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Solvent-Dependent Crystallization and Charge Transport Evolution in Thermally Annealed P3HT:PCBM Bulk Heterojunction Solar Cells
Dong-Kyun Kim, Byungyou Hong, Hyung Jin Kim
J Electr Electron Mater 2026;39(4):400-406.   Published online July 1, 2026
DOI: https://doi.org/10.4313/JEEM.2026.39.4.10
Organic solar cells based on bulk heterojunction (BHJ) structures have attracted considerable attention because of their low fabrication cost, mechanical flexibility, and compatibility with solution-processing techniques. In BHJ organic photovoltaic devices, nanoscale morphology and crystallinity of the photoactive layer critically influence photovoltaic performance. In this study, the effects of solvent selection and thermal annealing on crystallization evolution and photovoltaic characteristics of P3HT:PCBM organic solar cells were systematically investigated. Three different solvents, including toluene, chlorobenzene (CB), and dichlorobenzene (DCB), were employed for active-layer fabrication, followed by post-thermal annealing treatment. UV–visible absorption spectroscopy revealed solvent-dependent differences in molecular ordering and intermolecular π–π interactions within the active layer. X-ray diffraction analysis confirmed that thermal annealing significantly enhanced crystallinity and lamellar ordering of P3HT domains, particularly for CB-processed films. Electrical characterization demonstrated that solvent evaporation behavior strongly affects photovoltaic performance. Among the investigated devices, the thermally annealed CB-processed device exhibited the highest power conversion efficiency of 1.83% with an enhanced short-circuit current density of 7.057 mA cm⁻². The improved device performance is attributed to optimized crystallization behavior and balanced nanoscale phase separation induced by the moderate evaporation characteristics of CB. In contrast, although DCB-assisted films exhibited relatively strong optical absorption and enhanced crystallinity, excessively slow solvent evaporation likely induced excessive aggregation and coarse phase separation, limiting efficient photovoltaic characteristics. These results demonstrate that solvent engineering combined with thermal annealing is an effective strategy for controlling morphology evolution and crystallization behavior in P3HT:PCBM bulk heterojunction solar cells.
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Recent Advances on Layered Double Hydroxide Catalysts for Electrochemical Nitrate to Ammonia Conversion
Yun-ji Nam, Bu-gyeong Son, Hwi-su Ji, Keon-han Kim
J Electr Electron Mater 2026;39(2):111-121.
Published online March 1, 2026
DOI: https://doi.org/10.4313/JEEM.2026.39.2.1
This review systematically examines the structural characteristics, compositional design strategies, and recent research trends of layered double hydroxides (LDHs), which are recognized as promising electrocatalyst materials in electrochemical nitrate-to-ammonia conversion. Despite the rapid growth in related research, achieving simultaneous high selectivity and efficiency remains a significant technical challenge due to the complex mechanisms of the nitrate reduction reaction (NitRR) and its inherent competition with the hydrogen evolution reaction (HER). In this study, we analyzed the structural contributions of LDH catalysts for maximizing nitrate reduction efficiency and systematically established key catalyst design indicators required to ensure optimal performance. Specifically, we provide a detailed investigation of the physicochemical mechanisms for enhancing NH₃ production by precisely regulating the adsorption energies of reaction intermediates and maximizing charge transfer efficiency through compositional control and defect engineering. Furthermore, we discuss advanced structural design strategies, such as core-shell tandem structures, MOF-derived architectures, and interlayer anion control, as effective methods for enhancing catalytic performance and optimizing mass transport processes. These insights offer a strategic roadmap for designing high-performance LDH catalysts and represent a critical step toward the practical implementation of sustainable green ammonia production systems, particularly for integration into high-efficiency membrane electrode assembly (MEA) technologies.
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Humidity monitoring of exhaled breath has emerged as a vital approach for noninvasive respiratory health assessment, underscoring the need for sensitive and reliable humidity sensors. Despite its high conductivity and hydrophilic functional groups, reduced graphene oxide (rGO) often undergoes irreversible moisture adsorption and gradual oxidation by residual water, resulting in sensitivity degradation and long-term instability during cycling. In this study, a montmorillonite/reduced graphene oxide (MMT/rGO) composite is developed as a room-temperature humidity-sensing material, exhibiting an optimized response of 115%, more than 14 times higher than that of pristine rGO. This superior performance originates from the synergistic interaction between the reversible MMT swelling and the conductive rGO network near the electrical percolation transition, which ensures excellent stability and repeatability under repeated humidity cycles. These findings suggest that the MMT/rGO composite provides a cost-effective and biocompatible platform for next-generation wearable humidity sensors capable of continuous respiratory monitoring.
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A Study on the Development of an Uninterruptible Diagnosis Determination Method for Molded Transformers Using Multiple Diagnosis Sensors
Seok Myung Bae, Yong Moo Chang, Hyo Jin Kim
J Electr Electron Mater 2025;38(5):573-579.   Published online September 1, 2025
DOI: https://doi.org/10.4313/JEEM.2025.38.5.14
With the rapid development of digital technologies such as IoT, AI, and big data, electrical energy consumption is rapidly increasing. Electrical facilities that supply electrical energy are operated with high reliability and stability for end-of-life time. In addition, depending on the type of electrical load that consumes electrical energy in various forms, electrical insulation systems deteriorate due to electrical and thermal stress, which reduces electrical and mechanical insulation strength. Due to such continuous stress and electrical transient phenomena, electrical facilities may experience electrical accidents due to electrical insulation breakdown before the expected design lifetime. In addition, periodic inspections according to related regulations must be conducted to prevent unexpected electrical accidents, but this leads to problems in which the electrical facilities cannot be turned off. Therefore, it is believed that an uninterruptible diagnostic judgment technique that determines compliance with related regulations such as electrical facility technology standards, internal wiring regulations, and inspection regulations without turning off the electrical facilities and at the same time detects abnormal conditions of the facilities early, it is possible to prevent electrical accidents and improve the efficiency of electrical facilities. In this paper, we propose an uninterruptible power diagnosis judgment technique that can prevent or reduce electrical accidents in cast-iron transformers by applying judgment criteria of diagnostic sensors for various types of measurement parameters that can diagnose and evaluate the presence or absence of abnormalities in electrical equipment, including partial discharge, and AI algorithms learned from data of diagnostic sensors.
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Factors Limiting Power Conversion Efficiency in GaInN/GaN-Based μ-LEDs Investigated by Chip-Size and Temperature-Dependent Measurements
Hana Lim, Jiye Choi, Minji Ryu, Yejin Kim, Ilji Hwang, Dong-pyo Han
J Electr Electron Mater 2025;38(3):282-289.   Published online May 1, 2025
DOI: https://doi.org/10.4313/JKEM.2025.38.3.7
This study aimed to elucidate factors limiting power conversion efficiency (PCE) in GaN-based micro-light-emitting diodes (μ-LEDs). To this end, we investigated the effects of operating temperature and chip-size of μ-LEDs on their efficiency. For the investigation, 460 nm-emitting μ-LEDs with various chip-sizes were fabricated; then their characteristics were carefully measured from 100 to 400 K. As the chip-size decreases and the operating temperature increases, their PCE and external quantum efficiency (EQE) decrease, while voltage efficiency (VE) increases. This indicates that the EQE plays a more important role than the VE in determining the PCE of μ-LEDs. Particularly, for a chip-size of 20 × 20 μm2, the EQE was very lower and the ideality factor was unexpectedly higher compared to the others for all operating temperatures, which is believed to be due to the critical plasma damage at the sidewall during dry-etching process for the chip-size < 20 × 20 μm2.
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This study examined the crystallinity and potential of BaTiO₃ powder, prepared by hydrothermal synthesis at 60 nm, as a dielectric material for automotive MLCCs under varying heat treatment temperatures. At temperatures above 850℃, the powder exhibited an orthorhombic structure, with crystallinity and particle size increasing as the temperature rose. In the range of 850~900℃, the powder displayed a uniform particle size distribution and minimal agglomeration, with particles ranging between 150~200 nm. Additionally, it was confirmed that the heat treatment temperature significantly impacts the properties of BaTiO₃ powder, which are critical for the dielectric performance required in X7R MLCCs used in automotive applications. Specifically, high-temperature treatment (above 850℃) was essential for enhancing the powder's crystallinity and forming a stable core-shell structure, which is crucial for achieving stable TCC (Temperature Coefficient of Capacitance) characteristics. It was confirmed that increased crystallinity at temperatures above 850℃ facilitated the development of the core-shell structure through interactions with additives, thereby achieving the necessary characteristics required for highly reliable automotive MLCCs.
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Analysis of the Electrical Characteristics of the β-Ga₂O₃ JFET by Using Nitrogen Doping
Hyoung Woo Kim, Jung Hun Kim, Jae Hwa Seo
J Electr Electron Mater 2025;38(2):207-212.   Published online March 1, 2025
DOI: https://doi.org/10.4313/JKEM.2025.38.2.12
In this study, we proposed β-Ga₂O₃ JFET using nitrogen doping and analyzed the electrical characteristics. In β-Ga₂O₃, nitrogen ions act as a deep acceptor and are used to implement the current blocking layer. By using this characteristic of the nitrogen ion, in the proposed JFET, nitrogen ions are used to obtain gate control and pinch off the channel of the JFET. The numerical TCAD simulation was performed to design and analyze the proposed JFET. The simulated forward and reverse characteristics of the proposed JFET were obtained as a function of JFET width and nitrogen doping concentration. The maximum breakdown voltage of 1.7 kV was obtained with the on-resistance of 16.7 mΩ·cm2 when the channel width was 1.5 μm and nitrogen doping concentration is 1×1018/cm3, respectively.
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IoT Using Assemble Double Pipe System
Ji-min Lee, Chang-hyoung Lee, Min-cheol Oh, Sangjin Cho, Young Cho
J Electr Electron Mater 2025;38(1):84-88.   Published online January 1, 2025
DOI: https://doi.org/10.4313/JKEM.2025.38.1.11
Hazardous gas leakage incidents rank among the most serious safety accidents, leading to significant loss of life, extensive property damage, and severe environmental pollution. This paper describes an innovative IoT-based Assembly Double Pipe System (IADPS) designed for the prevention, early detection, and automated isolation of toxic gas leaks. The proposed system features a double-layered pipe design, with nitrogen charged between the inner and outer pipes, and gas detectors installed at strategic locations. This configuration is intended to prevent pipe corrosion, suppress ignition caused by escaping gas, and facilitate the early detection of gas leaks, thereby mitigating the risk of safety accidents. Furthermore, the system includes a comprehensive real-time monitoring system for pipe integrity and gas leakage, as well as an automated gas leakage detection and isolation system to quickly respond to any incidents.
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Simulation of Potential Difference Analysis in Conductor-Dielectric Type Triboelectric Generator Using COMSOL Multiphysics
Yong Hoon Son, Geon-tae Hwang
J Electr Electron Mater 2024;37(6):600-608.   Published online November 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.6.4
In the era of the Fourth Industrial Revolution, electronic devices are becoming increasingly miniaturized and lightweight to overcome spatial limitations, necessitating lower power consumption. Triboelectric nanogenerators (TENGs), which convert mechanical energy into electrical energy, offer an ideal solution as small-scale power generators for these compact devices. Recent research has focused on various materials and structural designs to maximize the output of triboelectric energy harvesters, highlighting the growing importance of theoretical structure analysis software for precise evaluation. COMSOL Multiphysics software provides an accurate method for simulating the electrical characteristics of TENGs. This Tutorial Status Report introduces the process of modeling TENGs and analyzing their electrical output using COMSOL Multiphysics
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Effect of High-Temperature Post-Oxidation Annealing in Diluted Nitric Oxide Gas on the SiO2/4H-SiC Interface
In Kyu Kim, Jeong Hyun Moon
J Electr Electron Mater 2024;37(1):101-105.   Published online January 1, 2024
DOI: https://doi.org/10.4313/JKEM.2024.37.1.14
4H-SiC power metal-oxide-semiconductor field effect transistors (MOSFETs) have been developed to achieve lower specific-on-resistance (Ron,sp), and the gate oxides have been thermally grown. The poor channel mobility resulting from the high interface trap density (Dit) at the SiO2/4H-SiC interface significantly affects the higher switching loss of the power device. Therefore, the development of novel fabrication processes to enhance the quality of the SiO2/4H-SiC interface is required. In this paper, NO post-oxidation annealing (POA) by using the conditions of N2 diluted NO at a high temperature (1,300℃) is proposed to reduce the high interface trap density resulting from thermal oxidation. The NO POA is carried out in various NO ambient (0, 10, 50, and 100% NO mixed with 100, 90, 50, and 0% of high purity N2 gas to achieve the optimized condition while maintaining a high temperature (1,300℃). To confirm the optimized condition of the NO POA, measuring capacitance-voltage (C-V) and current-voltage (I-V), and time-of-flight secondary-ion mass spectrometry (ToF-SIMS) are employed. It is confirmed that the POA condition of 50% NO at 1,300℃ facilitates the equilibrium state of both the oxidation and nitridation at the SiO2/4H-SiC interface, thereby reducing the Dit.
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A Brief Review on Piezoelectrics-Based Paint Sensors
Hyoung-su Han, Trang An Duong, Chang Won Ahn, Byeong Woo Kim, Jae-shin Lee
J Electr Electron Mater 2023;36(5):433-441.   Published online September 1, 2023
DOI: https://doi.org/10.4313/JKEM.2023.36.5.2
Piezoelectric ceramics play an important role in electrical and electronic devices such as sensors, actuators, and microelectronic devices. However, traditional ceramics are difficult to be used in various process industries due to their high brittleness and low flexibility. Therefore, piezoelectric paint sensors have been designed for application to the curved surfaces of complicated structures. Furthermore, recently, significant attention has been focused on the development of paint sensors that can be used as structure health monitoring sensors for vibration, impact, and acoustic emission. Several studies have successfully demonstrated the possibility that smart paint sensors can take the place of traditional ceramic sensors. In this review, we briefly introduce the concept of the piezoelectric paint sensors and the expected application field as well as their preparation and history.
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Nitrogen-doped graphene was synthesized by a hydrothermal method using graphene oxide (GO) as the raw material, urea as the reducing agent and nitrogen as the dopant. The morphology, structure, composition and electrochemical properties of the samples are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), nitrogen adsorptiondesorption analysis, electrical conductivity and electrochemical tests. The results show that urea can effectively reduce GO and achieve nitrogen doping under the hydrothermal conditions. By adjusting the mass ratio of raw materials to dopants, the graphene with different nitrogen doping contents can be obtained; the nitrogen content range is from 5.28~6.08% (atomic fraction percentage).When the ratio of dopant to urea is 1:30, the nitrogen doping content reaches a maximum of 6.08%.The supercapacitor performance test shows that the nitrogen content prepared by the ratio of 6.08% is the best at 0.1 A·g-1. The specific capacitance is 95.2 F·g-1.
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Real-Time Soil Humidity Monitoring Based on Sensor Network Using IoT
Kyeong Heon Kim, Hee-dong Kim
J Electr Electron Mater 2022;35(5):459-465.   Published online September 1, 2022
DOI: https://doi.org/10.4313/JKEM.2022.35.5.6
This paper reports a method to use a wireless sensor network deployed in the field to real-time monitor soil moisture, warning when the moisture level reaches a specific value, and wirelessly controlling an additional device (LED or water supply system, etc.). In addition, we report all processes related to wireless irrigation system, including field deployment of sensors, real-time monitoring using a smartphone, data calibration, and control of additional devices deployed in the field by smartphone. A commercially available open-source Internet of Things (IoT) platform, NodeMCU, was used, which was combined with a 9V battery, LED and soil humidity sensor to be integrated into a portable prototype. The IoT-based soil humidity sensor prototype deployed in the field was installed next to a tree for on-site demonstration for the measurement of soil humidity in real-time for about 30 hours, and the measured data was successfully transmitted to a smartphone via Wifi. The measurement data were automatically transmitted via e-mail in the form of a text file, stored on the web, followed by analyses and calibrations. The user can check the humidity of the soil real-time through a personal smartphone. When the humidity of a soil reached a specific value, an additional device, an LED device, placed in the field was successfully controlled through the smartphone. This LED can be easily replaced by other electronic devices such as water supplies, which can also be controlled by smartphones. These results show that farmers can not only monitor the condition of the field real-time through a sensor monitoring system manufactured simply at a low cost but also control additional devices such as irrigation facilities from a distance, thereby reducing unnecessary energy consumption and helping improve agricultural productivity.
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Development of Humidity Sensor Based on Ceramic/Metal Halide Composite Films for Non-Contact Biological Signal Monitoring Applications
Tae-ung Park, Ik-soo Kim, Min-ji Kim, Chulhwan Park, Eui-kyoung Seo, Jong-min Oh
J Electr Electron Mater 2022;35(4):412-417.   Published online July 1, 2022
DOI: https://doi.org/10.4313/JKEM.2022.35.4.15
Capacitive-type humidity sensors with a high sensitivity and fast response/recovery times have attracted a great attention in non-contact respiration biological signal monitoring applications. However, complicated fabrication processes involving high-temperature heat treatment for the hygroscopic film is essential in the conventional ceramic-based humidity sensors. In this study, a non-toxic ceramic/metal halide (BaTiO3(BT)/NaCl) humidity sensor was prepared at room temperature using a solvent-free aerosol deposition process (AD) without any additional process. Currently prepared BT/NaCl humidity sensor shows an excellent sensitivity (245 pF/RH%) and superior response/recovery times (3s/4s) due to the NaCl ionization effect resulting in an immense interfacial polarization. Furthermore, the non-contact respiration signal variation using the BT/NaCl sensor was determined to be over 700% by maintaining the distance of 20 cm between the individual and the sensor. Through the AD-fabricated sensor in this study, we expect to develop a non-contact biological signal monitoring system that can be applied to various fields such as respiratory disease detection and management, infant respiratory signal observation, and touchless skin moisture sensing button.
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Finite Element Analysis for the Optimal Shape of the High Voltage Insulator for Power Transmission Lines
Taeyong Kim, Simpy Sanyal, Matheus Rabelo, Junsin Yi
J Electr Electron Mater 2022;35(1):66-71.   Published online January 1, 2022
DOI: https://doi.org/10.4313/JKEM.2022.35.1.10
The insulator used for the transmission line is a device that is bonded with a cap, pin, ceramic, and cement to withstand insulation capacity and mechanical load. The insulator design can help to reduce the dispersion of the electric field; thus, the optimization of today’s design, especially as demanded power grows, is critical. The designs of four manufacturers were used to perform a comparative analysis. Under dry circumstances of the new product, an electric field distribution study was done with no pollutants attached. Manufacturer D’s design has the best voltage uniformity of 24.33% and the arc length of 500 mm or more. Manufacturer C’s design has an equalizing voltage of more than 2% higher than that of other manufacturers. The importance of the design of the insulator and the number of connections according to the installation conditions is very efficient for transmission lines that will increase in the future.
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Structural Analysis Simulation of Cantilever Shaped Piezoelectric Energy Harvester Using COMSOL Multiphysics
Min Sub Kwak, Geon-tae Hwang
J Electr Electron Mater 2021;34(6):416-425.   Published online November 1, 2021
DOI: https://doi.org/10.4313/JKEM.2021.34.6.3
In the 4th industrial age, electronic devices are becoming smaller and lighter with a low power consumption to overcome spatial limitation. The piezoelectric energy harvesters can convert mechanical kinetic energy into electric energy; thus, enabling the operation of small electronic devices. Recently, various piezoelectric harvesters have been reported and the electric output from these harvesters could be anticipated by theoretical analysis methods. For example, COMSOL Multiphysics software provides a theoretical simulation of piezoelectric effect with a combination of mechanical and electrical phenomena in the piezoelectric materials. This article introduces a brief modeling of piezoelectric harvester to investigate mechanical stress and electrical output of harvesting devices by the COMSOL Multiphysics software.
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Condition Monitoring Technique for Heating Cables by Detecting Discharge Signal
Dong-eon Kim, Nam-hoon Kim, Seung-hyun Lim, Gyung-suk Kil
J Electr Electron Mater 2021;34(2):136-141.   Published online March 1, 2021
DOI: https://doi.org/10.4313/JKEM.2021.34.2.10
Heating cables, widely used in office buildings, factories, streets and railways, deteriorate in electrical insulation during operation. The insulation deterioration of heating cables leads to electric discharges that can cause electrical fires. With this background, this paper dealt with a condition monitoring technique for heating cables by the analysis of discharge signals to prevent electrical fires. Insulation deterioration was simulated using an arc generator specified in UL1699 under AC operation, and the characteristic and propagation of discharge signals were analyzed on a 100 meter-long heating cable. Discharge signals produced by insulation deterioration were detected as a voltage pulse because they are as small as a few mV and they are attenuated through propagation path.The frequency spectrum of discharge signals mainly existed in the range from 70 kHz to 110 kHz, and the maximum attenuation of the signal was 84.8% at 100 meters away from the discharge point. Based on the experimental results, a monitoring device, which is composed of a high pass filter with the cut-off frequency of 70 kHz, a comparator, a wave shaper and a microprocessor, was designed and fabricated. Also, an algorithm was designed to discriminate the discharge signal in the presence of noise, compared with the pulse repetition period and the number of pulse counts per 100ms. In the experiment, the result showed that the prototype monitoring device could detect and discriminate the discharge signals produced at every discharge point on a heating cable.
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In the case of ZnO:Al thin films, it is the best material that can replace ITO that is mainly used as a transparent electrode in electronic devices such as solar cells and flat-panel displays. In this study, ZnO:Al films were fabricated by using the RF dual magnetron sputtering method at various substrate temperatures. As the substrate temperature increased, the crystallinity of the ZnO:Al thin films was improved, and the electrical conductivity and electrical properties of the thin film improved owing to the increase in grain size. In addition, the surface roughness of the ZnO:Al thin films increased due to changes in the surface and density of the thin films. Moreover, the substrate temperature increased the density of thin films and improved their transmittance. To be applied to solar cells and other several electronic devices in the future, the hardness and adhesion properties of the thin film improve as the substrate temperature increases.
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Using facing target magnetron sputtering (FTMS) with a graphite target source, carbon nitride thin films were deposited on silicon and glass substrates at different substrate temperatures to confirm the tribological, electrical, and structural properties of thin films. The substrate temperatures were room temperature, 150℃, and 300℃. The tribology and electrical properties of the carbon nitride thin films were measured as the substrate temperature increased, and a study on the relation between these results and structural properties was conducted. The results show that the increase in the substrate temperature during the fabrication of the carbon nitride thin films increased the hardness and elastic modulus values, the critical load value was increased, and the residual stress value was reduced. Moreover, the increase in the substrate temperature during thin-film deposition was attributed to the improvement in the electrical properties of carbon nitride thin film.
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Effect of Nitrogen, Titanium, and Yttrium Doping on High-K Materials as Charge Storage Layer
Ziyang Cui, Dongxu Xin, Jinsu Park, Jaemin Kim, Khushabu Agrawal, Eun-chel Cho, Junsin Yi
J Electr Electron Mater 2020;33(6):445-449.   Published online November 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.6.3
Non-volatile memory is approaching its fundamental limits with the Si3N4 storage layer, necessitating the use of alternative materials to achieve a higher programming/erasing speed, larger storage window, and better data retention at lower operating voltage. This limitation has restricted the development of the charge-trap memory, but can be addressed by using high-k dielectrics. The paper reviews the doping of nitrogen, titanium, and yttrium on high-k dielectrics as a storage layer by comparing MONOS devices with different storage layers. The results show that nitrogen doping increases the storage window of the Gd2O3 storage layer and improves its charge retention. Titanium doping can increase the charge capture rate of HfO2 storage layer. Yttrium doping increases the storage window of the BaTiO3 storage layer and improves its fatigue characteristics. Parameters such as the dielectric constant, leakage current, and speed of the memory device can be controlled by maintaining a suitable amount of external impurities in the device.
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Synthesis of TiN-Coated cBN Powder by Sol-Gel Method Using Titanium (IV) Isopropoxide
Youn Seong Lee, Sun Woog Kim, Young Jin Lee, Ji Sun Lee, Dongwook Shin, Sae-hoon Kim, Jin Ho Kim
J Electr Electron Mater 2020;33(5):373-379.   Published online September 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.5.7
In this study, TiN-coated cBN (cubic-structure boron nitride) powders were successfully synthesized by a sol-gel method using titanium (IV) isopropoxide (TTIP) and by controlling the heat treatment conditions. After the sol-gel process, amorphous nano-sized TiOx was uniformly coated on the surface of cBN powder particles. The obtained TiOx-coated cBN powders were heated at 1,000~1,300℃ for 1 or 6 h in a flow of 95%N2-5%H2 mixed gas. With increasing temperature, the chemical composition of the TiOx coating layer changed in the order of TiO2→Ti6O11→Ti4O7→TiN due to reduction of the Ti ions. The TiN coating layer was observable in the samples heated at 1,200℃ and appeared as the main phase in the sample heated at 1,300℃. The resulting thickness of the TiN coating layer of the sample heated at 1,300℃ was approximately 45~50 nm.
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Study on the Piezoelectric Bender Actuator for Small Walking Robots
Min Ho Park, Jong Man Park, Chi Hoon Song
J Electr Electron Mater 2020;33(4):276-280.   Published online July 1, 2020
DOI: https://doi.org/10.4313/JKEM.2021.33.4.5
A linear piezoelectric actuator that utilizes the elliptical motion of the two tips of the actuator is proposed. This device is easy to fabricate owing to its simple structure, consisting of three piezo ceramic benders and is suitable for use in micro robotic applications. A π-shaped structure, which was composed of four piezo ceramic benders, was constructed. Two of the benders were positioned on the center of the actuator, and the joints were attached at the ends of the cantilever. The other two benders were positioned on the side of the actuator and were attached between the joint and the tips. The actuator structure was designed to obtain the first bending mode of the horizontal vibration and the vertical vibration at the same frequency, resulting in elliptical motions at the tips. When two sinusoidal wave voltages with a 90-degree phase difference were applied to the two pairs of the actuator benders, elliptical motions were obtained at the tips. The driving characteristics of the prototype actuator were then measured using a laser doppler vibrometer.
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PLC Optical Sensor for Contamination Monitoring on the Flow-Cell in the Water Quality Measurement System
Seung Heon Han, Tae Un Kim, Haeng Yun Jung, Hyun Chul Ki, Doo Gun Kim, Seon Hoon Kim
J Electr Electron Mater 2019;32(6):472-476.   Published online November 1, 2019
We have proposed a novel planar lightwave circuit (PLC) optical sensor to monitor the contamination in a flow-cell where water is continuously supplied through a water quality measurement system. We designed a PLC chip with a V-shape waveguide and the simulated its function as a sensor for monitoring contamination in a flow-cell using a numerical the FDTD (finite-difference time-domain) analysis. A novel cross type of waveguide was introduced to make the PLC chip of the V-shaped waveguide. The fabricated PLC was cut into the cross waveguide. A change in the optical propagation loss of the PLC sensor was observed after immersing the PLC sensor into city water. It was determined that the propagation loss of the PLC sensor was 3 dB at a wavelength of 1.55 μm in the city water for 15 days.
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A Study on Technologies for Measuring Static Condition of Rigid Conductor System in Railway Electrification
Kyung Min Na, Kiwon Lee, Young Park
J Electr Electron Mater 2019;32(6):507-511.   Published online November 1, 2019
The purpose of an electric railway system contact wire is to supply electric energy to trains through a contacted pantograph. This energy is then converted into mechanical energy. Recent developments in overhead contact lines include the increase in the tension force up to 34 kN according to train speeds that reach up to 400 km/h with a verified safety. Rigid conductor catenary (R-Bar) for high speeds of up to 250 km/h have been developed in tunnels to save on construction costs. This is significant because minor defects in R-bars in aspects, such as height and stagger affect installation conditions. In this study, we propose the use of a detector that measures the static characteristics to reduce the R-bar installation errors. This detector has been developed to measure the height and stagger of the contact wire using video images.
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Thermal Characteristics of Silicone Composites for the Application to Heat-Controllable Components
Ho-du Kwak, Weontae Oh
J Electr Electron Mater 2019;32(2):116-121.   Published online March 1, 2019
Hexagonal boron nitride particles (s-hBN) modified with 3-aminopropyl triethoxysilane (APTES) were used for the preparation of silicone composite materials. The microstructure of the composite materials was observed, and the thermal conduction and mechanical characteristics of the composite sheets were studied based on the compositions and microstructures. When a small amount of s-hBN particles was used, the thermal conductivity of the composite improved as a whole, and the tensile strength of the sheet also increased. The thermal conductivity and tensile strength of the composite in which a small amount of carbon fiber was added along with s-hBN were further improved. However, the use of carbon nanotubes with structural characteristics similar to those of carbon fiber resulted in lower thermal conductivity and tensile strength. Elastic silicone composites exhibiting 2.5 W/mK of thermal conductivity and a low hardness are expected to be used as thermally conductive interfacial sheet materials.
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Optimization of Electrode Pattern for Multilayer Ceramic Heater by Finite Element Method
Yoonsoo Han, Shi Yeon Kim, Dong-hun Yeo
J Electr Electron Mater 2017;30(12):776-781.   Published online December 1, 2017
In this study, we investigated the effect of electrode pattern design on the thermal shock resistance and temperature uniformity of a ceramic heater. A cordierite substrate with a low thermal expansion coefficient was fabricated by tape casting, and a tungsten electrode was printed and used as a heating element. The temperature distribution of the ceramic heater was calculated by a finite-element method (FEM) by considering various electrode patterns, and the tensile stress distribution due to the thermal stress was calculated. In the electrode pattern with a single-line width, the central part of the ceramic heater was heated to the maximum temperature, and the position of the ceramic heater having a double-line width was changed to the maximum temperature, depending on the position of the minimum line width pattern. The highest tensile stress was found along the edges of the ceramic heater. The temperature gradient at the edge determined the tensile stress intensity. The smallest tensile stress was observed for electrode pattern D, which was expected to be advantageous in resisting thermal shock failures in ceramic heaters.
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Electrical Characteristic Changes of ZnO Varistors by Energy Absorption
Woo-hyun Kim, Seong-cheol Hwang, Guoming Wang, Gyung-suk Kil, Chang-hwan Ahn
J Electr Electron Mater 2017;30(12):817-821.   Published online December 1, 2017
As a ZnO varistor is subjected to electrical and environmental stresses, it degrades gradually, which may result in power interruption by short circuit. This study investigates changes in the electrical characteristics of ZnO varistors due to deterioration owing to energy absorption, and determines the optimal parameters for on-line diagnosis of the varistor. Two types of varistors were used for an accelerated aging experiment involving the application of the 8/20 μs standard lightning impulse current. The electrical characteristics in terms of the reference voltage, total leakage current, resistive leakage current, and third-harmonic component of the total leakage current were measured, and their change rates were analyzed. The results revealed that the total leakage current increased slightly with an increase in the varistor absorbed energy, while the resistive leakage current and the third-harmonic component increased apparently. Therefore, the third-harmonic component of the total leakage current was proposed as the optimal parameter for on-line monitoring of ZnO varistor conditions.
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Development of Heating Roller Monitoring System for Lamination
Jae-jun Oh, Woon-shik Choi, Seong-ju Choi
J Electr Electron Mater 2017;30(10):677-682.   Published online October 1, 2017
Lamination is used extensively in various industries. The type of lamination applied to the material depends on the precision level required, which varies for materials needed for everyday use, materials used in high-tech industries, and processes employed to fabricate finished products. Especially in hot lamination, the distribution of the surface temperature of the heating roller is very important to avoid the generation of internal bubbles and ensure flatness of the attached materials, and thus maintain a good standard of quality and productivity. In this study, we have developed a system to monitor the surface temperature of the heating rollerby applying a heterogeneous controller and a non - contact temperature sensor. This monitoring system accurately measures the surface temperature of the heating roller and applies the RS485 MODBUS communication method for easy expansion. Using this system, a laminated prototype was fabricated, and its efficacy for non-contact temperature sensor calibration, Ethernet IP communication, stoppage of the heating roller, and determination of temperature distribution with rotation was examined for its potential usage in industries.
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Development of Moving and Attaching Diagnosis Device Using IoT
Chool-hyun Ka, Dong-gyu Lee, Jin-sa Kim
J Electr Electron Mater 2017;30(9):596-601.   Published online September 1, 2017
The advancement and diversification of urban functions has caused an increasing need to improve the reliability of power supplies. The diversification of urban areas causes social disruptions by paralyzing urban functions during power outages. A large power outage occurs in the event of an accident, owing to the subduction of distribution lines. Therefore, in recent years, for the sake of the environment and safety, the safety diagnosis of electric power facilities has become an important issue. In this system, because thermal information changes rapidly during unattended monitoring owing to heat concentration phenomenon due to abnormal load or deterioration, studies have been conducted on the development of a device that can notify the manager at all times.
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Performance Estimation Based on 4D Lookup Table Interpolating and Unit Cell Discharge Tests for Thermal Battery
Byeong June Park, Ji Youn Kim, Sang Hyeon Ha, Jang Hyeon Cho
J Electr Electron Mater 2017;30(6):393-400.   Published online June 1, 2017
For comparison to the Li-ion battery, evaluating a thermal battery must consider additional variables. The first one is the temperature difference between the battery and its unit cell. Thermal batteries and their unit cells have a temperature difference that is caused by the thermal battery activation mechanism and its shape. The second variable is the electrochemical reaction steps. Most Li-ion batteries have a constant electrochemical reaction at the electrode, and battery voltage is affected when the concentration of Li ions is changed. However, a thermal battery has several steps in its electrochemical reaction, and each step has a different potential. In this study, we used unit cell discharge tests based on interpolating a 4D lookup table to estimate the performance of a thermal battery. From the test results, we derived an estimation algorithm by interpolating the table, which is queried from specified profile groups. As a result, we found less than a 5 percent difference between estimation and experiment at the 1.3 V cut-off time.
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