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"Sol-gel method"

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"Sol-gel method"

Structural and Electrical Properties of K(Ta0.70Nb0.30)O₃/K(Ta0.55Nb0.45)O₃ Heterolayer Thin Films for Electrocaloric Devices
Byeong-jun Park, Ji-su Yuk, Sam-haeng Yi, Myung-gyu Lee, Joo-seok Park, Sung-gap Lee
J Korean Inst Electr Electron Mater Eng 2024;37(3):297-303.   Published online May 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.3.9
In this study, KTN heterolayer thin films were fabricated by alternately stacking films of K(Ta0.70Nb0.30)O3 and K(Ta0.55Nb0.45)O3 synthesized using the sol-gel method. The sintering temperature and time were 750℃ and 1 hour, respectively. All specimens exhibited a polycrystalline pseudo-cubic crystal structure, with a lattice constant of approximately 0.398 nm. The average grain size was around 130~150 nm, indicating relatively uniform sizes regardless of the number of coatings. The average thickness of a single-coated film was approximately 70 nm. The phase transition temperature of the KTN heterolayer films was found to be approximately 8~12℃. Moreover, the 6-coated KTN heterolayer film displayed an excellent dielectric constant of about 11,000. As the number of coatings increased, and consequently the film thickness, the remanent polarization increased, while the coercive field decreased. The 6-coated KTN heterolayer film exhibited a remanent polarization and coercive field of 11.4 μC/cm2 and 69.3 kV/cm at room temperature, respectively. ΔT showed the highest value at a temperature slightly above the Curie temperature, and for the 6-coated KTN heterolayer film, the ΔT and ΔT/ΔE were approximately 1.93 K and 0.128×10-6 K·m/V around 40℃, respectively.
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Structural and Electrical Properties of (La0.7Sr0.3)(Mn1-xFex)O3 Thin Films Prepared by Sol-Gel Method for Thermistor Devices
Ji-su Yuk, Sam-haeng Yi, Myung-gyu Lee, Joo-seok Park, Young-gon Kim, Sung-gap Lee
J Korean Inst Electr Electron Mater Eng 2024;37(2):164-168.   Published online March 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.2.6
(La0.7Sr0.3)(Mn1-xFex)O3 (LSMFO) (x = 0.03, 0.06, 0.09, 0.12) precursor solution are prepared by sol-gel method. LSMFO thin films are fabricated by the spin-coating method on Pt/Ti/SiO2/Si substrate, and the sintering temperature and time are 800℃ and 1 hr, respectively. The average thickness of the 6-times coated LSMFO films is about 181 to 190 nm and average grain size is about 18 to 20 nm. As the amount of Fe added in the LSMFO thin film increased, the resistivity decreased, and the TCR and B25/65-value increased. Electrical resistivity, TCR and B25/65-value of the (La0.7Sr0.3)(Mn0.88Fe0.12)O3 thin film are 0.0136 mΩ-cm, 0.358%/℃, and 328 K at room temperature, respectively. The resistivity properties of LSMFO thin films matched well with Mott’s VRH model.
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Dielectric Properties of K(Ta0.6Nb0.4)O3 Thin Films Prepared by Sol-Gel Method for Microwave Applications
Min-su Kwon, Sung-gap Lee, Kyeong-min Kim, Sam-haeng Lee, Young-gon Kim
J Korean Inst Electr Electron Mater Eng 2018;31(6):403-407.   Published online September 1, 2018
DOI: https://doi.org/10.4313/JKEM.2018.31.6.403
In this study, double layer KTN/STO thin films were fabricated on Pt/Ti/SiO2/Si substrate, their structural and electrical properties were measured according with the number of STO coatings, and their applicability to microwave materials was investigated. The average grain size was about 80~90 nm, the average thickness of the 6-coated KTN thin film was about 320 nm, and the average thickness of the STO thin film coated once was about 45~50 nm. The dielectric constant decreased with increasing frequency, and as the number of STO coatings increased, the rate of change of the dielectric constant with the applied electric field decreased. The tunability of the KTN thin film showed a maximum value of 19.8% at 3 V. The figure of merit of the KTN/1STO thin film was 9.8 at 3 V.
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Gas Sensing Properties of Pt Doped Fe2O3 Nanoparticles Fabricated by Sol-Gel Method
Min-hyung Jang, Yooseong Lim, Seung-il Choi, Ji-in Park, Namgyung Hwang, Moonsuk Yi
J Korean Inst Electr Electron Mater Eng 2017;30(5):288-293.   Published online May 1, 2017
DOI: https://doi.org/10.4313/JKEM.2017.30.5.288
Fe2O3 is one of the most important metal oxides for gas sensing applications because of its low cost and high stability. It is well-known that the shape, size, and phase of Fe2O3 have a significant influence on its sensing properties. Many reports are available in the literature on the use of Fe2O3-based sensors for detecting gases, such as NO2, NH3, H2S, H2, and CO. In this paper, we investigated the gas-sensing performance of a Pt-doped ε-phase Fe2O3 gas sensor. Pt-doped Fe2O3 nanoparticles were synthesized by a Sol-Gel method. Platinum, known as a catalytic material, was used for improving gas-sensing performance in this research. The gas-response measurement at 300℃ showed that Fe2O3 gas sensors doped with 3%Pt are selective for NO2 gas and exhibita maximum response of 21.23%. The gas-sensing properties proved that Fe2O3 could be used as a gas sensor for nitrogen dioxide.
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Regular Paper : Thin Films and Sensors ; Structural and Electrical Properties of Sol-gel Derived BFO/PZT Thin Films with Variation of Solvents
Chang Hyun Cho, Ju Lee
J Korean Inst Electr Electron Mater Eng 2011;24(11):895-899.   Published online November 1, 2011
DOI: https://doi.org/10.4313/JKEM.2011.24.11.895
Multiferroic BFO/PZT(5/95) multilayer films were fabricated by spin-coating method on the Pt/Ti/SiO2/Si substrate alternately using BFO and PZT(9/95) alkoxide solutions. The structural and dielectric properties were investigated with variation of the solvent and the number of coatings. All films showed the typical XRD patterns of the perovskite polycrystalline structure without presence of the second phase such as Bi2Fe4O3. BFO/PZT multilayer thin films showed the typical dielectric relaxation properties with increase an applied frequency. The average thickness of 6-coated BFO/PZT multilayer film was about 600 nm. The dielectric properties such as dielectric constant, dielectric loss and remnant polarization were superior to those of single composition BFO film, and those values for BFO/PZT multilayer film were 1199, 0.23% and 12 μC/cm2.
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The Effect of Pb Mol Ratio in PbZrO3 Thin Films made by Sol-Gel Method
Se Hwan Bae, Byung Moon Jin, Sung Dae Kim
J Korean Inst Electr Electron Mater Eng 2008;21(6):552-555.   Published online June 1, 2008
DOI: https://doi.org/10.4313/JKEM.2008.21.6.552
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