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Early Stage Report: Graduate Research

Magnetically Directed Percolation Networks in Polydopamine-Mediated Carbon Nanotube/Fe3O4 Nanocomposites
Dongyeong Gim, Hyeokju Kwon, Minjeong Ha
J Electr Electron Mater 2026;39(3):288-294.
Published online May 1, 2026
DOI: https://doi.org/10.4313/JEEM.2026.39.3.8
Polymer nanocomposites incorporating inorganic nanofillers have emerged as highly promising electromagnetic interference (EMI) shielding materials, combining mechanical compliance with robust conductive percolation networks. Carbon nanotubes (CNTs) are particularly attractive as conductive fillers because their high aspect ratio facilitates percolation at low loadings. Also, CNTs offer superior mechanical durability under deformation compared to rigid, fracture-prone metal nanowires. For EMI shielding, high electrical conductivity is critical as it enhances both reflection and absorption through efficient charge dissipation and conduction losses. However, achieving highly aligned conductive pathways without degrading the intrinsic electrical properties of CNTs remains a significant challenge. Here, we demonstrate a non-destructive magnetic surface-functionalization and alignment strategy. Using a polydopamine (PDA)-mediated route, pristine multiwalled CNTs are uniformly decorated with Fe3O4 nanoparticles (FMWCNTs). This enables highly effective magnetic field-driven alignment at fields as low as 10 mT, promoting the strategic formation of percolation networks. By optimizing the Fe₃O₄/MWCNT ratio for high saturation magnetization and uniform coverage, the aligned FMWCNTs exhibit significant electrical anisotropy, delivering a 10.7-fold higher electrical conductivity in the parallel configuration compared to the vertical configuration. These findings present a scalable, room-temperature platform for engineering directionally enhanced conductivity in polymer nanocomposites, with broad applicability in advanced EMI shielding, flexible electronics, and advanced packaging technologies.
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The Effect of Mask Thickness in The Silicon Etching by Using High Density Plasma
Jong-sik Kim, Jong-chang Woo, Gwan-ha Kim
J Electr Electron Mater 2026;39(1):27-33.   Published online January 1, 2026
DOI: https://doi.org/10.4313/JEEM.2026.39.1.4
This study investigates the effect of mask material and thickness on the silicon etching profile using a high-density plasma (HDP) etching system, aiming to reduce optical loss in silicon-based optical waveguides. As the mask thickness increased, the etching sidewall angle became steeper. An etching profile angle of 87° was obtained when tetraethyl orthosilicate (TEOS) was used as the mask material, while 80° was obtained for photoresist (PR). This is attributed to electron charging on the mask surface in the plasma. The charged mask modifies the distribution and strength of the electric field depending on its thickness, thereby affecting the trajectory of positive ions accelerated toward the substrate by the bias voltage. Furthermore, Plasma diagnostics using optical emission spectroscopy (OES) and surface composition analysis using field emission Auger electron spectroscopy (FE-AES) revealed that changes in the mask material also alter the reaction pathways and formation characteristics of active species and silicon by-products in the plasma. These results suggest that the mask material influences the overall plasma characteristics, including electron density and ion energy, and plays a critical role in the precise control of silicon etching profiles for high-performance optical device fabrication.
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Structural and Electrical Properties of (La0.7-xBixSr0.3)FeO₃ Ceramics for Application of Temperature Sensors
Se-ho Kang, Myung-gyu Lee, Sam-haeng Lee, Joo-seok Park, Sung-gap Lee
J Electr Electron Mater 2025;38(6):645-649.   Published online November 1, 2025
DOI: https://doi.org/10.4313/JEEM.2025.38.6.6
(La1-xBixSr0.3)FeO₃ ceramics exhibiting excellent magnetoresistance were synthesized via the conventional solid-state reaction method. The structural and electrical properties were investigated as a function of Bi3+ content to evaluate their potential application as temperature sensors. And the sintering temperature and time were 1,200℃ and 4 h, respectively. The structural and electrical properties were investigated as a function of Bi content. With increasing Bi substitution, a slight enhancement in both average grain size and relative sintered density was observed. In particular, the specimen with x = 0.3 exhibited an average grain size of approximately 0.82 μm. All samples demonstrated negative temperature coefficient of resistance (NTCR) behavior, and the electrical resistivity decreased with increasing Bi content. The resistivity of the (La0.4Bi0.3Sr0.3)FeO₃ composition was 4.68 mΩ-cm at 25°C. Additionally, the temperature coefficient of resistance (TCR) and the B25/75-value, which quantify the sensitivity of resistivity to temperature variations, were found to increase with Bi content. (La0.4Bi0.3Sr0.3)FeO₃ sample exhibited a TCR of 0.43%/°C and a B25/75-value of 1,096 K at room temperature. The electrical conduction mechanism of the (La1-xBixSr0.3)FeO₃ system was well described by the small polaron hopping model, wherein thermally activated charge carriers hop between localized Fe-O-Fe sites via electron-phonon interactions.
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Simultaneous Low-Temperature Plasma Annealing Process for Enhancing the Electrical Performance of a-IGZO Thin Film Transistors
Jung Hun Choi, Jae-yun Lee, Beom Gu Lee, Jung Moo Seo, Sung-jin Kim
J Electr Electron Mater 2024;37(6):630-636.   Published online November 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.6.8
The display industry has recently been at the forefront of innovative advancements in modern electronic devices. Technological progress such as flexible display holds significant potential across various application fields, particularly in wearable devices and rollable displays. A low-temperature process is essential for fabricating such displays. One of the key technologies in displays is the thin film transistor (TFT), with amorphous indium gallium zinc oxide (a-IGZO) receiving particular attention. a-IGZO is widely applied in high-performance displays due to its high charge mobility and stability. While a thermal treatment above 350℃ is typically required to maximize the electrical performance of a-IGZO TFTs, such high temperatures pose challenges for utilizing polymer substrates like plastics. Here, we thesis investigates the simultaneous lowtemperature plasma annealing process to develop next-generation high-performance flexible display devices. To define the optimal temperature, devices were fabricated and analyzed at varying temperatures of 40℃, 80℃, 120℃, and 160℃. Experimental results indicated that devices fabricated at 160℃ and 80℃ exhibited superior performance, with those at 160℃ demonstrating better performance in terms of current ratio, threshold voltage, and subthreshold swing. These findings confirm that the simultaneous low-temperature plasma annealing process is effective for next-generation high-performance displays.
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Always Space Antibacterial Technology Using a Luminaire Applied with a Visible Light Catalyst
Doowon Jang, Chunghyeok Kim
J Electr Electron Mater 2024;37(5):512-518.   Published online September 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.5.7
Titanium oxide (TiO₂), a representative photocatalyst, reacts to ultraviolet ray energy and has antibacterial, deodorizing, and antifouling properties using superhydrophilic properties, so it is widely used in various industrial fields such as environmental purification, building exterior walls, and road facilities. However, due to the nature of the photocatalyst, it reacts to ultraviolet rays known to be harmful to the human body, and is designed to react to natural light outdoors and to ultraviolet light sources inside a sealed device indoors, so indoor space is extremely limited. This study aims to develop spatial antibacterial technology for everyday living spaces by researching methods for antibacterial and deodorization by reacting titanium oxide (TiO₂)-based photocatalysts with the visible light range emitted from lighting devices in everyday spaces. Through the results of this study, it was verified through experiments that the photocatalyst exhibits antibacterial and deodorizing properties in response to lighting devices (LED, fluorescent lights, etc.) used in daily life. Based on the research results, we hope that various studies will be conducted to create a safer living environment by applying this technology to various fields such as large-scale complex facilities where an unspecified number of floating populations gather, airports, port waiting rooms, and public transportation.
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Synthesis and Particle Size Control of δ-FeOOH Using H₂O₂ Oxidizing Agent
Seongmin Shin, Kyunghwan Kim, Jeongsoo Hong
J Electr Electron Mater 2024;37(3):292-296.   Published online May 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.3.8
In this study, Iron (III) oxide-hydroxide (δ-FeOOH) was successfully synthesized using hydrogen peroxide (H₂O₂) as an oxidizing agent. The synthesis of δ-FeOOH was carried out by controlling the amount of H₂O₂, and pure δ-FeOOH was successfully synthesized in ranges from 0.2 mL to 0.6 mL of H₂O₂. The size of the synthesized δ-FeOOH particles was compared by controlling the amount of oxidant H₂O₂. The average particle size of the synthesized pure δ-FeOOH particles increased from 875.1 nm to 897.2 nm as the amount of H₂O₂ was increased. The optical properties of δ-FeOOH synthesized under these specific conditions were investigated. All δ-FeOOH showed a similar trend of increasing and decreasing light absorption from 800 nm to 400 nm, although there was a slight difference in the amount of light absorption, with the largest amount of light absorption at 410 nm. The band gap energy of δ-FeOOH through the Tauc plot method was about 2.1~2.2 eV when H₂O₂ was 0.2~1.4 mL. With a sufficient small particle size, simple control of that particle size, and a small band gap energy enough to absorb light in the visible spectrum, δ-FeOOH could be useful in a variety of applications, including photoelectrochemistry and battery electrodes.
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Transfer Methods of Inorganic Thin Film Materials for Heterogeneously- Integration Flexible Semiconductor System
Gyeong Hyeon Ju, Jeong Hyeon Kim, Sang Yoon Park, Kang Hyeon Kim, Han Eol Lee
J Electr Electron Mater 2024;37(3):241-252.   Published online May 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.3.2
With the recent development of emerging technologies, information acquisition and delivery between users has been actively conducted, and inorganic thin film transfer technology that effectively transfers various materials and devices is being studied to develop flexible electronic devices accordingly. This is aimed at innovative structural changes and functional improvement of electronic devices in the era of the Internet of Things (IoT). In particular, advanced technologies such as micro- LEDs are used to realize high-resolution flexible displays, and the possibility of heterogeneous integrated technologies can be presented by precisely transferring materials to substrates through various transfer process. This paper introduced physical, chemical, and self-assembly transfer methods based on inorganic thin film materials to implement heterogeneous integrated flexible semiconductor systems and introduces the results of application studies of semiconductor devices obtained through different transfer technologies. These studies are expected to bring about innovative changes in the field of smart devices, medical technology, and user interfaces in the future.
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Theoretical Insights into Oxygen Vacancies in Reduced Bulk TiO₂: A Mini Review
Jaehyuk Choi, Junho Lee, Taehun Lee
J Electr Electron Mater 2024;37(3):231-240.   Published online May 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.3.1
Titanium dioxide (TiO₂) holds significant scientific and technological relevance as a key photocatalyst and resistive random-access memory, demonstrating unique physicochemical properties and serving as an n-type semiconductor. Understanding the density and arrangement of oxygen vacancies (VOs) is crucial for tailoring TiO₂’s properties to diverse technological needs, driving increased interest in exploring oxygen vacancy complexes and superstructures. In this mini review, we summarize the recent understandings of the fundamental properties of oxygen vacancies in bulk rutile (R-TiO₂) and anatase (A-TiO₂) based on DFT and beyond method. We specifically focus on the excess electrons and their spatial arrangement of disordered single VO in bulk R and A-TiO₂, aligned with the experimental findings. We also highlight the theoretical works on investigating the geometries and stabilities of ordered VOs complexes in bulk TiO₂. This comprehensive review provides insights into the fundamental properties of excess electrons in reduced TiO₂, offering valuable perspectives for future research and technological advancements in TiO₂-based devices.
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Research on Water-Repellent Coating Materials to Prevent Solar Module Pollution
Young-a Park, Da Yeon Jung, Hyun Chul Ki
J Electr Electron Mater 2024;37(2):182-187.   Published online March 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.2.9
Currently, the most developed new energy source is solar energy. Because solar power is installed outside, it is exposed to many pollutants. Pollutants are causing the characteristics of solar energy to deteriorate. Therefore, this study aims to develop a water-repellent coating to prevent contamination of solar modules. Silica and Titania materials are mainly used as water-repellent coating materials. In this study, it was based on silica and the contact angle characteristics were measured according to the change in the amount of silica and ammonia water added and the number of coatings. As a result of the measurement, it was confirmed that the contact angle was more than 60 degrees when 0.5 mol of TEOS was added to 50 mL and 0.15 M when 1 mL of ammonia water was added to 296.47 ml of distilled water. And it was confirmed that the contact angle improved when the number of coatings was applied twice. A water-repellent coating material was applied to low iron tempered glass used to protect dye-sensitized solar cell modules. The characteristics of the module were measured after spraying DI-Water on low-emission tempered glass with a water-repellent coating. As a result of the measurement, the efficiency of the module without application, the efficiency of the module coated once, and the module coated twice were 4.87%, 4.90%, and 4.91%, respectively. It was confirmed that the efficiency of the module increased by applying water-repellent coating. As a result of this study, it is determined that the water-repellent coating material will help improve solar power generation efficiency and lifespan by being self-cleaning and non-reflective.
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Quantum Efficiency Measurement and Analysis of Solar Cells
Youngkuk Kim, Donghyun Oh, Jinjoo Park, Junsin Yi
J Electr Electron Mater 2023;36(4):351-361.   Published online July 1, 2023
DOI: https://doi.org/10.4313/JKEM.2023.36.4.5
The purpose of this paper is to help those who research and develop solar cells in university laboratories and industrial sites understand the most basic and important quantum efficiency measurement and analysis method in analyzing solar cell performance. Starting with the definition of quantum efficiency, we calculate the theoretical current density according to the band gap of the solar cell material from the solar spectrum, along with a detailed introduction to the measurement and analysis methods, and measure and analyze the theoretical current density and quantum efficiency. We discuss in depth how to analyze the performance of solar cells through Quantum efficiency measurement and analysis of solar cells is a very useful method that can give intuition to solar cell performance analysis as it can analyze solar cells according to depth (front emitter, bulk, rear surface). Students and researchers who study solar cells with a deep understanding of theoretical current density and quantum efficiency measurement analysis are expected to use it as a basis for analyzing solar cell performance.
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Current Status of Solar Power Generation in Jinju City Close to the South Coast and Jeonju City Close to the West Coast
Kwang Pyo Hong, Yun-hi Kim, Gi-hwan Kim
J Electr Electron Mater 2023;36(1):62-69.   Published online January 1, 2023
DOI: https://doi.org/10.4313/JKEM.2023.36.1.10
Recently, renewable energy has been increasing in Korea to reduce greenhouse gas, and solar power generation, which accounts for the largest proportion of renewable energy, is noteworthy. The government policy will further increase solar power generation. In order to implement the policy, it is important to understand the current status of domestic solar power generation facilities. Therefore, the current status of solar power generation facilities in Jinju city close to the south coast and Jeonju city close to the west coast was investigated and compared. By 2020, 618 solar power plants had been installed in Jeonju city and 269 in Jinju city. However, there is not much difference in the amount of solar power generation for business at 9 GWh. The reason is that Jinju city has a lower population density than Jeonju city, so there are enough places to install a large-scale solar power facilities with a large power generation capacity. Monthly solar power generation was the highest in April in both Jeonju city and Jinju city and the lowest in January. In particular, in December, Jinju city showed more solar power generation than Jeonju city because of the large amount of insolation, long sunshine hours, and few clouds.
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Development of Embedded System Based Cortex-M for Smart Manufacturing
Choon-nam Cho
J Electr Electron Mater 2020;33(4):326-330.   Published online July 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.4.14
Small-scale production control systems for smart manufacturing are becoming increasingly necessary as the manufacturing industry seeks to maximize manufacturing efficiency as the demand for customized product production increases. Correspondingly, the development of an embedded system to realize this capability is becoming important. In this study, we developed an embedded system based on an open source system that is cheaper than a widely applied programmable logic controller (PLC)-based production control system that is easier to install, configure, and process than a conventional relay control panel. This embedded system is system is based on a low-power, high-performance Cortex M4 processor and can be applied to smart manufacturing. It is designed to improve the development environment and compatibility of existing PLCs, control small-scale production systems, and enable data collection through heterogeneous communication. The real-time response characteristics were confirmed through an operation test for input/output control and data collection, and it was confirmed that they can be used in industrial sites.
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Structural and Electrical Properties of BiFeO3 Thin Films by Eu and V Co-Doping
Sung-keun Chang, Youn-jang Kim
J Electr Electron Mater 2019;32(3):229-233.   Published online May 1, 2019
Pure BiFeO3 (BFO) and (Eu, V) co-doped Bi0.9Eu0.1Fe0.975V0.025O3+δ (BEFVO) thin films were deposited on Pt(111)/Ti/SiO2/Si(100) substrates by chemical solution deposition. The effects of co-doping were observed by X-ray diffraction, Raman spectroscopy, and scanning electron microscopy (SEM). The electrical properties of the BEFVO thin film were improved as compared to those of the pure BFO thin film. The remnant polarization (2Pr) of the BEFVO thin film was approximately 26 μC/cm2 at a maximum electric field of 1,190 kV/cm with a frequency of 1 kHz. The leakage current density of the co-doped BEFVO thin film (4.81×10-5 A/cm2 at 100 kV/cm) was two orders of magnitude lower than of that of the pure BFO thin film.
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A Study on Data Transmission Using Dual Frequency
Jin Lee, Sung Soo Park
J Electr Electron Mater 2018;31(6):398-402.   Published online September 1, 2018
The following conclusions were obtained after analyzing the data transmission characteristics using two frequencies and studying a system that selects data with a good reception frequency as a priority data. Data transmission and reception using two frequencies were measured at -41 to -51 dBm when the frequency was normal, and data transmitted at 900 MHz was selected as priority data. When priority frequency failure occurred, the frequency reception data of the next rank was automatically adopted, and when the frequency of the next rank was disturbed, the priority frequency search was performed again. The above results show that the use of two frequencies enables more stable data transmission and transmission, and further studies should be continued to expand the transmission and reception distances.
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Structural and Electrical Properties of Bi0.9A0.1Fe0.975Zn0.025O3-δ (A=Eu, Dy) BiFeO3 Thin Films by Chemical Solution Deposition
Youn-jang Kim, Jin-won Kim, Sung-keun Chang
J Electr Electron Mater 2018;31(4):226-230.   Published online May 1, 2018
Pure BiFeO3 (BFO) and codoped Bi0.9A0.1Fe0.975Zn0.025O3-δ (A=Eu, Dy) thin films were prepared on Pt(111)/ Ti/SiO2/Si(100) substrates by chemical solution deposition. The remnant polarizations (2Pr) of the Bi0.9Eu0.1Fe0.975Zn0.025O3-δ (BEFZO) and Bi0.9Dy0.1Fe0.975Zn0.025O3-δ (BDFZO) thin films were about 36 and 26 μC/cm2 at the maximum electric fields of 900 and 917 kV/cm, respectively, at 1 kHz. The codoped BEFZO and BDFZO thin films showed improved electrical properties, and leakage current densities of 3.68 and 1.21×10-6 A/cm2, respectively, which were three orders of magnitude lower than that of the pure BFO film, at 100 kV/cm.
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Microstructural and Electrical Properties of Bi0.9A0.1Fe0.975V0.025O3+α(A=Nd, Tb) Thin Films by Chemical Solution Deposition Method
Sung-keun Chang, Youn-jang Kim
J Electr Electron Mater 2017;30(10):646-650.   Published online October 1, 2017
We have evaluated the ferroelectric and electrical properties of pure BiFeO3 (BFO) and Bi0.9A0.1Fe0.975V0.025O3+α(A=Nd, Tb) thin films on Pt(111)/Ti/SiO2/Si(100) substrates by using a chemical solution deposition method. The remnant polarization (2Pr) of the Bi0.9Tb0.1Fe0.975V0.025O3+α (BTFVO) thin film was approximately 65 μC/㎠, with a maximum applied electric field of 950 kV/cm and a frequency of 10 kHz, where as that of the Bi0.9Nd0.1Fe0.975V0.025O3+α (BNFVO) thin film was approximately 37 μC/㎠ with a maximum applied electric field of 910 kV/cm. The leakage current density of the co-doped BNFVO thin film was four orders of magnitude lower than that of the pure BFO thin film, at 2.75×10-7 A/㎠ with an applied electric field of 100 kV/cm. The grain size and uniformity of the co-doped BNFVO and BTFVO thin films were improved, in comparison to the pure BFO thin film, through structural modificationsdue to the co-doping with Nd and Tb.
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Effect of LaFeO3 Doping on the Ferroelectric and Piezoelectric Properties of Bi0.5(Na0.78K0.22)0.5TiO3 Lead-Free Piezoceramics
Chun-kil Park, Ji-ho Lim, Jung-soo Park
J Electr Electron Mater 2017;30(3):157-161.   Published online March 1, 2017
(1-x)Bi0.5(Na0.78K0.22)0.5TiO3-xLaFeO3 ceramics were fabricated using a solid state reaction method. The microstructural, ferroelectric and piezoelectric properties were characterized using X-ray diffraction (XRD), scanning electron microscope (SEM), and polarization hysteresis loops (P-E). XRD results indicated that BNKT ceramic crystal structure modified by LaFeO3 was transformed from a ferroelectric tetragonal to a non-polar pesudo-cubic phase with increased LaFeO3 content. The improved piezoelectric properties resulted from the addition of LaFeO3 up to 3 mol%. The LaFeO3 3mol% sample showed markedly improved piezoelectric and strain behaviors in comparison with pure BNKT ceramic.
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Insulation Materials : Regular Paper ; Effect of PEO Process Conditions on Oxidized Surface Properties of Mg alloy, AZ31 and AZ91. 1. Applied Voltage and Time
Jae Ho Ham, Min Seok Jeon, Yong Nam Kim, Min Chul Shin, Kwang Youp Kim, Bae Yeon Kim
J Electr Electron Mater 2016;29(4):218-224.   Published online April 1, 2016
The surface of Mg alloy, AZ31 and AZ91, were treated by PEO (plasma electrolytic oxidation) in Na-P system electrolyte, with different applied voltage and time. Thickness, roughness and X-ray crystallographic analysis revealed several results. The more applied time and voltage of PEO treated, the thicker oxidized surface coating layer were covered. And surface roughness increased with the thickness of oxidized layer. It was thought that when oxide layer grew, resistivity and breakdown voltage increased with the thickness of layer, and then, the energy of micro plasma need to be higher then before. So, it made craters and pores of surface become greater, which were responsible for the coarse surface.
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Insulation Materials : Regular Paper ; Effect of PEO Process Conditions on Oxidized Surface Properties of Mg alloy, AZ31 and AZ91. 2. Electrolyte
Jae Ho Ham, Min Seok Jeon, Yong Nam Kim, Hyun Gyoo Shin, Sung Youp Kim, Bae Yeon Kim
J Electr Electron Mater 2016;29(4):225-230.   Published online April 1, 2016
Effect of electrolyte composition and concentration on PEO coating layer were investigated. Mg alloy, Surface of AZ31 and AZ91 were oxidized using PEO with different electrolyte system, Na-P and Na-Si. and applied voltage and concentration. We measured thickness, roughness, X-ray crystallographic analysis and breakdown voltage of the oxidized layer. When increasing concentration of electrolyte, the thickness of oxide layer also increased too. And roughness also increased as concentration of electrolyte increasing. Breakdown voltage of coated layer showed same behavior, the voltage goes high as increasing thickness of coating layer, as increasing concentration of electrolyte, and increasing applied voltage of PEO. Mg2SiO4 phase were observed as well as MgO.
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Regular Paper : Microstructure and Electrical Properties of (YNdSm)-Ba-Cu-O High Tc Composite Superconductors by Zone Melting Process
So-jung Kim, Sang-heon Lee
J Electr Electron Mater 2016;29(2):110-113.   Published online February 1, 2016
(YNdSm)-Ba-Cu-O system high Tc composite superconductors were directionally grown by zone melting process, having large temperature gradient, in air atmosphere. Cylindrical green rods of (YNdSm)1.8Ba2.4Cu3.4Ox [(YNS)1.8]composite oxides by CIP (cold isostatic pressing) method using rubber mold were fabricated. Themicrostructure and superconducting properties were investigated by XRD, TEM and SQUID magnetometer. The size of nonsuperconducting (YNdSm)2BaCuO5 inclusions of the melt-textured (YNS)1.8 sample with CeO2 additive were remarkably reduced and uniformly distributed within the superconducting (YNS)1.8 matrix. (YNS)1.8 samples, with / without CeO2 additive, showed an onset Tc ≥ 90 K and sharp superconducting transition. The critical current density Jc value of the (YNdSm)1.8 superconductor with CeO2 additive were 840 A, 1.2×104 A/cm2 in 77 K, 0Tesla by direct current transport method.
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Ferroelectric and Piezoelectric Properties of PMW-PNN-PZT Ceramics as a Function of BiFeO3 Substitution
Cheol Min Ra, Ju Hyun Yoo
J Electr Electron Mater 2015;28(9):577-580.   Published online September 1, 2015
In this paper, in order to develop the composition ceramics with the outstanding piezoelectric properties, (Mg_{1/2} W _{1/2} )_{0.03} (OWNS_{1/3} Nb_{2/3})_{0.09} (Zr_{0.5} Ti_{0.5})_{0.88} O_{3} ceramics substituted with BiFeO_{3} were prepared by the conventional solid-state reaction method. The addition of small amount of Li2CO_{3} and CaCO_{3} as sintering aids decreased the sintering temperature of the ceramics. The effects of BiFeO3 substitution on their piezoelectric and dielectric properties were investigated. when 0.015 mol BiFeO_{3} was substituted, the optimal physical properties of d33=590 pC/N, Ec=8.78 kV/mm were obtained.
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Regular Paper : A Study on the Photo Reversible One-dimensional Photonic Crystals Composed of TeOx(x=1.42)/SiO2
Heon Kong, Jong Bin Yeo, Hyun Yong Lee
J Electr Electron Mater 2015;28(2):99-103.   Published online February 1, 2015
One-dimensional photonic crystals (1D PCs) were fabricated by RF sputtering technique on p-Si (100), and fused quartz substrates. The 1D PCs structures consisted of TeOx (x=1.42), and SiO2 with the difference refractive index. In order to estimate the effect on a defect level within 1D PCs structures, samples were prepared with both normal, and defect mode. The structural and optical properties were confirmed by Scanning electron microscope (SEM), and Ultraviolet visible near-infrared spectrophotometer (UV-VIS-NIR) respectively. In the case of a 1D PC normal mode without defect layer, it had a photonic band gap (PBG) in the near infrared (NIR) region. In the case of a 1D PC defect mode with defect layer, it had a sharp transmission band owing to a defect level, and moved towards the longer wavelength after exposing He-Cd laser with a wavelength of 325 nm.
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Display and Optical Devices : Optical Analysis for the Autostereoscopic Display with a Lenticular Array Using Finite Ray Tracing
Bong Sik Kim, Keon Woo Kim, Da Shin Choi, Woo Sang Park
J Electr Electron Mater 2014;27(3):162-166.   Published online March 1, 2014
We propose an analysis method of an autostereoscopic display system with lenticular lens array using finite ray-tracing method that is verified by the geometrical optics. In the present work, we adopt the cylinder equation for the mathematical expression of the lenticular lens. For the calculation of the direction cosine of the transmitted ray, we first calculate the refracting point at bottom of the lens and the direction cosine of the incident ray that propagating through the lens by the Snell`s law, and then apply to finite ray-tracing method. Finally, we obtain the simulation results for the intensity distribution of the ray at optimal viewing distance. From these results, we confirm the realization of 3D image that exists separately according to the viewing position at an optimal viewing distance.
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Printing Properties of Ag Paste with the Variation of Binder on the SiNx Coated Si Wafer
Jea Won Kang, Hyo Soon Shin, Dong Hun Yeo, Dae Yong Jeong
J Electr Electron Mater 2014;27(2):85-90.   Published online February 1, 2014
Ag paste has been used in the front electrode of the Si-solar cell. It is composed by Ag powder, glass frit, binder, solvent and dispersant. The role of the binder and the solvent is to make a flow and a printing property. However, it was not enough to report the printing properties with the variation of binder in the controled viscosity. In this study, we selected 3 kinds of typical binder which were used as binder for the paste in the industry, such as Ethyl cellulose, Hydroxypropyl cellulose and Acrylic. Ag pastes using these were prepared, controled viscosity and printed on the SiNx coated Si wafer. In the ‘A paste’ used Acrylicbinder, printed hight was highest and ‘H paste’ used Hydroxypropyl cellulose binder was lowest. Because ‘Hpaste’ was high viscosity due to the molecular weight, the solvent was added in the paste to control the viscosity. Therefore, the content of solid was lower in ‘H paste’. The relative pattern width which is related to the spreading of paste was the best in the case of ‘H paste’ and ’EH paste’ at 30℃. It is thought that the optimization of the relative pattern width is possible for a paste by the controling shear thinning phenomenon. In the case of ‘A paste’, though printing hight was best, the pattern width was dependant on the temperature.
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Optical Analysis for the 3D Display with a Lenticular Array
Bong Sik Kim, Keon Woo Kim, Ku Loon Lee, Woo Sang Park
J Electr Electron Mater 2013;26(7):534-538.   Published online July 1, 2013
Abstract: We propose a generic method to calculate the optical functionalities of a 3D display with a lenticular lens array. In the present work, based on the geometrical optics, it is designed considering the specifications of the display panel. For the effective simulation, we first calculate the optical functionalities of a single cylindrical lens and, by comparing with the results obtained from the conventional geometrical optics, confirm the validity of the present method. Afterwards, we obtain the full distribution of the light intensity at an optimum viewing distance by expanding the results of the single lens to the horizontal plane of the display panel. From these results, we finally confirm whether the 3D images are realized or not in the system.
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Dielectric and Piezoelectric Properties of Environmantal Friendly (Li0.04(Na0.56K0.44)0.96(Nb0.9Ta0.10)0.998Zn0.005O3 Ceramics for Energy Harvesting Devices
Sang Hoon Sin, Ju Hyun Yoo
J Electr Electron Mater 2013;26(5):355-359.   Published online May 1, 2013
In this paper, the + 0.005KNhO: ÷ xwt9`o le02 lead-free piezoelectric ceramics for energy harvesting devices were fabricated by the conventiona] mixed oxide method. The microstructure, dielectric, and piezoelectric properties were investigated as a function of the Te09 addition. All the specimens showed an orthorhombic phase structure. At the composition ceramics doped with 0.1 wt%Te02, the optimum values of da 212 pC/N, d33`g33= 9.54 pm2/N, and kp= 0.448 were obtained, respectively. The results indicate that the composition ceramics is a promising candidate for energy harvesting devices applications.
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Ferroelectric BiFeO3-coated TiO2 Electrodes for Enhanced Photovoltaic Properties of Dye-sensitized Solar Cells
Ho Yong Joo, Su Bong Hong, Ho Sang Lee, Ji Hoon Jeon, Bae Ho Park, Sung Chul Hong, Tack Jib Choi
J Electr Electron Mater 2013;26(3):198-203.   Published online March 1, 2013
Dye-sensitized solar cells (DSSCs) based on titanium dioxide (TiO2) have been extensively studied because of their promising low-cost alternatives to conventional semiconductor based solar cells. DSSCs consist of molecular dye at the interface between a liquid electrolyte and a mesoporous wide-bandgap semiconductor oxide. Most efforts for high conversion efficiencies have focused on dye and liquid electrolytes. However, interface engineering between dye and electrode is also important to reduce recombination and improve efficiency. In this work, for interface engineering, we deposited semiconducting ferroelectric BiFeO3 with bandgap of 2.8 eV on TiO2 nanoparticles and nanotubes. Photovoltaic properties of DSSCs were characterized as a function of thickness of BiFeO3. We showed that ferroelectric BiFeO3-coated TiO2 electrodes enable to increase overall efficiency of DSSCs, which was associated with efficient electron transport due to internal electric field originating from electric polarization. It was suggested that engineering the dye-TiO2 interface using ferroelectric materials as inorganic modifiers can be key parameter for enhanced photovoltaic performance of the cell.
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From UV irradiation, we achieved homeotropic liquid crystal alignment on blended photo-polymer layer which is composed of polyvinyl-cinnamate (PVCi) and homeotropic polyimide (PI). From vertical alignment (VA) mode, we measured threshold voltages by various PVCi doping concentration. Also, the rise time and fall time of VA cells were measured to verify the best doping concentration. Transmittance curves showed about 70% value between 380 nm and 780 nm wavelength which mean visible region.
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BLFeO3-based Lead-free Piezoelectric Ceramics
Jin Hong Choi, Hyun Ah Kim, Seung Ho Han, Hyung Won Kang, Hyeung Gyu Lee, Jeong Seog Kim, Chae Ii Cheon
J Electr Electron Mater 2012;25(9):692-701.   Published online September 1, 2012
Recently, many lead-free piezoelectric materials have been investigated for the replacement of existing Pb-based piezoelectric ceramics because of globally increasing environmental interest. There has been remarkable improvement in piezoelectric properties of some lead-free ceramics such as (Bi, Na) Ti03-(Bi, K) Ti03-BaTiO3, (Na, K) Nb03-LiSbO3, and so on. However, no one still has comparable piezoelectric properties to lead-based materials. Therefore, new lead-free piezoelectric ceramics are required. BiFeO3 has a rhombohedrally distorted perovskite structure at room temperature and a very high Curie temperature (Tc=1,100 K). And a very large electric polarization of 50~60 uC/cm2 has been reported both in epitaxial thin film and single crystal BiFeO3. Therefore, a high piezoelectric effect is expected also in a BiFeO3 ceramics. The recent research activities on BiFeO3 or BiFeO3-based solid solutions are reviewed in this article.
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Based on first-principles LCAO method, we study the electronic and atomic structures of DNA nucleobases adenine (A), thymine (T), guanine (G), and cytosine (C) adsorbed on graphene surfaces. The π-π stacking interactions between graphene and nucleobases lead to the bilayer geometries similar to the Bernal stacked graphite. Through the density of states and charge density analyses, it is found that nucleobases are physisorbed on graphene by dispersive interactions with negligible charge exchange. Our calculations reproduce the atomic structures obtained in previous plane wave calculations accurately with much less computation, and well describe the delocalized π-π interactions in graphene-nucleobases system, indicating that the LCAO method is very efficient for investigating graphene-bio systems.
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