Metamaterials, as artificially engineered structures with unconventional mechanical and acoustic properties, have recently emerged as a transformative platform for enhancing the capabilities of triboelectric nanogenerator (TENG) systems. Since the invention of TENG devices, extensive efforts have been devoted to improving charge density, output stability, and overall performance. Conventional performance optimization strategies mainly rely on device-level improvements such as surface chemistry modification, microstructuring, and nanopatterning. However, limited emphasis has been given to system-level development of smart self-powered intelligent systems. The integration of metamaterials into TENG devices opens a new era by enabling frequency-selective localization, mechanical impedance matching, and controllable deformation pathways. These engineered mechanical structures not only improve energy harvesting efficiency but also introduce new functionalities into the system. This review systematically summarizes recent advances in metamaterial-integrated TENG systems across four major application domains: (i) energy harvesting, (ii) acoustic telecommunication and acoustic-to-electric conversion, (iii) self-powered sensing, and (iv) vibration suppression and monitoring. Overall, the integration of metamaterials into TENG systems will pave the way for next-generation sustainable, intelligent, self-powered devices with diverse functionalities.
Cellulose nanofiber (CNF) has attracted significant attention as a next-generation insulating material due to its ecofriendly nature and outstanding functionalities. However, conventional kraft insulation paper suffers from limited dielectric breakdown strength and long-term reliability under high-voltage conditions, highlighting the need for alternative materials. In this study, kraft pulp was combined with five types of CNFs (A, B, C: wood-based / D, E: non-wood-based) to fabricate composite insulation papers, and their electrical and mechanical properties were systematically evaluated. The results showed that CNF incorporation generally enhanced density and tensile strength, while certain types contributed to lowering dielectric constant and improving breakdown strength. Among the wood-based CNFs, type C exhibited the most balanced performance in terms of dielectric stability and mechanical reinforcement. Among the non-wood-based CNFs, type E demonstrated notable improvements in structural compactness and tensile strength, suggesting favorable reliability. Therefore, this study identifies CNF C among wood-based types and CNF E among non-wood-based types as the most promising candidates for insulation performance enhancement, suggesting their applicability as next-generation insulating materials for power equipment and ecofriendly electronic devices.
The laser (LASER), originating from the principle of stimulated emission proposed by Albert Einstein, has been a catalyst for substantial advancements across numerous industrial and scientific domains. Initially confined to research and laboratory applications, the scope of laser technology has expanded rapidly over time. This expansion is primarily due to the laser's unique characteristics, such as high-density energy output and precise beam control, which have facilitated its widespread integration into contemporary industrial practices. Specifically, laser materials processing technology enables the machining of diverse materials, including metals, ceramics, and polymers, in a non-contact manner, thereby achieving high precision without the risk of wear or contamination. As a result, laser processing has become indispensable in fields such as advanced electronics manufacturing, medical device production, aerospace, and the automotive industry. Furthermore, laser materials processing exhibits significant potential for high-precision applications that demand minimal thermal deformation of materials, such as microfabrication and the production of complex geometries. This paper provides a comprehensive examination of the development and necessity of laser processing technology, explores various laser types and their possible applications, and elucidates why laser technology has emerged as a fundamental component of modern manufacturing, alongside its trajectory for future development.
Quantum computing is set to transform the field of materials science, offering computational methods that could far surpass conventional approaches for tackling intricate material design challenges. This review introduces the foundational principles of rapidly growing quantum computing and its application trends in the design and analysis of nanomaterials. We explain how quantum speedup, achieved through quantum algorithms utilizing qubit superposition and entanglement, is applied to material design. Additionally, the principles and research trends of quantum variational methods, including the Variational Quantum Eigensolver (VQE), which has recently gained attention as a quantum algorithm simulation technique, will be discussed. By combining new techniques based on quantum algorithms with the quantum speed-up, the quantum computing is expected to offer new insights into data-intensive materials research and provide innovative methodologies for the development of new functional materials. With the advancement of quantum algorithms, the field of materials science could enter a new era, enabling more precise and efficient approaches in materials design and functional analysis.
Understanding the structure-property relationship in functional materials is crucial as microstructural features such as nano-precipitates, phase boundary, grain boundary segregation, and grain boundary phases play a key role in their functional properties. Atom probe tomography (APT) is an advanced analytical technique that allows for the three-dimensional (3D) mapping of atomic distributions and the precise determination of local chemical compositions in materials. Moreover, it offers sub-nanometer spatial resolution and chemical sensitivity at the tens of parts per million (ppm) level. Owing to its unique capabilities, this technique has been employed to uncover the 3D elemental distributions in a wide range of materials, including alloys, semiconductors, nanomaterials, and even biomaterials. In this paper, various kinds of examples are introduced for elucidating structure-property relationships on functional materials by utilizing the atom probe tomography.
This paper is an experimental study on the improvement of smoke and flame detection from different materials with YOLO. For the study, images of fires occurring in various materials were collected through an open dataset, and experiments were conducted by changing the main factors affecting the performance of the fire object detection model, such as the bounding box, polygon, and data augmentation of the collected image open dataset during data preprocessing. To evaluate the model performance, we calculated the values of precision, recall, F1Score, mAP, and FPS for each condition, and compared the performance of each model based on these values. We also analyzed the changes in model performance due to the data preprocessing method to derive the conditions that have the greatest impact on improving the performance of the fire object detection model. The experimental results showed that for the fire object detection model using the YOLOv5s6.0 model, data augmentation that can change the color of the flame, such as saturation, brightness, and exposure, is most effective in improving the performance of the fire object detection model. The real-time fire object detection model developed in this study can be applied to equipment such as existing CCTV, and it is believed that it can contribute to minimizing fire damage by enabling early detection of fires occurring in various materials.
Titanium dioxide (TiO₂) holds significant scientific and technological relevance as a key photocatalyst and resistive random-access memory, demonstrating unique physicochemical properties and serving as an n-type semiconductor. Understanding the density and arrangement of oxygen vacancies (VOs) is crucial for tailoring TiO₂’s properties to diverse technological needs, driving increased interest in exploring oxygen vacancy complexes and superstructures. In this mini review, we summarize the recent understandings of the fundamental properties of oxygen vacancies in bulk rutile (R-TiO₂) and anatase (A-TiO₂) based on DFT and beyond method. We specifically focus on the excess electrons and their spatial arrangement of disordered single VO in bulk R and A-TiO₂, aligned with the experimental findings. We also highlight the theoretical works on investigating the geometries and stabilities of ordered VOs complexes in bulk TiO₂. This comprehensive review provides insights into the fundamental properties of excess electrons in reduced TiO₂, offering valuable perspectives for future research and technological advancements in TiO₂-based devices.
Recently, with the development of the smart device market, the integration of high-functional devices has increased the heat density, causing overload of the device, and resulting in various problems such as shortened lifespan, performance degradation, and failure. Therefore, research on heat dissipation materials is being actively conducted to realize next-generation electronic products. The heat dissipation material is characterized in that it is easy to dissipate heat due to its high thermal conductivity and minimizes leakage current flowing through the heat dissipation material due to its low electrical conductivity. In this study, flower-shaped Al2O3 and BN composites were engineered with a simple hydrothermal synthesis approach, and their thermal conductivity characteristics were compared and evaluated for each synthesis condition for the application to a heat dissipation material. Spherical BN and flower-shaped Al2O3 were easily obtained, and SEM/EDS analyses confirmed the uniform presence of BN between the Al2O3, and it can be expected that these shapes can affect the thermal conductivity.
The utilization of scanning transmission electron microscopy (STEM) in conjunction with cathodoluminescence (CL) has emerged as a valuable tool for the investigation of material optical properties. In recent years, this technique has facilitated significant advancements in the fields of plasmonics and quantum emitters by surpassing prior technical restrictions. The review commences by providing an outline of the diverse STEM-CL operating modes and technical aspects of the instrumentation. The review explains the fundamental physics of light production under electron beam irradiation and the physical basis for interpreting STEM-CL experiments for different types of excitations. Additionally, the review compares STEM-CL to other related techniques such as scanning electron microscope CL, photoluminescence, and electron energy-loss spectroscopy.
With the recent increase in demand for electronic devices, multi-layer ceramic capacitors (MLCCs) have become the most important core component. In particular, the next-generation MLCC with extremely high reliability is required for the 4th industrial revolution and electric vehicle applications. Therefore, it is necessary to develop dielectric ceramic materials with high dielectric properties and reliability. During the decades, electrical properties of BaTiO3 based dielectric ceramics, which have been widely used in MLCC industrial field, have been improved by microstructure and defect chemistry control. However, electrical properties of BaTiO3 have reached their limits, and new types of dielectric materials have been widely studied. Based on these backgrounds, this report presents the recent development trends of BaTiO3-based dielectric materials for the nextgeneration MLCCs, and suggests promising candidates to replace BaTiO3 ceramics.
[011] poled ternary Pb(In1/2Nb1/2)O3-Pb(Mg1/3Nb2/3)O3-PbTiO3 (PIN-PMN-PT) single crystals have been investigated for active materials for acoustic transducers because of their high piezoelectric properties in both shear and transverse modes. In order to use [011] poled PIN-PMN-PT single crystals for acoustic transducers, the characterization of full-matrix material properties is required. In this study, full sets of compliance, dielectric, and piezoelectric constants of [011] poled rhombohedral PIN-PMN-PT were measured by a resonance method. Dimensions and geometries of 12 samples were proposed for measuring 17 independent material constants of [011] poled rhombohedral PIN-PMN-PT single crystals. Two sets of samples with different PT concentrations, 0.24PIN-0.49PMN-0.27PT and 0.24PIN-0.46PMN-0.30PT, were fabricated and their material properties were measured. Measured impedance spectra and simulated impedance spectra of the samples were compared to check the accuracy of the measurements.
As the recent climate problems are getting worse year after year, the demands for clean energy materials have highly increased in modern society. However, the candidate material classes for clean energy expand rapidly and the outcomes are too complex to be interpreted at laboratory scale (e.g., multicomponent materials). In order to overcome these issues, the firstprinciples calculations are becoming attractive in the field of material science. The calculations can be performed rapidly using virtual environments without physical limitations in a vast candidate pool, and theory can address the origin of activity through the calculations of electronic structure of materials, even if the structure of material is too complex. Therefore, in terms of the latest trends, we report academic progress related to the first-principles calculations for design of efficient electrocatalysts. The basic background for theory and specific research examples are reported together with the perspective on the design of novel materials using first-principles calculations.
Non-volatile memory is approaching its fundamental limits with the Si3N4 storage layer, necessitating the use of alternative materials to achieve a higher programming/erasing speed, larger storage window, and better data retention at lower operating voltage. This limitation has restricted the development of the charge-trap memory, but can be addressed by using high-k dielectrics. The paper reviews the doping of nitrogen, titanium, and yttrium on high-k dielectrics as a storage layer by comparing MONOS devices with different storage layers. The results show that nitrogen doping increases the storage window of the Gd2O3 storage layer and improves its charge retention. Titanium doping can increase the charge capture rate of HfO2 storage layer. Yttrium doping increases the storage window of the BaTiO3 storage layer and improves its fatigue characteristics. Parameters such as the dielectric constant, leakage current, and speed of the memory device can be controlled by maintaining a suitable amount of external impurities in the device.
This paper reports the microstructure and electrochemical properties of Si-Al-Fe ternary amorphous alloys prepared by rapid solidification as an anode for lithium secondary batteries. The microstructure was analyzed using XRD and HR-TEM with EDS mapping. In accordance with DSC analysis, annealing was performed to crystallize the active nano-Si in the amorphous alloy. Thus, nano-Si forms (~80 nm) embedded in the matrix alloy, such as Fe2Al3Si3, FeSi2, and Fe0.42Si2.67, were successfully synthesized. The electrode based on the Si-Al-Fe ternary alloy delivered an initial discharge capacity of approximately 700 mAh g-1, and exhibited a high Coulombic efficiency of 99.0~99.6% from the 2nd to 70th cycles.
This work investigated the effects of different conductive agents on the electrochemical properties of anodes. SiOx possesses high theoretical capacity and shows excellent cycle performance; however, the low initial coulombic efficiency and poor electrical conductivity limit its applications in real batteries. In this study, electrodes were fabricated using two different conductive agents, and the resulting physical and electrochemical properties were analyzed. SEM observations confirmed the formation of a CNT conductive network throughout the electrodes, while the electrical conductivity contributed to the electrode was confirmed by impedance measurements. Thus, the electrode fabricated with the CNT conductive agent showed greater capacity and superior cycle performance than did the electrode fabricated using the DB conductive agent.
We researched about a bulk metallic glass system as an additive to an Ag paste for high temperature thermoelectric modules. Bulk metallic glass (BMG) ribbons were produced by using a rapid solidification process (RSP) under a cooling rate condition higher than 10℃/sec. We investigated BMG characteristics of the ribbons by means of x-ray diffraction (XRD) and differential scanning calorimetry (DSC) in order to evaluate the glass transition temperature (Tg) and the recrystallization temperature (Tx) lower than 400℃. A milling process was also developed to apply the BMG ribbons to a commercial Al paste as an additive for lower sintering temperature.
Two-dimensional (2D) materials such as transition metal dichalcogenides have attracted tremendous scientific interests owing to their potential of solving the zero band-gap issue of graphene. In this work, the research areas and technology evolutionary dynamics of the 2D materials were identified using the scientometric method focusing on keyword mapping and clustering. The time-series analysis showed that the technological progress of 2D material is in the early growth period. The overlay mapping analysis were carried out to investigate the technology evolution of 2D materials with time. The strategic diagram of co-word analysis classifying the topological positions of keyword was derived to support the analysis results. It is conjectured that extensive research will be conducted widely on the application of 2D materials not only in electronic and optoelectronic devices, but also in various other fields such as biomedical applications, and that their development will be more rapid based on accumulated results of extant graphene research.
Skutterudite materials show PGEC (phonon glass electron crystal) characteristics which is an optimal strategy for designing high performance thermoelectric materials. Now two methods are in parallel to control thermal conductivity of skutterudites, a rattler-atoms doping method and a process for nanostructured bulk materials. Amount of rattler atoms in p-type skutterudite are depends on a Fe/Co ratio of matrix, and the optimal Fe/Co ratio has been reported about from 3:1 to 3.5:0.5 in R(Fe,Co)₄Sb12 structure. In this paper, our discussion for rattler doping research was concentrated on double-rattler systems and DD-doped systems in p-type skutterudites. A melt spinning precess combined with high energy ball milling were suggested as a strategy for nanostructured bulk materials with PGEC (phonon glass electron crystal) characteristics in p-type skutterudites.
Molded insulation materials are widely used from large electric power transformer apparatus to small electrical machinery and apparatus. In this study, by adding MgO with the average particle of several tens nm and the excellent thermal conductivity into molding material, we improved the problem of insulation breakdown strength decrease according to rising temperature in overload or in bad environmental condition. We confirmed the life evaluation by using the insulation breakdown and inverse involution to investigate the electrical characteristics of nano-composites materials. By using a scanning electron microscope, it is confirmed that MgO power with the average particle size of several tens nm is distributed and the filler particles is uniformly distributed in the cross section of specimens. And it is confirmed that the insulation breakdown strength of Virgin specimens is rapidly decreased at the high temperature area. But it is confirmed that the insulation breakdown strength of specimens added MgO slow decreased by thermal properties in the high temperature area improved by the contribution of the heat radiation of MgO and the suppression of tree. The results of life prediction using inverse involution, it is confirmed that the life of nano-composites is improved by contribution of MgO according to the predicted insulation breakdown strength after 10 years of specimens added 5.0 wt% of MgO is increased about 2.9 times at RT, and 4.9 times at 100 than Virgin specimen, respectively.
A new information society of late has arrived by the rapid development of various information & communications technologies. Accordingly, mobile devices which are light and thin, easy and convenient to carry on the market. Also, the requirements for the larger television sets such as fast response speed, low-cost electric power, wider visual angle display are sufficiently satisfied. The currently most widely studied display material, the Organic Light-emitting Diodes(OLEDs) overwhelms the Liquid Crystal Display(LCD), the main occupier of the market. This new material features a response speed of more than a thousand times faster, no need of backlight, a low driving voltage, and no limit of view angle. And the OLEDs has high luminance efficiency and excellent durability and environment resistance, quite different from the inorganic LED light source. The OLEDs with simple device structure and easy produce can be manufactured in various shapes such as a point light source, a linear light source, a surface light source. This will surely dominate the market for the next generation lighting and display device. The new display utilizes not the glass substrate but the plastic one, resulting in the thin and flexible substrate that can be curved and flattened out as needed. In this paper, OLEDs device was produced by changing thickness of Teflon-AF of hole injection material layer. And as for the electrical properties, the four layer device of ITO/TPD/Alq3/BCP/LiF/Al and the five layer device of ITO/Teflon AF/TPD/Alq3/BCP/Lif/Al were studied experimentally.
New material design has obtained tremendous attention in material science community as the performance of new materials, especially in nano length scale, could be greatly improved to applied in modern industry. In certain conditions limiting experimental synthesis of these new materials, new approach by computer simulation has been proposed to be applied, being able to save time and cost. Recent development of computer systems with high speed, large memory, and parallel algorithms enables to analyze individual atoms using first principle calculation to predict quantum phenomena. Beyond the quantum level calculations, mesoscopic scale and continuum limit can be addressed either individually or together as a multi-scale approach. In this article, we introduced current endeavors on material design using analytical theory and computer simulations in multi-length scales and on multi-physical properties. Some of the physical phenomena was shown to be interconnected via a cross-link rule called ``cross-property relation``. It is suggested that the computer simulation approach by multi-physics analysis can be efficiently applied to design new materials for multi-functional characteristics.
The 0.99Bi0.5(Na0.78K0.22)0.5TiO3?0.01LaAlO3, 0.01LaMnO3 or 0.01LaFeO3 (0.99BNKT?0.01LA,0.01LM or 0.01LF) ceramics were prepared by a conventional mixed mothod. The structure andmorphology of the lead free ceramics were characterized by XRD (X-ray diffraction) and FE-SEM (fieldemission scanning electron microscopy). XRD results indicated that the BNKT ceramics modified by LA,LM or LF induced a transition from a ferroelectric tetragonal to a non-polar pseudo-cubic phase, leadingto decrease in the remnant polarization (Pr) and coercive field (Ec) in the P-E hysterisis loops. Theeffects of the BNKT ceramics modified by La-based ABO3 pervskite structure on the electric-fieldinduced strain were investigated, and the largest normalized unipolar strain (Smax/Emax) was found inBNKT-0.01LF ceramic.
The wind power generation is an eco-friendly clean energy that produces almost zero CO2emission, and has a good economic feasibility. As for the location, the installation of large turbines and construction of large-scale wind farm is easier on the offshore than on the land. In Korea, it is inevitable to generate offshore wind power through the offshore wind farm, and the radio interference of larger wind power generators and offshore wind power farm to broadcasting, communication and radars is becoming a core issue for constructing the offshore wind farm. In this study, the wind power generation status and rotor blade technology trend were presented, along with the technical trend of radar radio interference reduction relating to construction of the offshore wind farm.
This is the study on the development of fusion heat dissipation of carbon magnesium materials. The purpose of this study is for effective utilization of heat emission which is the core of LED lighting. The result of study enabled the derivation of side satisfying result of making the surface temperature of lighting to be below 70℃ (actual measurement: 58℃) using magnesium. The lighting products that use magnesium was made possible based on the result of this study. Also from the performance aspect such as light distribution, the measurement of light efficiency demonstrated the level of 90 lm/W. Therefore the commercialization of lighting was made possible and the efficiency could be further enhanced by supplementation of LED performance.
We introduced sensitizing dyes into the bulk-heterojunction (BHJ) photovoltaic (PV) layer of polymer solar cells (PSCs). The sensitizing dyes doped were Bis(tetra butyl ammonium) cis-dithio cyanato bis(2,2`-bipyridine-4-carboxylicacid-4`-carboxylate) ruthenium (II) (N719 dye) and the BHJ PV layer used was made of poly (3-hexylthiophene) (P3HT) and phenyl C61-butyric acid methyl ester (PCBM). It was found that the N719 dyes increase the photovoltaic performance, i.e., increasing open-circuit voltage and short-circuit current density with improved fill factor. For the P3HT: PCBM PV cells doped with the N719 dyes (0.24wt %), an increase in power conversion efficiency of 4.0% was achieved, compared to that of the control cells (3.6%) without the N719 dyes.
Nano-fibers of the Li[Ni1/3Co1/3Mn1/3]O2 electrode were synthesized from a metal oxide precursor using the electrospun method. The XRD patterns of all prepared powders showed a hexagonal α- NaFeO2 structure (space group: R-3 m, 166). Scanning electron microscopy showed that all the synthesized samples were comprised of nanofibers with a size of 100~800 nm. Among the samples tested, the calcined Li[Ni1/3Co1/3Mn1/3]O2 nanowires in oxygen heating atmosphere showed a high charge and discharge capacity of 239.22 and 172.81 mAhg-1 at the 1st cycle, respectively. In addition, the charge transfer resistance was also improved significantly compared to the other samples.
We introduced nanoscale interfacial layers between the PV layer and the cathode in poly (3-hexylthiophene):methanofullerene bulk-heterojunction polymer photovoltaic (PV) cells. The nanoscale double interfacial layers were made of ultrathin poly (oxyethylenetridecylether) surfactant and low-work-function alloy-metal of Al:Li layers. It was found that the nanoscale interfacial layers increase the photovoltaic performance, i.e., increasing short-circuit current density and fill factor with improved device stability. For PV cells with the nanoscale double interfacial layers, an increase in power conversion efficiency of 4.18 ± 0.24% was achieved, compared to that of the control devices (3.89 ± 0.08%) without the double interfacial layers.
In this study the (Alnico, Sm-Co) bonded magnets were fabricated by mixing the Sm-Co added alnico alloy powders with epoxy resin and binder, appropriately. Also, the hybrid ring magnets of (Alnico, Sm-Co)/Sr-ferrite were fabricated by coupling the Sr-ferrite composite layer with an (Alnico, Sm-Co) magnet. The magnetic properties of (Alnico, Sm-Co) ring magnets were varied with the amount of Sm-Co powders. The addition of Sm-Co powders increased a remanent induction(Br) and coercive force(BHC), while decreasing a surface flux density and repulsive distance. The surface flux density and repulsive distance for the (Alnico, Sm-Co) ring magnet increased with a magnetizing voltage up to about 160 V and reached an apparent saturation point. Also, the measurements of temperature and moisture characteristics showed that the surface flux densities of N-S poles and repulsive distance decreased a little within 4% after 10 days passed.
The yttrium-barium-copper-oxide (YBCO) coated conductor, which supplement the fault of the existing superconducting current-limit materials YBCO thin film, bismuth-strontium-calcium-copper-oxide(BSCCO) wire and bulk, has been improved its mechanical weakness and has high index; hence, after quench YBCO coated conductor could limit the fault current effectively because of fast resistance occurrence speed. Furthermore, it has wide applicable area as an current limit material because it shows different resistance occurrence tendency by the thickness and kind of stabilization material sputtered on the superconducting layer. Therefore, many researchers are carrying out the study of application of YBCO coated conductor to superconducting fault current limiter (SFCL) for making high quality current limit element, based on resistance type. On the other hand, the study for other type except resistance type has been rarely conducted for the application of YBCO coated conductor to SFCL as an current limit element. Consequently, in this study, YBCO coated conductor with different stabilization layer Cu and Stainless steel, is applied to SFCL using iron core and coil, and examine the many index points as an current limit element, such as current limit characteristic, the tendency of resistance occurrence, response time, the temperature trend for stability.