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Early Stage Report: Graduate Research

Magnetically Directed Percolation Networks in Polydopamine-Mediated Carbon Nanotube/Fe3O4 Nanocomposites
Dongyeong Gim, Hyeokju Kwon, Minjeong Ha
J Electr Electron Mater 2026;39(3):288-294.
Published online May 1, 2026
DOI: https://doi.org/10.4313/JEEM.2026.39.3.8
Polymer nanocomposites incorporating inorganic nanofillers have emerged as highly promising electromagnetic interference (EMI) shielding materials, combining mechanical compliance with robust conductive percolation networks. Carbon nanotubes (CNTs) are particularly attractive as conductive fillers because their high aspect ratio facilitates percolation at low loadings. Also, CNTs offer superior mechanical durability under deformation compared to rigid, fracture-prone metal nanowires. For EMI shielding, high electrical conductivity is critical as it enhances both reflection and absorption through efficient charge dissipation and conduction losses. However, achieving highly aligned conductive pathways without degrading the intrinsic electrical properties of CNTs remains a significant challenge. Here, we demonstrate a non-destructive magnetic surface-functionalization and alignment strategy. Using a polydopamine (PDA)-mediated route, pristine multiwalled CNTs are uniformly decorated with Fe3O4 nanoparticles (FMWCNTs). This enables highly effective magnetic field-driven alignment at fields as low as 10 mT, promoting the strategic formation of percolation networks. By optimizing the Fe₃O₄/MWCNT ratio for high saturation magnetization and uniform coverage, the aligned FMWCNTs exhibit significant electrical anisotropy, delivering a 10.7-fold higher electrical conductivity in the parallel configuration compared to the vertical configuration. These findings present a scalable, room-temperature platform for engineering directionally enhanced conductivity in polymer nanocomposites, with broad applicability in advanced EMI shielding, flexible electronics, and advanced packaging technologies.
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Synthesis of Size-Controlled Urchin Ag Nanoparticles and Surfcace Enhanced Raman Spectroscopy (SERS)
Young Wook Lee, Tae Ho Shin
J Electr Electron Mater 2019;32(6):454-457.   Published online November 1, 2019
Controlling the shape of Ag nanoparticles (NPs) is very difficult. In the present work, urchin Ag NPs with different sizes and pod length control have been synthesized successfully in high yield by the concentration of a reducing agent. Unique Ag NPs were observed by TEM and SEM. These nanocrystals exhibit tunable surface plasmon resonance properties from the visible to near-infrared regions. They were applied to surface-enhanced Raman scattering (SERS) substrates using rhodamine 6G (R6G), benzenethiol (BT), and 4-amino benznethiol (4-ABT) molecules. The enhanced local field effect due to the sharp pod length, size, and surface plasmon of the urchin Ag NPs resulted in enhanced SERS properties and can serve as high-sensitivity substrates for SERS measurements.
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Synthesis of Shape Controlled Pd Nanoparticles and Surface-Induced Photoreduction of 4-Nitrobenzenethiol on Pd
Young Wook Lee, Tae Ho Shin
J Electr Electron Mater 2019;32(6):458-461.   Published online November 1, 2019
The facile synthesis of shape-controlled Pd nanoparticles (PdNPs) with ascorbic acid as a reducing agent and cetyltrimethylammonium bromide (CTAB) as a capping agent is presented in this study. The synthesized PdNPs were characterized by UV-vis spectroscopy, transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction (XRD), and Raman Spectroscopy. The prepared PdNPs show efficient surface-enhanced Raman scattering (SERS) properties. SERS studies on the adsorption characteristics of 1,4-phenylene diisocyanide (1,4-PDI) on colloidal PdNPs have revealed that the relative peak intensity of the (NC)free and (NC)bound modes distinctly depends on the 1,4-PDI concentration as well as the shape of the PdNPs. Furthermore, we found that the PdNPs are also efficient photoelectron emitters such that the SERS spectrum of 4-nitrobenzenethiol (4-NBT) on PdNPs is readily converted to that of 4-aminobenzenethiol (4-ABT) under 632.8 nm radiation.
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Synthesis of Size Controlled Gold Nanoparticles and Surface Enhanced Raman Spectroscopy (SERS) Effect
Young Wook Lee, Tae Ho Shin
J Electr Electron Mater 2019;32(6):462-465.   Published online November 1, 2019
Nanoscale gold particles have been intensively researched due to their potential applications in catalysis, electronics, plasmonics, and biological assays. In our study, we fabricated gold nanoparticles (NPs) that were synthesized in an aqueous environment via the reduction of HAuCl4 by ascorbic acid (AC) with a sodium citrate (SC) surfactant. Highly monodispersed gold particles with sizes ranging from 123 to 184 nm were prepared in high-yield by a surfactant concentration. The structural and optical properties of the synthesized gold nanoparticles were characterized by transmission electron microscopy (TEM) and UV-vis spectroscopy. The prepared nanoparticles exhibited efficient surface-enhanced Raman scattering (SERS) properties that were dependent on their on size.
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Granulations of SiOx Nanoparticles to Improve Electrochemical Properties as a Li-Ion Battery’s Anode
Bora Lee, Jae Young Lee, Boyun Jang, Joonsoo Kim, Sung-soo Kim
J Electr Electron Mater 2019;32(1):70-77.   Published online January 1, 2019
SiOx nanoparticles were granulated, and their microstructures and effects on electrochemical behaviors were investigated. In spite of the promising electrochemical performance of SiOx, nanoparticles have limitations such as high surface area, low density, and difficulty in handling during slurry processing. Granulation can be one solution. In this study, pelletizing and annealing were conducted to create particles with sizes of several decades of micron. Decrease in surface area directly influences the initial charge and discharge process when granules are applied as anode materials for Li-ion batteries. Lower surface area is key to decreasing the amount of irreversible phase-formation, such as Li2Si2O5, Li2SiO3 and LuSiO4, as well as forming the solid electrolyte interface. Additionally, aggregation of nanoparticles is required to obtain further enhancement of the electrochemical behavior due to restrictions that there be no Li4SiO4-related reaction during the first discharge process.
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Structural Properties of ZnS Nanoparticles by Hydrothermal Synthesis Process Conditions and Optical Properties of Ceramic
Seo-yeong Yeo, Tae-hyeong Kwon, Chang-il Kim, Ji-sun Yun, Young-hun Jeong, Youn-woo Hong, Jeong-ho Cho, Jong-hoo Paik
J Electr Electron Mater 2018;31(6):392-397.   Published online September 1, 2018
In this paper, the ZnS nanoparticles were synthesized according to the process conditions of hydrothermal synthesis. When the molar ratio of Zn to S was 1:1.2, it was confirmed that it had a cubic single phase and a high crystal phase. After the molar ratio is fixed, hydrothermal synthesis was conducted at 180℃ for 24, 36, 72 and 96 h in order to confirm the structural change with the change of hydrothermal synthesis times. As the hydrothermal synthesis times increased, the particle size increased. The hydrothermal synthesized particle size for 72 h was considered to be suitable for sintering. The ZnS ceramic had a density of 99.7% and an excellent transmittance of ~70% in the long-wavelength region.
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Affected Enhance of Dye-Sensitized Solar Cells Using Silver Nanoparticle
Haeng Yun Jung, Kyung Jin Hong
J Electr Electron Mater 2018;31(1):34-39.   Published online January 1, 2018
In this study, e-beam equipment was used to form silver nanoparticles on thin films of TiO2 to increase the efficiency of dye-sensitized solar cells and improve the annealing process. TiO2 thin films with nanoparticle photoelectrodes were fabricated in individual units for use in dye-sensitized solar cells. The characteristics of dye-sensitized solar cells were compared to those of the prepared TiO2 photoelectrode with and without nanoparticles. The dye-sensitized solar cells with silver nanoparticles showed a significant increase in the electric current density compared with the pure TiO2 dye-sensitized solar cell and improved the solar conversion efficiency to 27.89%. The increased density of electric current increased the extent of light absorption of the dye owing to the plasmon resonance of the nanoparticles at the local surfaces. This phenomenon led to increased light scattering, which in turn increased the current density of the dye-sensitized solar cells and improved the solar conversion efficiency.
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Sintering and Optical Properties of ZnS Nanoparticles Sintered by Spark Plasma Sintering
Chang-il Kim, You-bi Kim, Seo-yeong Yeo, Youn-woo Hong, Ji-sun Yun, Woon-ik Park, Young-hun Jeong, Jeong-ho Cho, Jong-hoo Paika
J Electr Electron Mater 2017;30(6):349-355.   Published online June 1, 2017
Zinc sulphide (ZnS) nanoparticles were fabricated by hydrothermal synthesis at 180℃ for 12 h. Two kinds of ZnS powder (hydrothermal synthesized ZnS and commercial ZnS) were investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM) for phase and microstructure, respectively. The XRD patterns showed that all ZnS nanoparticles have a sphalerite (cubic) structure. The nanoparticles of two different ZnS powders were sintered by spark plasma sintering. The sintered ZnS were analyzed by XRD, SEM, and FT-IR. We found that the transmittance of the infrared region is highly dependent on the density and crystal structure of sintered ZnS and the purity of the starting ZnS powder.
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Rcgular Paper : Energy Materials ; Synthesis of Boron-doped Crystalline Si Nanoparticles Synthesized by Using Inductive Coupled Plasma and Double Tube Reactor
Chun Young Jung, Jeong Boon Koo, Bo Yun Jang, Jin Seok Lee, Joon Soo Kim, Moon Hee Han
J Electr Electron Mater 2014;27(10):662-667.   Published online October 1, 2014
B-doped Si nanoparticles were synthesized by using inductive coupled plasma and speciallydesigned double tube reactor, and their microstructures were investigated. 0∼10 sccm of B2H6 gas wasinjected during the synthesis of Si nanoparticles from SiH4 gas. Highly crystalline Si nanoparticles weresynthesized, and their crystallinity did not change with increase of B2H6 flow rates. From SEMmeasurement, their particle sizes were approximately 30 nm regardless of B2H6 flow rates. From SIMSanalysis, almost saturation of B in Si nanoparticles was detected only when 1 sccm of B2H6 was injected. When B2H6 flow rate exceeded 5 sccm, higher concentration of B than solubility limit was detected evenif any secondary phase was not detected in XRD or HR-TEM results. Due to their high electronicconductivity, those heavily B-doped Si nanoparticles can be a potential candidate for an active material inLi-ion battery anode.
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Energy Materials : Regular Paper ; Organic Solar Cells with CuO Nanoparticles Mixed PEDOT: PSS Buffer Layer
Sang Hoon Oh, Seung Jin Heo, Hyun Jae Kim
J Electr Electron Mater 2014;27(2):121-125.   Published online February 1, 2014
In this research, nanocomposite layers consisting of poly (3,4,-ethylene dioxythiophene):polystyrene sulfonic acid (PEDOT:PSS) and CuO nanoparticles were investigated as hole transport layers in organic solar cells based on poly (3-hexylthiophene) (P3HT) as the electron donor and (6.6) phenyl-C61-butyric acid methyl ester (PCBM) as the electron acceptor. The addition of CuO nanoparticles to PEDOT:PSS layer improved the solar cell performance with 0.5% CuO nanoparticle concentration. At optimized concentration, CuO mixed PEDOT:PSS films had good electrical (4.131 Ω?cm) and optical (transmittance > 90%) properties for using hole transporting layer. We investigated that improved solar cell performance with CuO nanoparticles mixed PEDOT:PSS films.
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Thin Films and Sensors : Gas Sensing Property of SnO2 Nanoparticles Synthesized by Flame Spray Pyrolysis
Seong Hyeon Hong, Hong Chan Kim, Dong Wook Shin
J Electr Electron Mater 2012;25(8):626-631.   Published online August 1, 2012
SnO2 nanoparticles were synthesized by flame spray pyrolysis, which were directly deposited on Pt interdigitated substrates. Gas sensing performance was evaluated for various gases such as H2, CO, H2S, and NH3, and it was compared with that of commercial SnO2 nanopowder. The synthesis of SnO2 nanoparticles was also conducted in various solvents. As a result, the primary particle size was changed with the solvent of precursor solution, and their H2 sensing properties were significantly affected.
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Regular Paper : Characteristics of NFGM Devices Constructed with a Single ZnO Nanowire and Al Nanoparticles
Sung Su Kim, Kyoung Ah Cho, Sang Sig Kim
J Electr Electron Mater 2011;24(4):325-327.   Published online April 1, 2011
In this paper, nonvolatile nano-floating gate memory devices are fabricated with ZnO nanowires and Al nanoparticles on a SiO2/Si substrate. Al nanoparticles used as floating gate nodes are formed by the sputtering method. The fabricated device exhibits a threshold voltage shift of -1.5 V. In addition, we investigate the endurance and retention characteristics of the nano-floating gate memory device.
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Application of AuNPs immobilized on UV Cross-Linked P4VP Thin Film as pH Nanosensors
Min Sung Kim, Yeon Tae Jeong
J Electr Electron Mater 2008;21(11):1010-1018.   Published online November 1, 2008
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