The printed and bifacial organic photovoltaics (OPVs) using a semi-transparent electrode structure to enhance light management were investigated. To optimize energy-band alignment for bifacial device structure, a cathode interlayer of ZnO nanoparticles with a low work function of 3.9 eV combined with a polyethyleneimine (PEI) layer was employed. Photon distribution simulations revealed the influence of structural parameters on device conductivity, light absorption, and surface morphology. The dispensing strength, adjusted via applied voltage during printing, significantly impacted device performance. At 13 V and 17 V, J-V characteristics were consistent; however, at 20 V, line width increased by approximately 100%, resulting in a 50% reduction in PCE. These findings highlight the critical relationship between spraying strength, line width, and efficiency, offering valuable insights for advancing printed OPV technologies.
