a result, the corresponding electrochemical characteristics can be improved.

This paper reports the microstructure and electrochemical properties of Si-Al-Fe ternary amorphous alloys prepared by rapid solidification as an anode for lithium secondary batteries. The microstructure was analyzed using XRD and HR-TEM with EDS mapping. In accordance with DSC analysis, annealing was performed to crystallize the active nano-Si in the amorphous alloy. Thus, nano-Si forms (~80 nm) embedded in the matrix alloy, such as Fe₂Al₃Si₃, FeSi₂, and Fe_0.42Si_2.67, were successfully synthesized. The electrode based on the Si-Al-Fe ternary alloy delivered an initial discharge capacity of approximately 700 mAh ^g-1, and exhibited a high Coulombic efficiency of 99.0~99.6% from the 2^nd to 70^th cycles.

This work investigated the effects of different conductive agents on the electrochemical properties of anodes. SiOx possesses high theoretical capacity and shows excellent cycle performance; however, the low initial coulombic efficiency and poor electrical conductivity limit its applications in real batteries. In this study, electrodes were fabricated using two different conductive agents, and the resulting physical and electrochemical properties were analyzed. SEM observations confirmed the formation of a CNT conductive network throughout the electrodes, while the electrical conductivity contributed to the electrode was confirmed by impedance measurements. Thus, the electrode fabricated with the CNT conductive agent showed greater capacity and superior cycle performance than did the electrode fabricated using the DB conductive agent.

Black phosphorus (BP) is a potential candidate for an anode in lithium ion batteries due to its high theoretical capacity and the large interlayer spacing in the monolayered phosphorene form, allowing for lithium intercalation/ deintercalation. In this study, large-scale exfoliation of bulk BP was accomplished using a solution of NaOH and N-methyl-2-pyrrolidone (NMP), yielding phosphorene, which can be assembled into nanoflakes using electrophoretic deposition (EPD). Through the systematic addition of NaOH and subsequent sonication, BP nanoflakes were obtained in high yields by EPD, allowing for the integration of these nanoflakes into an anode in the film state. Anodes with a charge/discharge capacity of 172 mAh/g at a rate of 200 mA/g were obtained, which are promising for battery applications through various post-film treatments.

Lithium-ion batteries used for IT, automobiles, and industrial energy-storage devices have battery management systems (BMS) to protect the battery from abnormal voltage, current, and temperature environments, as well as safety devices like, current interruption device (CID), fuse, and vent to obtain positive temperature coefficient (PTC). Nonetheless, there are harmful to human health and property and damage the brand image of the manufacturer because of smoke, fire, and explosion of lithium battery packs. In this paper, we propose a systematic protection algorithm combining battery temperature, over-current, and interconnection between protection elements to prevent copper deposition, internal short circuit, and separator shrinkage due to frequent and instantaneous over-current discharges. The parameters of the proposed algorithm are suggested to utilize the experimental data in consideration of battery pack operating conditions and malicious conditions.

SiO_x nanoparticles were granulated, and their microstructures and effects on electrochemical behaviors were investigated. In spite of the promising electrochemical performance of SiO_x, nanoparticles have limitations such as high surface area, low density, and difficulty in handling during slurry processing. Granulation can be one solution. In this study, pelletizing and annealing were conducted to create particles with sizes of several decades of micron. Decrease in surface area directly influences the initial charge and discharge process when granules are applied as anode materials for Li-ion batteries. Lower surface area is key to decreasing the amount of irreversible phase-formation, such as Li₂Si₂O₅, Li₂SiO₃ and LuSiO₄, as well as forming the solid electrolyte interface. Additionally, aggregation of nanoparticles is required to obtain further enhancement of the electrochemical behavior due to restrictions that there be no Li₄SiO₄-related reaction during the first discharge process.

The effect of various lithium sources such as LiCl, LiOH, and Li-metal on the microstructure and electrochemical properties of granulated SiO_x powders were investigated. Various lithium sources were metallurgically added for a passive pre-lithiation of SiO_x to improve its low initial coulombic efficiency. In spite of using the same amount of Li in various sources, as well as the same process conditions, different lithium silicates were obtained. Moreover, irreversible phases were formed without reduction of SiO_x, which might be from additional oxygen incorporation during the process. Accordingly, there were no noticeable electrochemical enhancements. Nevertheless, the Li₄SiO₄ phase changes the initial electrochemical reaction, and consequently the relationship between the microstructure and electrochemical properties of metallurgically pre-lithiated SiO_x could provide a guideline for the optimization of the performance of lithium ion batteries.

A large number of lithium-ion batteries are arranged in series and parallel in battery packs, such as those in electric vehicles or energy storage systems. As battery packs age, their output power and energy density drop because of voltage deviation, constant and non-uniform exposure to abnormal environments, and increased contact resistance between batteries; this reduces application system efficiency. Despite the balancing circuit and logic of the battery management system, the output of the battery pack is concentrated in the most severely aged unit cell and the output is frequently limited by power derating. In this study, we implemented a cell imbalance detection algorithm and selected parameters to detect a sudden decrease in battery pack output. In addition, we propose a method to increase efficiency by applying the measured testing values considering the operating conditions and abnormal conditions of the battery pack.

The lithium-ion battery pack of an electric vehicle (EV) deserves to be considered for an alternative use within smart-grid infrastructure. Despite the long automotive service life, EV batteries retain over 70~80% of their initial capacity. These battery packs must be managed for their reliability and safety. Therefore, a battery management system (BMS) should use specific algorithms to measure and estimate the status of the battery. Most importantly, the BMS of a grid-connected energy storage system (ESS) must ensure that the lithium-ion battery does not catch fire or explode due to an internal short from uncontrolled dendrite growth. In other words, the BMS of a lithium-ion battery pack should be capable of detecting the battery’s status based on the electrochemical reaction continuously until the end of the battery’s lifespan. In this paper, we propose a new protection algorithm for a dendritic lithium battery. The proposed algorithm has applied a parameter from battery pack aging results and has control power managing.

High-capacity secondary batteries can cause explosion hazards owing to microcurrent variations or current surges that occur in short circuits. Consequently, complete safety cannot be achieved with general protection that is limited to a mere current fuse. Hence, in the case of secondary batteries, it is necessary for the protector to limit the inrush current in a short circuit, and to detect the current during microcurrent variations. To serve this purpose, a fuse can be employed for the secondary battery protection circuit with current detection. This study aims at designing a protection device that can stably operate in the hazardous circumstances associated with high-capacity secondary batteries. To achieve the said
objective
, a detecting fuse was designed from an alloy of low melting point elements for securing stability in abnormal current states. Experimental results show that the operating I-T and V-T characteristic constraints can be satisfied by employing the proposed current detecting self-contained low melting point fuse, and through the resistance of the heating resistor. These results thus verify that the proposed protection device can prevent the hazards of short circuit current surges and microcurrent variations of secondary batteries.

Transition metal oxide materials have attracted widespread attention as Li-ion battery electrode materials owing to their high theoretical capacity and good Li storage capability, in addition to various nanostructured materials. Here, we fabricated a CoO Li-ion battery in which Co nanoparticles (NPs) are deposited into a current collector through electrophoretic deposition (EPD) without binding and conductive agents, enabling us to focus on the intrinsic electrochemical properties of CoO during the conversion reaction. Through optimized Co NP synthesis and electrophoretic deposition (EPD), CoO Li-ion battery with 630 mAh/g was fabricated with high cycle stability, which can potentially be used as a test platform for a fundamental understanding of conversion reaction.

High-power lithium batteries are suitable for equipment with high power output needs, such as for ESS’s initial start-up. However, their management cost is increased by the installation of air-conditioning to minimize the risk of explosion due to internal temperature rise and also by a restriction on the number of charge/discharge cycles. High-capacity flow batteries, on the other hand, have many advantages. They can be used for over 20 years due to their low management costs, resulting from no risk of explosion and a high number of charge/discharge cycles. In this paper, we propose an ESS based on hybrid batteries that uses a lithium iron phosphate battery (LiFePO) at the initial startup and a vanadium redox flow battery (VRFB) from the end of the transient period, with a bi-directional PCS to operate two batteries with different DC voltage levels and using an efficient energy management control algorithm.

Thermal batteries are used in military power sources that require robustness and long storage life for applications in missiles and torpedoes. FeS₂ powder is currently used as a cathode material because of its high specific energy density, environmental non-toxicity, and low cost. MS₂ (M = Fe, Ni, Co) cathodes have been explored as novel candidates for thermal batteries in many studies; however, the discharge characteristics (1, 2, 3 plateau) of single cells in thermal batteries with different cathodes have not been elucidated in detail. In this study, we independently analyzed the discharge voltage and calculated the total polarizations of single cells using MS₂ cathodes. Based on the results of this study, we propose NiS₂ as a potential cathode material for use in thermal batteries.

In this study, Li₂MnSiO₄ cathode material and LiPON solid electrolyte were manufactured into thin films, and the possibility of their use in thin-film batteries was researched. When the RTP treatment was performed after Li₂MnSiO₄ cathode thin-film deposition on the SUS substrate by a sputtering method, a β-Li₂MnSiO₄ cathode thin film was successfully manufactured. The LiPON solid electrolyte was prepared by a reactive sputtering method using a Li₃PO₄ target and N₂ gas, and a homogeneous and flat thin film was deposited on a Li₂MnSiO₄ cathode thin film. In order to evaluate the electrochemical properties of the Li₂MnSiO₄ cathode thin films, coin cells using only a liquid electrolyte were prepared and the charge/discharge test was conducted. As a result, the amorphous thin film of RTP treated at 600℃ showed the highest initial discharge capacity of about 60 μAh/㎠. In cases of coin cells using liquid/solid double electrolyte, the discharge capacities of the Li₂MnSiO₄ cathode thin films were comparable to those without solid LiPON electrolyte. It was revealed that Li₂MnSiO₄ cathode thin films with LiPON solid electrolyte were applicable in thin film batteries.

For comparison to the Li-ion battery, evaluating a thermal battery must consider additional variables. The first one is the temperature difference between the battery and its unit cell. Thermal batteries and their unit cells have a temperature difference that is caused by the thermal battery activation mechanism and its shape. The second variable is the electrochemical reaction steps. Most Li-ion batteries have a constant electrochemical reaction at the electrode, and battery voltage is affected when the concentration of Li ions is changed. However, a thermal battery has several steps in its electrochemical reaction, and each step has a different potential. In this study, we used unit cell discharge tests based on interpolating a 4D lookup table to estimate the performance of a thermal battery. From the test results, we derived an estimation algorithm by interpolating the table, which is queried from specified profile groups. As a result, we found less than a 5 percent difference between estimation and experiment at the 1.3 V cut-off time.

Powder compaction technology is widely used to prepare thermal battery components. This method, however, is limited by the size, thickness, and geometry of the battery components. This limitation leads to excessive cell capacity, overweight, and higher cost of the pellets, which decreases the specific capacities and delays the activation time of thermal batteries. FeS₂ thin-film cathodes were fabricated by tape-casting technology and analyzed by SEM and EDS in this paper. The residual organic binder of the FeS₂ thin-film cathodes decreased with the temperature of the heat treatment, which improved the specific capacity because of the lower resistance. Specific capacities of the FeS₂ thin-film cathodes decreased because of the higher residual binder and the restrictive reaction of active materials with molten salts as the thickness increased. FeS₂ thin-film cathodes showed much higher specific capacity (1,212.2 As/g) than pellet cathodes (860.7 As/g) at the optimal heat-treatment temperature (230℃).

Pulverized FeS₂ (pyrite) gives different discharge test results with as-received FeS₂ electrodes. The as-received FeS₂ electrode shows three voltage plateaus during the discharge test. However, the ball-milled FeS₂ electrode shows two voltage plateaus. To interpret this result, the effect of FeS₂ particle size on electrochemical reactions is investigated by unit cell discharge tests, SEM and XRD. As a result, it is found that the transition reaction product (Li₂ + xFe + xS₂) of FeS₂ explains the difference. The as-received FeS₂ reacts according to three reaction steps (FeS₂ → Li₃Fe₂S₄ → Li₂ + xFe₁ + xS₂ → LiFe₂S₄). However, ball-milled FeS₂ reacts without the Li₂ + xFe₁ + xS₂ stage. In this study, this result is explained by the difference in electrochemical reaction mechanism. The as-received FeS₂ has a larger radius than the ball-milled FeS₂. Therefore, the lithium ion has to diffuse into the FeS2 unreacted core, and Li₂ + xFe₁ + xS₂, the transition reaction product of as-received FeS₂, is formed during this stage.

Thermal batteries use inorganic salt as electrolyte, which is inactive at room temperature. As soon as heat pellets are fired by an igniter, all the solid electrolytes are instantly melted into excellent ionic conductors. However, the abnormal heat generation by the igniter flame or heat pellets causes the thermal decomposition of the electrode and the melting of the anode, eventually leading to a thermal runaway, which results in overheating or explosion. The thermal runaway can be significantly reduced by the adoption of Zr/BaCrO4 heat papers. In this study, the heat papers with various ratios of fuel (Zr) and oxidizer (BaCrO4) were prepared by the paper-making process. We have investigated the calorimetric value, burning rate, and ignition sensitivity. The ignition test of heat pellets and the discharge test of thermal batteries were also carried out. At the composition of 40 wt.% of Zr, the heat papers showed the highest specific calorimetric value and burning rate. As a result, Zr/BaCrO4 heat paper made by the paper-making process has shown the applicability for thermal batteries.