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Regular Paper

Effect of APS Dip-Coating Time on Interfacial Charge Transport in Dye-Sensitized Solar Cells
Jin Wook Lee, Minjae Shin, Byungyou Hong, Hyung Jin Kim
J Electr Electron Mater 2026;39(4):387-393.   Published online July 1, 2026
DOI: https://doi.org/10.4313/JEEM.2026.39.4.8
Dye-sensitized solar cells (DSSCs) suffer from efficiency limitations due to interfacial charge recombination at the TiO₂/dye/electrolyte interface. In this study, aminopropyltrimethoxysilane (APS) was introduced onto nanoporous TiO₂ photoelectrodes via a dip-coating process with controlled coating times to investigate the effect of silanization time on interfacial charge transport behavior. Unlike concentration-driven structural modification, this work focuses on the evolution of the APS-modified interface governed by reaction time. The DSSC with 30 min APS treatment exhibited the highest power conversion efficiency of 5.34%, representing a 19% enhancement compared to the untreated device (4.49%), mainly due to increased short-circuit current density and open-circuit voltage. However, prolonged coating times (2 h and 24 h) resulted in a significant decrease in photocurrent density, leading to reduced device performance despite partial improvement in recombination resistance. These results are attributed to the time-dependent evolution of the APS interfacial layer. At moderate coating time, APS provides effective surface functionalization, enhancing dye adsorption and suppressing interfacial recombination. In contrast, prolonged coating is expected to induce increased surface coverage and silane condensation, which can hinder electron injection and increase charge transport resistance. Therefore, the photovoltaic performance is governed by a trade-off between recombination suppression and charge injection efficiency, controlled by the silanization time. This study highlights the critical role of interfacial reaction kinetics in determining charge transport behavior and provides an effective strategy for optimizing DSSC performance through time-dependent interface engineering.
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Recent Advances in Artificial Synapses and Neurons Based on Organic Electrochemical Transistors
Hyunhak Jeong
J Electr Electron Mater 2026;39(2):147-162.
Published online March 1, 2026
DOI: https://doi.org/10.4313/JEEM.2026.39.2.4
Neuromorphic computing, which mimics the energy-efficient parallel processing capabilities of the human brain, has emerged as an alternative to traditional von Neumann architectures that struggle with high power consumption in the era of artificial intelligence (AI). Despite the potential of Si-based neuromorphic chips, they often face fundamental limitations in integration density and biological compatibility, necessitating the development of next-generation devices that can better emulate the ionic signaling of biological systems. This review provides a comprehensive analysis of the recent research trends in artificial synapses and neurons based on organic electrochemical transistors (OECTs), highlighting their unique ability to achieve high transconductance and mixed ionic-electronic conduction at ultra-low operating voltages. We discuss how OECTs successfully replicate diverse synaptic plasticities and complex neuronal spiking behaviors through advanced material engineering and structural optimizations such as vertical architectures. Furthermore, this review discusses the implementation of high-order neural functions, including associative learning and logic operations, which are facilitated by the inherent electrochemical dynamics of organic semiconductors. Finally, overcoming current challenges in reliability and scalability will establish OECTs as a pivotal platform for low-power neuromorphic hardware and bio-integrated electronics.
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Enhanced Electrical Stability of MoS₂ FETs with Sb₂Te₃ vdW Contacts via h-BN Encapsulation
Eun Bi Lee, Se Hee Lim, Jae Mo Yun, Yoon Kyeung Lee
J Electr Electron Mater 2026;39(2):217-223.
Published online March 1, 2026
DOI: https://doi.org/10.4313/JEEM.2026.39.2.12
MoS₂ has attracted significant attention as a next-generation semiconductor material to overcome the physical scaling limits of silicon-based devices due to its atomic thinness and excellent electrical properties. However, high contact resistance and the formation of Schottky barriers resulting from interface defects during the metal deposition process remain major bottlenecks that degrade overall device performance and reliability. In this study, we fabricated MoS₂ FETs by employing Sb₂Te₃, van der Waals (vdW) contacts. Minimized interface inhomogeneity was achieved through a hemispherical stamp-based dry transfer of h-BN for device encapsulation. h-BN encapsulation decreased the hysteresis window in the ±25 V gate voltage range from 17 V to 11.5 V compared to un-capped devices, confirming that charge trapping phenomena induced by external environmental factors were suppressed. Consequently, the dry transfer technique of h-BN using a hemispherical stamp demonstrated in this study provides a potential solution for securing the long-term reliability of MoS₂ devices with vdW contact by minimizing interface contamination.
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Encapsulation Strategies to Improve the Environmental Stability of Perovskite Nanocrystals
Jiwoo Hong, Sunghoon Kim
J Electr Electron Mater 2025;38(4):358-365.   Published online July 1, 2025
DOI: https://doi.org/10.4313/JKEM.2025.38.4.2
Metal halide perovskite materials have emerged as promising candidates for next-generation optoelectronic applications owing to their outstanding optical properties and tunable emission characteristics. However, their practical application is hindered by poor environmental stability, especially under conditions of heat, moisture, and UV exposure, necessitating effective encapsulation strategies. This review summarizes recent progress in enhancing the environmental stability of perovskite nanocrystals through polymer matrix embedding, inorganic oxide encapsulation, and compositionally matched core-shell structures using homogenous perovskite derivatives. We discuss how polymers enhance the environmental and moisture stability of perovskite nanocrystals, how oxide-based shells (e.g., SiO₂, TiO₂) contribute to thermal robustness and barrier protection, and how homostructural core-shells provide lattice-matched defect passivation with improved long-term durability. A comprehensive understanding of the advantages and limitations of each encapsulation strategy, along with their rational integration, can accelerate the commercialization of perovskite-based technologies in various applications such as highcolor- purity displays, color conversion filters, and flexible optoelectronic devices.
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Recent Progress of Light-Stimulated Synapse and Neuromorphic Devices
Seungho Song, Jeehoon Kim, Yong-hoon Kim
J Electr Electron Mater 2022;35(3):215-222.   Published online May 1, 2022
DOI: https://doi.org/10.4313/JKEM.2022.35.3.2
Artificial neuromorphic devices are considered the key component in realizing energy-efficient and brain-inspired computing systems. For the artificial neuromorphic devices, various material candidates and device architectures have been reported, including two-dimensional materials, metal-oxide semiconductors, organic semiconductors, and halide perovskite materials. In addition to conventional electrical neuromorphic devices, optoelectronic neuromorphic devices, which operate under a light stimulus, have received significant interest due to their potential advantages such as low power consumption, parallel processing, and high bandwidth. This article reviews the recent progress in optoelectronic neuromorphic devices using various active materials such as two-dimensional materials, metal-oxide semiconductors, organic semiconductors, and halide perovskites
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Display and Optical Devices : Evaluation of Driving Properties by Cell-gap Difference of Single Particle-Microcapsule Type Electronic Paper
Jin Seok Song, Young Cho Kim
J Electr Electron Mater 2015;28(8):518-523.   Published online August 1, 2015
We fabricate a single particle-microcapsule type electronic paper using electrophoresis, which is different with a reported dual particle-microcapsule type and of which electro-optical researches are not reported. So we analyzed a basic properties, such as reflectivity, response time, and driving voltage. Our display panels having various cell-gaps of 30 ㎛, 34 ㎛, 38 ㎛, 42 ㎛, and 46 ㎛ are inspected. As a results, a driving voltage is defined to 10 V and desirable cell-gap is 30 ㎛ or 34 ㎛. Considering a mechanical strength, the optimum cell-gap is 34 ㎛ for the single particle type electronic paper.
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Encapsulation Method of OLED with Organic-Inorganic Protective Thin Films Sealed with Metal Sheet
Su Young Lim, Jung Hyun Seo, Sung Hoo Ju
J Electr Electron Mater 2013;26(7):539-544.   Published online July 1, 2013
Abstract: To study the encapsulation method for heat dissipation of high brightness organic light emitting diode (OLEI)), red emitting OLED of ITO (150 nm) / 2 TNATA (50 rim) / NPB (30 rim) / A1q3 1 vol.% Rubrene (30 nm) / Alq3 (30 nm) / LiF (0.7 nm) / Al (200 nm) structure was fabricated, which on Alq3 (150 nm) / LiF (ISo nm) as buffer layer and Al as protective layer was deposited to protect the damage of OLED, and subsequently it was encapsulated using attaching film and metal sheet. The current density, luminance and power efficiency was improved according to thickness of Al protective layer. The emission spectrum and the Commission International de L`Eclairage (CIE) coordinate did not have any effects on encapsulation process using attaching film and metal sheet The lifetime of encapsulated OLED using attaching film and metal sheet was 307 hours in 1,200 nm Al thickness, which was increased according to thickness of Al protective layer, and was improved 7% compared with 287 hours, lifetime of encapsulated OLEI) using attaching film and flat glass. As a result, it showed the improved current density, luminance, power efficiency and the long lifetime, because the encapsulation method using attaching film and metal sheet could radiate the heat on OLED effectively.
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Diameter controlled carbon nanotubes (CNTs) were grown using surface modified iron nano-particle catalysts with aminpropyltriethoxysilane (ASP). Iron nano-particles were synthesized by thermal decomposition of iron pentacarbonyl-oleic acid complex. Subsequently, APS modification was done using the iron nano-particles synthesized. Agglomeration of the iron nano-particles during the CNT growth process was dffectively prevented by the surface modification of nano-particles with the ASP. Plays as a linker material between Fe nano-particles and SiO₂ substrate resulting in blocking the migration of nano-particles. ASP also formed siliceous material covering iron nano-particles that prevented agglomeration of iron nano- particles at the early stages of the CNT growth. Therefore we could obtain the diameter controlled CNTs by blocking agglomeration of iron nano-particles.
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Light Source and Application Technology : Effect of Curing Method on the Reliability of Silicone Encapsulant for Light Emitting Diode
Wan Ho Kim, Min Suk Jang, Young Rae Kang, Ki Hyun Kim, Sang Bin Song, In Seon Yeo, Jae Pil Kim
J Electr Electron Mater 2012;25(10):844-848.   Published online October 1, 2012
Encapsulant curing in terms of convection oven leads to thermal induced stress due to nonuniform thermal conductivity in LED package. We have adopted infrared (IR) light for silicone curing in order to release the stress. The light uniformity irradiated on an encapsulant surface is confirmed to be uniform by optical simulation. Shear strength of die paste using IR compared to convection oven is increased 19.2% at the same curing time, which indicates curing time can be shortened. The indentation depth difference between center and edge of silicone encapsulant in terms of convection oven and IR are 14.8% and 3.4%, respectively. Curing by IR also shows 2.3% better radiant flux persistency rate of LED at 85℃ after 1,000 h reliability test compared to convection curing.
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Light Source and Application Technology : Enhancement of Light Extraction in White LED by Double Molding
Min Suk Jang, Wan Ho Kim, Young Rea Kang, Ki Hyun Kim, Sang Bin Song, Jin Hyuk Kim, Jae Pil Kim
J Electr Electron Mater 2012;25(10):849-856.   Published online October 1, 2012
Chip on board type white light emitting diode on metal core printed circuit board with high thixotropy silicone is fabricated by vacuum printing encapsulation system. Encapsulant is chosen by taking into account experimental results from differential scanning calorimeter, shearing strength, and optical transmittance. We have observed that radiant flux and package efficacy are increased from 336mW to 450mW and from 11.9 lm/W to 36.2 lm/W as single dome diameter is varied from 2.2 mm to 2.8 mm, respectively, Double encapsulation structure with 2.8 mm of dome diameter shows further significant enhancement of radiant flux and package efficacy to 667mW and 52.4 lm/W, which are 417mW and 34.8 lm/W at single encapsulation structure, respectively.
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Encapsulation Method of OLED with Organic-inorganic Protective Thin Films Sealed with Flat Glass
Min Kyung Park, Sung Hoo Ju
J Electr Electron Mater 2012;25(5):381-386.   Published online May 1, 2012
To study encapsulation method for large-area organic light emitting diodes (OLEDs), red emitting OLEDs were fabricated, on which Alq3 as organic buffer layer and LiF and Al as inorganic protective layers were deposited to protect the damage of OLED by epoxy. And then the OLEDs were attached to flat glass by printing method using epoxy. The basic structure of OLED doped with rubrene of 1 vol.% as emitting layer is ITO(150 ㎚)/2-TNATA(50 ㎚)/α-NPD(30 ㎚)/Alq3:Rubrene(30 ㎚)/Alq3(30 ㎚)/LiF(0.7 ㎚)/Al(100 ㎚). In case of depositing Alq3, LiF and Al and then attaching of flat glass onto OLED, current density, luminance, efficiency and driving voltage were not changed and lifetime was increased according to thickness of Al as inorganic protective layers. The lifetime of OLED/Alq3/LiF/Al_4/glass structure was 139 hours increased by 15.8 times more than bare OLED of 8.8 hours and 1.6 times more than edge sealed OLED of 54.5 hours.
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Encapsulation Method of OLED with Inorganic Multi-Layered Thin Films Sealed with Flat Glass
Min Kyung Park, Sung Hoo Ju, Jae Woong Yang, Kyeong Kap Paek
J Electr Electron Mater 2011;24(11):905-910.   Published online November 1, 2011
To study encapsulation method for large-area organic light emitting diodes (OLEDs), red emitting OLEDs were fabricated, on which LiF and Al were deposited as inorganic protective films. And then the OLED was attached to flat glass by printing method using epoxy. In case of direct coating of epoxy onto OLED by printing method, luminance and current efficiency were remarkably decreased because of the damage to the OLED by epoxy. In case of depositing LiF and Al as inorganic protective films and then coating of epoxy onto OLED, luminance and current efficiency were not changed. OLED lifetime was more increased through inorganic protective films between OLED and flat glass than that without any encapsulation (8.8 h), i.e., 47 (LiF/Al/epoxy/glass), 62 (LiF/Al/LiF/epoxy/glass), and 84 h (LiF/Al/Al/epoxy/glass). The characteristics of OLED encapsulated with inorganic protective films (attached to flat glass) showed the possibility of application of protective films.
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Temperature-dependent Resistance Change of Conductive CNT Thin-film
Min Kyu Kwon, Yong Taek Hong
J Electr Electron Mater 2009;22(2):151-157.   Published online February 1, 2009
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Characteristics of the Photonic Bandgaps in Two-dimensional Photonic Crystals with a Square Lattice by FDTD Simulation
Jong Bin Yeo, Hoe Young Yang, Hyun Yong Lee
J Electr Electron Mater 2009;22(1):61-66.   Published online January 1, 2009
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Encapsulation of Fullerenes in Single-walled Carbon Nanotubes and their Characteristic Analysis by Raman Spectroscopy
Jeung Choon Goak, Nae Sung Lee
J Electr Electron Mater 2008;21(2):118-125.   Published online February 1, 2008
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Improvement of Permeation of Solvent-free Multi-Layer Encapsulation of Thin Films on Polyethylene Terephthalate(PET)
J Electr Electron Mater 2006;19(8):754-757.   Published online August 1, 2006
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Passivation Properties of SiNx Thin Film for OLED Device
J Electr Electron Mater 2006;19(8):758-763.   Published online August 1, 2006
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Improvement of Permeation of Applied Multi-Layer Encapsulation of Thin Films on Ethylene Terephthalate(PET)
J Electr Electron Mater 2006;19(3):255-259.   Published online March 1, 2006
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Characteristics of Defects in SiOx Thin Films on Ethylene Terephthalate by High-temperature E-beam Deposition
J Electr Electron Mater 2006;19(1):71-74.   Published online January 1, 2006
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Display,Optical Devices : The Effect of Encapsulation Layer Incorporated into Polymer Substrates for Bending Stress
Jun Baeg Park, Dae Sig Seo, Sang Geug Lee, Jun Ung Lee, Yeong Hun Kim, Dae Gyu Mun, Jeong In Han
J Electr Electron Mater 2004;17(4):443-447.   Published online April 1, 2004
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A Study on the Optical Properties of HgGa2S4 Single Crystal
Gwan Gyo Lee, Sang Yeol Lee, Jong Ug Kang, Bong Ju Lee, Hyeong Gon Kim, Seung Cheol Hyeon, Tae Hwan Bang
J Electr Electron Mater 2003;16(11):969-974.   Published online November 1, 2003
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