Cellulose nanofiber (CNF) has attracted significant attention as a next-generation insulating material due to its ecofriendly nature and outstanding functionalities. However, conventional kraft insulation paper suffers from limited dielectric breakdown strength and long-term reliability under high-voltage conditions, highlighting the need for alternative materials. In this study, kraft pulp was combined with five types of CNFs (A, B, C: wood-based / D, E: non-wood-based) to fabricate composite insulation papers, and their electrical and mechanical properties were systematically evaluated. The results showed that CNF incorporation generally enhanced density and tensile strength, while certain types contributed to lowering dielectric constant and improving breakdown strength. Among the wood-based CNFs, type C exhibited the most balanced performance in terms of dielectric stability and mechanical reinforcement. Among the non-wood-based CNFs, type E demonstrated notable improvements in structural compactness and tensile strength, suggesting favorable reliability. Therefore, this study identifies CNF C among wood-based types and CNF E among non-wood-based types as the most promising candidates for insulation performance enhancement, suggesting their applicability as next-generation insulating materials for power equipment and ecofriendly electronic devices.

Abstract In this study, to develop composition ceramics for energy harvesting devices, Pb(Ni_1/3Nb_2/3)O₃-Pb(Zr Ti)O₃ system ceramics substituted with Pb(Mg_1/2W_1/2)O₃ were manufactured by conventional mixed oxide method using Li₂CO₃ and Na₂CO₃ (LNCO) as sintering aids. Their microstructure and piezoelectric properties were also investigated. At the specimen sintered at 930℃, high values of piezoelectric properties appeared: the dielectric constant (εr) of 2,522 planar electromechanical coupling factor kp of 0.602, and k₃₁ of 0.385, d31 = 229 [pC/N], g₃₁ = 10.13 [mV.m/N], Qm of 70, respectively. These values were suitable for the application of devices such as energy harvesting devices and ultrasonic devices.

This study developed a dielectric composition for high-capacitance MLCCs with C0G and U2J temperature compensation characteristics (Class I) under reducing conditions. The potential application of this composition in highpermittivity class I MLCCs was examined. Using (Ba₀.₂₄Ca₀.₁₆Sr₀.₆)(TiₓZr₁₋ₓ)O₃. XRD analysis showed that secondary phases like Sr₂TiO₄ and TiO₂ formed at higher Ti content, affecting the stoichiometric balance. Adjusting the Ti/Zr molar ratio resulted in a dielectric constant of 41.2 ~ 105, a dielectric loss of 0.082 ~ 0.174%, and insulation resistance above 1.6 × 10¹³ ohms at 25℃. The TCC shifted from C0G to U2J as the Ti/Zr ratio increased, but the composition enabled the design of high-capacitance and high-voltage MLCCs with favorable dielectric and electrical properties.

In this study, Pb(Ni_1/3Nb_2/3)O₃-Pb(Zr,Ti)O₃ ceramics substituted with Pb(Mg_1/2W_1/2)O₃ were fabricated with the variation of CuO for application to ultrasonic cleaning of removable orthodontic appliances (ROA). And their piezoelectric and dielectric properties were investigated. At the 0.12 wt% CuO added ceramics sintered at 930℃, the excellent values of dielectric constant=2,519, density=7.82 g/㎤, kp=0.64, d₃₃=536 pC/N, Qm=57 were obtained, respectively. These values were suitable for application to ultrasonic cleaning of ROA.

In this study, the electrical properties of a C0G (class 1 ceramic) dielectric composition with internal reducibility, specifically (Ba_0.27CaSr)(Zr_0.95Ti_0.05)O₃, were investigated by fixing Ba at the A site and varying the Ca/Sr molar ratio. The potential application of this composition in high-permittivity C0G MLCCs was examined. The powder was calcined at 1,150℃ for 2 hours, as determined by TG-DTA analysis, and the resulting powder was ground to achieve a particle size (D50) of 0.35 to 0.4 μm and a specific surface area (BET) of 4.5 to 5.0 g/m². With a Ca/Sr molar ratio of 0.3, the composition (Ba0.27Ca0.17Sr0.56) (Zr0.95Ti0.05)O₃ exhibited electrical properties with a permittivity of 41.9, a loss of less than 0.008%, and an insulation resistance exceeding 2.2×10¹³ Ω. The feasibility of using this composition for high-capacitance C0G MLCCs was confirmed.

Ultrasonic sensor is suitable as a next-generation autonomous driving assist device because its lower price compared to that of other sensors and its sensing stability in the external environment. Although Pb(Zr, Ti)O₃ (PZT)-relaxor ferroelectric system has excellent piezoelectric properties, the change in capacitance is large in the daily operating temperature range due to the low phase transition temperature. Recently, many studies have been conducted to improve the temperature stability of ferroelectric ceramics by controlling the grain size and crystal structure, so it is necessary to study the effect of the grain size on the piezoelectric properties and the temperature stability of PZT-relaxor ferroelectric system. In this study, the piezoelectric properties, phase transition temperature, and temperature coefficient of capacitance (TCC) of 0.9 Pb(Zr_1-xTi_x)O₃-0.1 Pb(Zn_1/3Nb_2/3)O₃ (PZT_x-PZN) ceramics with various grain sizes were investigated. PZT_x-PZN ceramics with larger grain size showed higher piezoelectric properties and temperature stability, and are expected to be suitable for ultrasonic devices in the future.

In this work, the (K_1-xAg_x)(Ta_0.8Nb_0.2)O₃ (x=0.1-0.4) ceramics were fabricated using mixed-oxide method, and their structural and electrical properties were measured. All specimens represented a pseudo cubic structure with the lattice constant of 0.3989 nm. When 0.4 mol of Ag was added, second phases induced from metallic Ag and K₂(Ta,Nb)₆O₁₆ phase were observed. Dielectric constant and dielectric loss of K(Ta_0.8Nb_0.2)O₃ specimen doped with 0.3 mol of Ag were 2,737 and 0.446, respectively. The curie temperature was about -5℃, which does not change with Ag addition. The remanent polarization began to decrease sharply around 12~15℃, and the temperature at which the remanent polarization began to decrease as the applied voltage increased shifted to the high temperature side. The electrocaloric effect (ΔT) and electrocaloric efficiency (ΔT/ΔE) of the (K_0.7Ag_0.3)(Ta_0.8Nb_0.2)O₃ ceramics were 0.01024℃ and 0.01825 KmV^-1, respectively.

Theoretical background for the meaning of various piezoelectric properties can be easily found in a number of textbooks and academic papers. In contrast, how they are actually measured and characterized are rarely described, though this information would be the most important especially to the researchers who just started working on the field. It follows that this report was intended to provide a practical guidance for measuring basic but essential properties of ferroelectric-based piezoelectric materials. The discussion begins with how to measurement dielectric properties such as dielectric permittivity and loss (dissipation factor), followed by piezoelectric properties such as piezoelectric constants, electromechanical coupling factor, and quality factor as well as ferroelectric features, i.e., electric field dependent polarization hysteresis. Though our discussion here is limited to the techniques that are already well-standardized, it is expected to make a seed to be developed into more challenging and creative ones.

Phase evolution, thermal and microwave dielectric properties of cordierite-Al₂O₃ composite were investigated. As the content of Al₂O₃ increased, mullite, sapphirine, and spinel were formed as secondary phases, implying that cordierite may be decomposed by the reaction with Al₂O₃. All sintered specimens exhibited dense microstructures. The densification occurred through liquid phase sintering. As the content of Al₂O₃ increased, the thermal expansion coefficient and the dielectric constant increased, whereas the quality factor decreased. The thermal expansion coefficient, the dielectric constant, and the quality factor of the 90 wt% cordierite 10 wt% Al₂O₃ composite sintered at 1,425℃ were 2.9×10^-6 K^-1, 5.1, and 34,844 GHz, respectively.

Four types of BaTiO₃ powders are prepared and successfully deposited on glass and Pt/Si substrates using the aerosol deposition process. Particles with sizes of 0.45 μm and 0.3 μm are selected as the starting powder, while those powders are treated using a different milling method. The jet-milled and ball-milled powders not only showed a smaller particle-size distribution, but compared with the non-milled powder, it also had a higher deposition rate using the uniformly generated aerosol. Although the films deposited using particles with size 0.45 μm exhibited some craters on the surface, significantly flat film surfaces were obtained. However, particles with size 0.3 μm create a slightly rough film surface, but the dielectric constant was greater than in the case involving particles with size 0.45 μm. Consequently, a suitably large particle size significantly influences the deposition rate and improvement in the surface roughness, and a uniform particle size distribution appears to contribute to an improved dielectric constant. Therefore, it is believed that the dielectric properties along with the growth characteristics can be enhanced by limiting particle size and shape.

In this study, we investigate the effect of an Sb-deficiency on the thermoelectric properties of double-filled n-type skutterudite (In_0.05Yb_0.15Co₄Sb_12-x). Samples were prepared by encapsulated induction melting, consecutive long-time annealing, and finally spark plasma sintering processes. The Sb-deficient sample contained a CoSb₂ secondary phase. Both the double-filled n-type skutterudite pristine and Sb-deficient samples showed metallic behavior in electrical conductivity with increasing temperature. The carrier concentration of the Sb-deficient sample decreased compared with that of the pristine sample. Due to a decrease in carrier concentration, the Sb deficient sample showed decreased electrical conductivity and an increased Seebeck coefficient compared with the conductivity and coefficient of the pristine sample. Furthermore, the Sb deficient sample showed an increase in the power factor (σ·S²); the power factor maximum shifted to athe lower temperature side than ones of the pristine sample. As a result, the Sb-deficient sample represents an improved average figure of merit (ZT) and a ZT_max temperature lower than that of the pristine sample. Therefore, we propose that Sb-deficient double-filled n-type skutterudite thermoelectric material (In_0.05Yb_0.15Co₄Sb_12-x) be used in the 573~673 K temperature range.

Pb(Sb_0.5Nb_0.5)x(Zr_0.51Ti_0.49)_1-xO₃ (abbreviation: PSN-PZT) ceramics were synthesized, using conventional bulk ceramic processing technology, with various PSN doping contents. The maximum density of PSN-PZT was 97% of the theoretical density in the samples sintered at 1,250℃. The maximum values of the piezoelectric properties achieved using the conventional processes were: k_p of 0.625, d₃₃ of 531 pC/N, and g₃₃ of 33 mV·m/N. Finally, we fabricated a piezo-speaker with the optimized PSN-PZT ceramics. The SPL of the speaker was measured at a distance of 1 m, with a driving voltage of 40 V_rms in the frequency range of ~300 Hz to 9 kHz. The measured SPL_max was at a very high level (95 dB), which was superior in quality in comparison with those of other commercial products.

In this study, double layer KTN/STO thin films were fabricated on Pt/Ti/SiO₂/Si substrate, their structural and electrical properties were measured according with the number of STO coatings, and their applicability to microwave materials was investigated. The average grain size was about 80~90 nm, the average thickness of the 6-coated KTN thin film was about 320 nm, and the average thickness of the STO thin film coated once was about 45~50 nm. The dielectric constant decreased with increasing frequency, and as the number of STO coatings increased, the rate of change of the dielectric constant with the applied electric field decreased. The tunability of the KTN thin film showed a maximum value of 19.8% at 3 V. The figure of merit of the KTN/1STO thin film was 9.8 at 3 V.

The piezoelectric properties of 0.65Pb(Zr_1-xTi_x)O₃-0.35Pb(Zn_1/6Ni_1/6Nb_2/3)O₃ (PZT_x-PZNN) ceramics with 0.530≤ x≤0.555 were investigated for application to piezoelectric energy harvesters. Although a morphotropic phase boundary (MPB) was found at approximately x＝0.545, the ceramic with the highest figure of merit (FOM) (d₃₃×g₃₃) was observed at a composition of x＝0.540. Values of this figure of merit, d₃₃×g₃₃, of 19.6 pm²/N and 20.2 pm²/N were obtained from PZT_0.540-PZNN ceramics sintered at 920℃ and 950℃, respectively. A high output power of 937 μW and a high power density of 3.3 mW/cm³ were obtained from unimorph-type piezoelectric energy harvesters fabricated using PZT_0.540-PZNN ceramic sintered at 920℃ for 4h.

Pb(Mn_1/3Nb_2/3)_0.07(Ni_1/3Nb_2/3)_0.10(Zr_0.5Ti_0.5)_0.83O₃ composition ceramics with high piezoelectric properties were fabricated by the columbite precursor method for ultrasonic generators, and the effects of sintering temperature on microstructure and piezoelectric properties were systematically investigated. It was found that the tetragonality of the ceramics decreased with increase in sintering temperature. Moreover, excellent physical properties such as d₃₃=447 pC/N, ε_r=1,843, k_p=0.641, and Q_m=1,207 were obtained for an ultrasonic generator when the second calcination temperature and sintering temperature were 720℃ and 920℃, respectively.

In this paper, Pb(Mn_1/3Nb_2/3)_0.07(Ni_1/3Nb_2/3)_0.10(Zr_0.5Ti_0.5)_0.83O₃ ceramics were fabricated by the conventional solid state method to obtain excellent dielectric properties for ultrasonic generators. The effects of 2nd calcination temperature on their microstructure and piezoelectric properties were systematically investigated. The tetragonality increased in the ceramics when 2nd calcination temperature increased to the optimized temperature at 750℃. At that temperature, excellent physical properties (d₃₃= 352 pC/N, ε_r= 1,687, k_p= 0.570, Q_m= 1,640) were obtained for ultrasonic generator application.

With trend of the miniaturization and the high-functionalizing of mobile communication system, low-loss microwave dielectric materials are widely used for high frequency communication components. These dielectric materials should be co-sintered with highly electric-conducting metal such as silver or copper for high-frequency and thick film process application. Sintering temperature of Ca[(Li_1/3Nb_2/3)_1-xTi_x]O_3-δ, which has excellent dielectric properties such as ε_r above 40, quality factor (Q·f₀) above 16,000 GHz, and TCF (temperature coefficient of resonant frequency) of -20~-10 ppm/℃, is reported as high as 1,175℃, so it could not be co-sintered with silver or copper. Therefore in this study, low-temperature melting glasses of Zn-B-O and Zn-B-Si-O systems were added to Ca[(Li_1/3Nb_2/3)_1-xTi_x]O_3-δ to lower its sintering temperature under 900℃ without losing excellency of dielectric properties. With 15 weight % of Zn-B-Si-O glass and sintered at 875℃, specimen showed density of 4.11 g/cm³,ε _r of 40.1, Q·f₀ of 4,869 GHz, and TCF of -5.9 ppm/℃. With 15 weight % of Zn-B-O glass and sintered at 87 5℃, specimen showed density of 4.14 g/cm³, ε_r of 40.4, Q·f₀ of 7,059 GHz, and TCF of -0.92 ppm/℃.

The aim of this study is to improve of dielectric properties using epoxy/nano alumina composites with adding glycerol diglycidyl ether (GDE:1,2 g). This paper deals with the effects of dielectric properties(□´ and tan δ) for epoxy/nano alumina contents (1,3 phr) and GDE addition (1,2 g)composites. 5 kinds specimen were prepared with containing epoxy resins, epoxy nano alumina composites. Average particle size of nano used were 30 nm. The nano alumina used were gamma phase particles of spherical shape. The suppression of epoxy chain motion by addition of nano alumina+GDE decreased dielectric loss and relative permittivity magnitude.

In this work, the complex permittivity of epoxy resins is measured. Epoxy resins, epoxy with micro size fillers and epoxy with micro+nano alumina composites have been evaluated for dielectric properties according to frequency variation. The dielectric spectroscopy measurement and analyses are carried out in the frequency range of 10^-2 Hz to 1MHz and constant to room temperature. The results of dielectric loss suggest that significant improvement in the electrical performance can be expected by using samples containing nano and micro fillers mixture when compared to materials containing only microfillers. As the result, we verified the specific characteristics of dielectric permittivity and dielectric loss namely, relative permittivity become low with improving dispersibility of nano+micro mixture composites and become rise with agglomerate of nano particles.

In this study, in order to develop composition ceramics for Acoustic Emission (abbreviated as AE) sensor application, the PZT system ceramics was fabricated by conventional solid state reaction method. When x=0.48, the density, electromechanical coupling factor(kp), piezoelectric coefficient d₃₃ and piezoelectric voltage constant g₃₃ of the maximum values of 7.857 g/cm₃, 0.51, 190[pC/N], 52[10-₃mV/N] were obtained, respectively, suitable for AE sensor.

In this study, to develop low temperature sintering capacitor composition ceramics with the good dielectric properties, (Ba0.86Ca0.14)(Ti0.85Zr0.12Sn0.03)O3 (BCTZ) ceramics were prepared by the conventional solid-state reaction method. The effects of B2O3 addition on the dielectric properties and microstructure was investigated. The XRD patterns demonstrated that all the specimens showed Perovskite phase, and secondary phases are indicated in the measurement range of XRD. And also, temperature coefficient of capacitance(TCC) of all the specimen sintered at 1,180℃ showed +3∼-56% except for x=0.006. For all the specimens, observed one peak was tetragonal cubic difuse phase transition temperature(Tc), which is located in the vicinity of room temperature.

The surface of Mg alloy, AZ31 and AZ91, were treated by PEO (plasma electrolytic oxidation) in Na-P system electrolyte, with different applied voltage and time. Thickness, roughness and X-ray crystallographic analysis revealed several results. The more applied time and voltage of PEO treated, the thicker oxidized surface coating layer were covered. And surface roughness increased with the thickness of oxidized layer. It was thought that when oxide layer grew, resistivity and breakdown voltage increased with the thickness of layer, and then, the energy of micro plasma need to be higher then before. So, it made craters and pores of surface become greater, which were responsible for the coarse surface.

In this paper, in order to develop optimum composition ceramics with excellent piezoelectric properties, (Na0.525K0.443Li0.037)(Nb0.823Sb0.08Ta0.037)O3 + 0.3 wt%Bi2O3 + 0.4 wt%Fe2O3 lead-free piezoelectric ceramics were synthesized by conventional soild-state method. The calcination temperature of columbite precursors were fabricated at temperature range from 950℃ to 1,150℃ and sintering aids with low melting point were added to densify these ceramics. Effect of calcination temperature on dielectric and piezoelectric properties of ceramics were investigated. the ceramics with B-site columbite precursors at temperature of 1,100℃ obtained the optimal values of d33=272 [pC/N], kp=0.51, Qm=102, εr=978.

In this work, [Pb(Mg1/2W1/2)0.03(Ni1/3Nb2/3)x(Zr0.5Ti0.5)0.97-xO3-BiFeO3] (x=0.02 to 0.12) composition ceramics were fabricated by the conventional soild state reaction method and their microstructure and piezoelectric properties were investigated according to PNN substitution. The addition of small amount of BiFeO3, Li2CO3, and CaCO3 were used in order to decrease the sintering temperature of the ceramics. The XRD (x-ray diffraction patterns) of all ceramics exhibited a perovskite structure. The sinterability of PMW-PNN-PZT-BF ceramics was remarkably improved using liquid phase sintering of CaCO3, Li2CO3. However, it was identified from of the X-ray diffraction patterns that the secondary phase formed in grain boundaries decreased the piezoelectric properties. According to the substitution of PNN, the crystal structure of ceramics is transformed gradually from a tetragonal to rhombohedral phase. The x=0.10 mol PNN-substituted PMW-PNN-PZT-BF ceramics sintered at 920 showed the optimum values of piezoelectric constant(d33), piezoelectric figure of merit(d33·g33), planar piezoelectric coupling coefficient(kp) and density : d33=566 [pC/N], g33=29.28 [10-3mV/N], d33·g33=16.57 [pm2/N], kp=0.61, density=7.82 [g/cm3], suitable forduplex ultrasonic sensor application.

In this study, we investigate the effect of high-energy ball milling on thermoelectric transport properties in double-filled CoSb3 skutterudite (In0.2Yb0.1Co4Sb12). In0.2Yb0.1Co4Sb12 powders are milled using high-energy ball milling for different periods of time (0, 5, 10, and 20 min), and the milled powders are consolidated into bulk samples by spark plasma sintering. Microstructure analysis shows that the high-energy ball milled bulk samples are composed of nano- and micro-grains. Because the filling fractions are reduced in the bulk samples due to the kinetic energy of the high-energy ball milling, the carrier concentration of the bulk samples decreases with the ball milling time. Furthermore, the mobility of the bulk samples also decreases with the ball milling time due to enhanced grain boundary scattering of electrons. Reduction of electrical conductivity by ball milling has a decisive effect on thermoelectric transport in the bulk samples, power factor decreases with the ball milling time.

In this paper, in order to develop the composition ceramics with the outstanding piezoelectric properties, (Mg_{1/2} W _{1/2} )_{0.03} (OWNS_{1/3} Nb_{2/3})_{0.09} (Zr_{0.5} Ti_{0.5})_{0.88} O_{3} ceramics substituted with BiFeO_{3} were prepared by the conventional solid-state reaction method. The addition of small amount of Li2CO_{3} and CaCO_{3} as sintering aids decreased the sintering temperature of the ceramics. The effects of BiFeO3 substitution on their piezoelectric and dielectric properties were investigated. when 0.015 mol BiFeO_{3} was substituted, the optimal physical properties of d33=590 pC/N, Ec=8.78 kV/mm were obtained.

In this study, in order to develop the capacitor composition ceramics with the good dielectric properties, (Ba0.86Ca0.14)(Ti0.85Zr0.12Sn0.03)O3+ xCuO (x= 0.006~0.010) ceramics were prepared by the conventional solid-state reaction method. The effects of CuO addition on the microstructure and dielectric properties was investigated. All specimens indicated rhombohedra1 phase without any secondary phase. As CuO addition increased, the variation width of TCC was increased at more than 40°C. Also, the specimen with x=0.007 sintered at 1,250°C showed the high dielectric constant of 9,632 in spite of low temperature sintering temperature.

In this study, (1-x)Pb(Mg1/2W1/2)0.03(Ni1/3Nb2/3)0.09(Zr0.5Ti0.5)0.88O3 + xCeMnO3 (x= 0∼0.02) ceramics were prepared by Columbite precursor method. The phase structure, ferroelectric and piezoelectric properties were systematically investigated. It was found that PMW-PNN-PZT possessed superior electrical properties due to its composition close to the MPB (morphotropic phase boundary). Coercive electric field of 10.05 [kV/cm] and density of 7.88 [g/cm3] were obtained when the substitution amount of CeMnO3 is x=0.02. In contrast, specimens with x=0.01 showed the mechanical quality factor(Qm) of 1,091 and the electromechanical coupling factor(kp) of 0.613.

In this paper, in order to develop the composition ceramics with the excellent dielectric properties, Pb(Mg1/2W1/2)0.03(Ni1/3Nb2/3)0.09(Zr0.5Ti0.5)0.88O3 ceramics were fabricated by the conventional solid-state method. The effects of ZnO addition on their microstructure and piezoelectric properties were systematically investigated. The rhombohedral-tetragonal phase coexistence has been found in the ceramics without ZnO content and then with further increasing ZnO content, specimens exhibited tetragonal phase. The optimized ZnO content formed liquid phase and aided the grain growth of specimens. When 0.4 wt% ZnO was added, the optimal physical properties (d33= 422pC/N, d31= 161 pC/N, εr= 1,905, kp= 0.55, Qm= 160) were obtained.

(Na,K)NbO3-based piezoelectric ceramics were synthesized by a solid phase sintering method with various milling solvents. The solvents were varied with acetone, ethanol, and pure water to investigate the effect on the microstructure and electrical properties. NKN ceramics showed the maximum values of the relative density (94%), the mechanical quality factor (Qm: 78) and the electro-mechanical coupling factor (kp: 0.25) at the ethanol solvent. It might mean that a solid phase sintering of the NKN piezoelectrics with a suitable solvent could improve the relative density and the piezoelectric properties.