In this work, the (K_1-xAg_x)(Ta_0.8Nb_0.2)O₃ (x=0.1-0.4) ceramics were fabricated using mixed-oxide method, and their structural and electrical properties were measured. All specimens represented a pseudo cubic structure with the lattice constant of 0.3989 nm. When 0.4 mol of Ag was added, second phases induced from metallic Ag and K₂(Ta,Nb)₆O₁₆ phase were observed. Dielectric constant and dielectric loss of K(Ta_0.8Nb_0.2)O₃ specimen doped with 0.3 mol of Ag were 2,737 and 0.446, respectively. The curie temperature was about -5℃, which does not change with Ag addition. The remanent polarization began to decrease sharply around 12~15℃, and the temperature at which the remanent polarization began to decrease as the applied voltage increased shifted to the high temperature side. The electrocaloric effect (ΔT) and electrocaloric efficiency (ΔT/ΔE) of the (K_0.7Ag_0.3)(Ta_0.8Nb_0.2)O₃ ceramics were 0.01024℃ and 0.01825 KmV^-1, respectively.

The electrocaloric effect in 0.94(Bi_0.5Na_0.5)TiO₃+0.06KNbO3+0.9 wt% G.F.ferroelectricceramics was observed in terms of the temperature change (ΔT) of the fabricated ceramics, Curie temperature Tc, and applied electric field. The specimens were fabricated by a conventional solid-state reaction. T_c appeared near 165∼170℃. The P-E hysteresis showed a tendency to slim down with a temperature increase and finally was slimmest near 150℃. With the increase of temperature, the polarization revealed a gradual decrease, and a sharp decline near T_c. When an electric field of 45 kV/cm was applied, the largest polarization was shown. The maximum value of the temperature change (ΔT=0.31℃) was obtained at 165℃ under an applied electric field of 45 kV/cm.

In this study, in order to develop relaxor ferroelectric ceramics for refrigeration device application with large electrocaloric effect and low sintering temperature, PLZT(8/65/35) ceramics was fabricated using conventional solid-state method with the variation of sintering temperature (1,050℃, 1,100℃, 1,200℃). The XRD pattern of all specimens indicated general perovskite structure with secondary phase. From the results of temperature dependence of dielectric constant, the TC (ferroelectric-paraelectric phase transition temperature) was shifted toward high temperature with increasing sintering temperature. When the specimen was sintered at 1,100℃, the optimal value of .T ∼0.349℃ in ambient temperature of 215℃ was appeared. It is considered that PLZT(8/65/35) ceramics possess the possibility of refrigeration device application.

In this study, in order to develop relaxor ferroelectric ceramics for refrigeration device application with large electrocaloric effect, PLZT(8/65/35) composition was fabricated using conventional solid-state method. The Curi temperature of this composition PLZT ceramics was 230℃, and the P-E hysteresis loops of the PLZT ceramics as a fuction of temperature became slim by degrees with higher temperatures. The maximum value of .T of 0.243°C in ambient temperature of 215°C with 30 kV/cm was appeared. It is considered that PLZT ceramics possess the possibility of refrigeration device application.

In this work, in order to develop the ceramics with an excellent electrocaloric effect, [Bi0.5(Na0.84K0.16)0.5]TiO3 ceramics were fabricated by conventional solid state reaction method. The ceramics was observed as rhombohedral phase by X-ray diffraction patterns. To investigate the electrocaloric effect of the ceramics, P-E hysteresis loops were measured at various temperature. The temperature change ΔT of these ceramics was calculated using the Maxwell``s relations. The maximum value of temperature change ΔT was obtained as 0.3 1℃ at 165℃ under applied electric fields 45 kV/cm.