The development of a large-area solution process for CuO nanowires, which are promising p-type thin film transistors (TFT) channel materials, is required. To overcome the limitations of the existing high-vacuum and high-cost deposition process, a large-area Cu nanowire network was formed on the substrate using the Mayer rod coating method, and a CuO channel was implemented by subsequent thermal annealing. Consequently, p-type TFT with an on/off current ratio of 1.4×104 and a field-effect mobility µFE≈10-4 cm2/(V⋅s). was fabricated and optimized. X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) analyses showed that the sample annealed at 200°C exhibited an incomplete oxidation state with a mixed Cu/Cu2O phase and a high fraction of M-OH species (58.78%), resulting in a low on/off current ratio (≈1.2). In contrast, annealing at 450°C leads to a CuOdominant phase, where the fraction of lattice oxygen(O1) increases to 31.11% and the oxygen vacancy (VO) component increases to 7.15%, indicating a significant improvement in hole concentration and charge transport. These phase transitions and surface chemical changes are identified as the key mechanisms for the enhanced TFT switching characteristics. The low-cost, large-area Mayer rodbased solution process proposed in this study provides a basic process platform for p-type TFTs applicable to flexible wearables and display technologies and suggests the possibility of commercialization through additional optimization of bias stability in the future.
In this study, copper oxide thin films were fabricated by facing target sputtering system and their structural, optical, and electrical properties were investigated. Crystal phase of samples were changed by variation of oxygen flow rate from Cu to Cu₂O and CuO. Compared to Cu metal film, electrical properties of Cu₂O and CuO were relatively degraded, however, asfabricated Cu₂O and CuO indicated still low resistivity (~10-3 Ω·cm) and high carrier concentration (~1019 cm-3). From the results, it is thought that the copper oxide thin films Cu₂O fabricated under optimal conditions can be applied to various optoelectronic devices including ultraviolet photodetector.
In this study, we fabricated single grain YBCO bulk superconductors with control of the distance between the seed and the upper surface of the YBCO compacts. The magnetic levitation force of the YBa2Cu3O7 superconducting bulk, which corresponds to the energy amount of the superconducting bulk, was measured to be 32.634 N at the center of the bulk where the seed was placed. Under field cooling conditions, a capture magnetic force of 2.17 kG was observed at the center of the bulk. The trapped magnetic force curve corresponding to the stability of the superconducting bulk means that the superconducting specimens were well grown in the form of single grains.
This aim of this study was to develop a process for creating bulk single-crystal YBaCuO superconductors in a high magnetic field. To support the bulk unidirectional growth of YBa2Cu3O7-y, SmBa2Cu3O7-y seeds were planted inside YBaCuO composites and samples were produced by melting, enabling the growth of two YBaCuO superconductors. Due to the magnetism generated inside the superconductor of the upper sample, the magnetization inside the superconducting single crystals was evenly distributed, the sharpness of the induced magnetic force was improved, and the superconducting magnetization were significantly improved. This approach is widely applicable for the production of superconducting wires and current leads used for DC power breakers.
In this research, the development of fabrication technique of bulk YBaCuO superconductors for application was studied. In fluence of BaZrO3 addition on magnetization characteristics of thermal pyrolysis textured YBaCuO superconductor was investigated. Fine BaZrO3 particle were dispersed within the textured YBaCuO matrix by means of the thermal pyrolysis processing. Magnetic levitation force for YBaCuO superconductors were obtained using Nd-B-Fe permanent magnet, at 77 K and at the magnetic field from 0 to 5.3 K gauss. In the unadded superconductor and 5 wt% BaZrO3 addition, anomalous magnetization behavior, which is characterized by the intermediate magnetic field, was observed at 77 K. Critical current density was about few hundreds A/㎠ and the magnetic characteristics increased slightly by addition of BaZrO3 powder. Maximum magnetic force was obtained in the YBaCuO superconducting bulk with 3 wt.% BaZrO3 addition.
In this study, p-type thin film transistors consisting of CuO channels were fabricated by sol-gel process, with copper (II) acetate monohydrate precursors. At 500℃, the deposited films were fully converted into monoclinic phase CuO. The fabricated CuO thin film transistors deliver field effect mobility in saturation regime of 0.015㎠/Vs, and Ion/Ioff of ~10³. The degradation of the performance of the fabricated CuO thin film transistor caused by the exposure to air has been studied.
In this paper, piezoelectric ceramics with the composition of (Na0.525K0.4425Li0.0375)(Nb0.8975Sb0.065Ta0.0375)O3 + 0.3 wt% CoO + x CuO (0.005≤x≤0.025) (abbreviated to NKL-NST) were fabricated for ultrasonic sensor application. The effects of CuO addition and sintering on the microstructure and the piezoelectric properties of the NKL-NST ceramics were systematically studied. Excellent piezoelectric properties such as electromchanical coupling factor(kp) = 0.415, piezoelectric constant (d33) =166 pC/N and piezoelectric figure of merit d33*g33= 5.47 pm2/N were obtained from the 2.5 mol% CuO doped NKL-NST+0.3 wt%CoO ceramics sintered at 1,000℃ for 3 h.
The effects of Al-substitution on thermoelectric and charge transport properties of BiCuOSe compounds were investigated. The compounds were prepared by a solid-state reaction and consolidated by SPS (spark plasma sintering). In spite of the increase in the hole concentration with increasing Al amounts in BiCuOSe compound, the electrical conductivity at room temperature was kept constant due to the reduction of mobility. However, electrical conductivities of Al-substituted BiCuOSe compounds at elevated temperature (> 600 K) were higher than those of BiCuOSe, and this result was discussed in terms of it``s the band gap energy. The Seebeck coefficient was drastically reduced when Al was substituted in Bi site, which indicated that the electronic structure was influenced by the Al-substitution into Bi-site.
In this paper, in order to develop outstanding Pb-free piezoelectric composition ceramics, the (Na0.525K0.443Li0.037)(Nb0.883Sb0.08Ta0.037)O3 + 0.3 wt%Bi2O3 + 0.4 wt%Fe2O3 + x wt%CuO (x= 0∼0.8 wt%)(abbreviated as NKL-NST) lead-free piezoelectric ceramics have been synthesized using the ordinary solid state reaction method. The effects of CuO-doping on the structure and electrical properties of the NKL-NST ceramics were systematically studied. The results show that the ceramics exhibit a pure perovskite structure with orthorhombic phase at room temperature, and secondary phase was found in the ceramics. The 0.4 wt%CuO added ceramics sintered at 950℃ showed the optimum properties of piezoelectric constant(d33), planar piezoelectric coupling coefficient(kp) and mechanical quality factor(Qm) : d33= 213 [pC/N], kp= 0.43, Qm= 423,respectively.
We investigated the dielectric relaxation properties 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 ceramics with CuO addition. With increasing CuO addition, the lattice parameter was increased by substitution of small amount Cu2+ ion in B-site of 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 ceramics. Also the grain size and the maximum dielectric constant of 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 ceramics was decreased with increasing amounts of CuO addition. Moreover, the diffused phase transition properties (γ) of 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 ceramics was increased by compositional fluctuation with increasing of CuO amount, changed from 1.45 at 1 wt% CuO addition to 1.94 at 7 wt% CuO addition.
(Na0.525K0.4425Li0.0375)(Nb0.9975Sb0.065Ta0.0375)O3 + 0.3 wt%CoO ceramics were fabricated as a functionof CuO addition by traditional solid state sintering process in order to develop excellent lead-freepiezoelectric ceramics composition. The addition of CuO in the LNKNTS composition ceramics caneffectively enhance the densification of the ceramics, resulting in the oxygen vacancies as hardeningeffect. The excellent piezoelectric properties of electromechanical coupling factor(kP) of 0.378, piezoelectricconstant(d33) of 152 pC/N were obtained from the 1.0 mol% CuO doped LNKNTS ceramics sintered at1,020℃ for 3 h.
In this research, nanocomposite layers consisting of poly (3,4,-ethylene dioxythiophene):polystyrene sulfonic acid (PEDOT:PSS) and CuO nanoparticles were investigated as hole transport layers in organic solar cells based on poly (3-hexylthiophene) (P3HT) as the electron donor and (6.6) phenyl-C61-butyric acid methyl ester (PCBM) as the electron acceptor. The addition of CuO nanoparticles to PEDOT:PSS layer improved the solar cell performance with 0.5% CuO nanoparticle concentration. At optimized concentration, CuO mixed PEDOT:PSS films had good electrical (4.131 Ω?cm) and optical (transmittance > 90%) properties for using hole transporting layer. We investigated that improved solar cell performance with CuO nanoparticles mixed PEDOT:PSS films.
Additions (ZnO, CuO) doped 0.98(Na0.5K0.5)NbO3-0.02Li(Sb0.17Ta0.83)O3 (0.98NKN-0.02LST-x) lead free piezoelectric ceramics have been fabricated by ordinary sintering technique. The effects of additions doping on the dielectric, piezoelectric, and ferroelectric properties of the ceramics were mainly investigated. X-ray diffraction of the sample appeared orthorhombic phase. The specimen doped with additions exhibits enhanced electrical properties (d33= 153 pC/N). These results indicate that the 0.98NKN-0.02LST-x ceramics is a promising candidate for lead-free piezoelectric ceramics for applications such as piezoelectric actuators, harmonic oscillator and so on.
Abstract: The 0.98 (Na0.44K0.52)Nb0.84O3-0.02Li0.04 (Sb0.06Ta0.1)O3-0.5 mol%CuO ceramics have been fabircated by ordinary sintering technique and the effect of various calcination method on the electrical propertis and microstructure have been studied. It was observed that the various calcination method influenced the elelctrical properties and structural properties of the 0.98NKN-0.02LST-0.5 mol%CuO ceramics with the optimum piezoelectric constant (d33) and electromechanical coupling factor (kp) at room temperature of about 155ρC/N and 0.349, respectively, from 0.98NKN-0.02LST-0.5 mol%CuO ceramics sample. The curie temperature (Tc) of this ceramic was found at 440℃. The 0.98NKN-0.02LST-0.5 mol%CuO ceramics are a promising lead-free piezoelectric ceramics.