Recent studies have focused on enhancing the efficiency of triboelectric nanogenerators (TENGs) using aluminum (Al) and polydimethylsiloxane (PDMS). This research investigates how surface morphology and material structure affect energy generation. By layering PDMS/Al and creating pyramid-shaped patterns, the study found that increasing the number of PDMS/Al layers significantly boosts the output voltage, reaching over 234 mV with three layers. Additionally, increasing the number of pyramid structures from 1 to 36 on PDMS surfaces, while maintaining the same contact area, led to a notable rise in generated voltage due to charge concentration at the pyramid tips. Higher pyramid angles also amplified this effect. These results highlight the importance of structural optimization in maximizing the energy output of TENGs, offering a promising route for more efficient energy harvesting.